• 제목/요약/키워드: solvent-resistance

검색결과 234건 처리시간 0.028초

Fabrication of transparent conducting films of carbon nanotubes using a spray method

  • Geng, Hong Zhang;Lee, Kyu;Song, Young-Il;Kim, Gil-Yong;Choi, Ha-Kyu;Jun, Bae-Jung;Ahn, Kay-Hyeok;Lee, Young-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.525-528
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    • 2006
  • Transparent conducting films were fabricated on polyethylene terephthalate substrate by a spray method using double-walled carbon nanotubes dispersed in organic solvent and water-based solution. We analyzed the films by absorption spectra, sheet resistance, and scanning electron microscopy. Transparent conducting films with high uniformity and high transparency were fabricated by the spray method. We found that the dispersion particularly nanodispersion of CNTs was of crucial importance to improve the film performance.

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전기화학적 중합으로 제조된 ABS/PPy 복합 박막의 전도특성 (Conducting Characteristics of ABS/PPy Composite Film Prepared by Electrochemical Polymerization)

  • 김진;윤도영;김대흠;한춘;김상용
    • 전기화학회지
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    • 제5권3호
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    • pp.164-167
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    • 2002
  • 본 연구에서는 ABS(Acrylonitrile-Butadiene-Styrene)을 주-고분자로 사용하여 산화안정성이 개선된 ABS/Polypyrrole 복합박막을 전기화학적 방법으로 합성하였다 우선 acetonitrile계의 용매로 주-고분자를 팽창시켰으며, pyrrole과 지지전해질이 백금전극에 미리 코팅된 ABS내부로 투과하여 백금 전극표면에 ABS/PPy복합체가 형성되도록 하였다. 결과적으로 전도성 ABS/PPy 복합박막은 polypyrrole과 비교하여 일정한 저항을 유지하였으며, 산화안정성도 향상되는 것으로 나타났다.

난류유동장에서 Shear - thinning 유체에 의한 마찰저항 감소에 관한 연구 (A Study on the Drag Reduction by Shear-thinning Fluid in Turbulent Flow Fields)

  • 차경옥;김재근;오율권
    • Journal of Advanced Marine Engineering and Technology
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    • 제21권2호
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    • pp.126-135
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    • 1997
  • Drag reduction in polymer solutions is the phenomenon where by extremely dilute solutions of high molecular weight polymers exhibit frictional resistance to flow much lower than the pure solvent. This effect, largely unexplained as yet, has attracted the attention of polymer scientists and fluid flow specialists. Although applications are beginning to appear, the principle interest to data has been in attempting to relate the effect to the fluid mechanics of turbulent flow. Drag reduction in two phase flow can be applied to the transport of crude oil, phase change system such as chemical reactor, and pool and boiling flow. But the research on drag reduction in two phase flow is not intensively investigated. Therefore, experimental investigations have been carried out to analyze the drag reduction produced by polymer addition in the single phase and two phase flow system. The objectives of the proposed investigation are primarily in identifying and developing high performance polymer additives for fluid transportations with the benefits of turbulent drag. Also we want to is to evaluate the drag reduction in horizontal flow by measuring pressure drop and mean velocity. Experimental results show higher drag reduction using co - polymer(A611P) then using polyacrylamide (PAAM) and faster degradation using PAAM than using A611P under the same superficial velocity.

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Indium Tin Oxide (ITO) Coatings Fabricated using Nanoparticle Slurry and Sol

  • Cheong, Deock-Soo;Yun, Dong-Hun;Kim, Dong-Hwan;Han, Kyoung-R.
    • 한국세라믹학회지
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    • 제48권6호
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    • pp.516-519
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    • 2011
  • Indium tin oxide (ITO) coatings were made using an ITO slurry and an ITO sol. This was achieved by dispersing nanosized ITO powder in a mixed solvent without any dispersant and developing an adhesive ITO sol from indium acetate and tin tetrachloride in a mixture of DMF and n-butanol. Coating was carried out in one step by spin coating an ITO slurry, which was then followed by an ITO sol over it. Here, the sol penetrates into the nano ITO particle layers to make them adhere to each other as well as to a glass substrate. This is then followed by sintering at 500$^{\circ}C$ for 1 h to produce a uniform film consisting of ITO particles of about 50 nm and 10 nm. ITO films were obtained with sheet resistances from 450 to 1500 ohm/${\Box}$ by varying spin speed and concentration. Transmittance is higher than 90% at 550 nm.

Methanol 가스에 대한 고분자 센서의 온도와 습도 영향 고찰 (Effect of Humidity and Operating Temperature of Polymer Sensor to Methanol Gas)

  • 이경문;허용수;전희권;손성옥;허증수
    • 한국재료학회지
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    • 제13권12호
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    • pp.796-800
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    • 2003
  • The polypyrrole prepared with pyrrole monomer, APS and DBSA was synthesized by chemical Polymerization at $V^{\circ}C$ under atmosphere conditions. After dissolving polypyrrole powder to the chloroform including DBSA, polypyrrole film was prepared on the alumina substrate with an interdigitated electrode by using the dip-coating method. This film was soaked in methanol solvent for 1 h at room temperature and heated to $70^{\circ}C$ for 4 h in $N_2$. Initial resistance was increased with the increasing humidity and decreasing temperature. The sensitivity was increased with lower humidity and decreasing temperature. The best linearity was achieved at $25^{\circ}C$ and low humidity of 0%.

Polyether Polyol을 이용한 수분산 폴리우레탄의 1,4-butanediol 사슬연장에 의한 물성변화 (A Study on Measurement of Mechanical Properties of Polyther Polyol Base Polyurethane Dispersion by 1,4-butanediol Chain Extension)

  • 이주엽
    • 한국응용과학기술학회지
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    • 제31권4호
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    • pp.711-718
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    • 2014
  • 본 논문에서는 피혁에 사용되는 수용성 폴리우레탄 사슬 연장제인 1,4-butanediol(1,4-BD)의 함유에 따른 물성변화를 조사하였다. 합성에 사용된 시약은 poly propylene glycol(PPG), isoporon diisocyanate((IPDI), dimethylolpropionic acid(DMPA), 1,4-BD를 사용하였다. 1,4-BD의 함유에 따른 내용제성과 내굴곡성 측정값은 시료 전부 우수한 물성을 보였다. 인장강도, 내마모성 측정결과 1,4-BD가 많이 함유된 시료들이 각각 $1.80kg_f/mm^2$, 49.54 mg.loss로 우수한 물성을 확인하였다. 연실율 측정결과 1,4-BD가 적게 함유된 시료가 364%로 가장 우수한 측정값을 나타냈다.

분말사출성형에 의한 WC-Co 계 milling insert 제조 (WC-Co Milling Inserts Manufactured by Powder Injection Molding)

  • 성환진
    • 한국분말재료학회지
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    • 제6권1호
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    • pp.88-95
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    • 1999
  • The purpose of this study is to investigate the manufacturing feasibility of WC-Co milling inserts via Powder Injection Molding (PIM) process. WC-Co is used in a wide variety of cutting tools due to its high hardness, stiffness, compressive strength and wear resistance properties. WC-Co parts for a high stress application were conventionally produced by the press and sinter method, which were Iimited to 2 dimensional shapes. Manufacturing WC-Co parts for a high stress application by PIM implies that tool efficiency can be highly improved due to increased freedom is design. P30 grade WC powder (WC-Co-TiC-TaC system) was mixed with RIST-5B133 binder and injection molded into milling inserts (Taegu Tech. Model WCMX 06T 308). The mean grain size of the powder was about 0.8$\mu$m. Injection molded specimens were debound by solvent extraction and thermal degradation method at various conditions. The specimens were sintered at 140$0^{\circ}C$ for 1 hr in vacuum. Carbon content, weight loss, dimensional change, and macro defects of the specimen were carefully monitored at each stage of the PIM process. PIMed WC-Co milling inserts reached 100% full density after sinteing. Its mechanical properties and micro-structures were comparable with the press and sintered milling insert. Carbon content of the sintered WC-Co insert was mainly determained by the atmosphere of thermal debinding. By controlling powder loading and injection molding condition, dimensional accuracy could be obtained within 0.4%. We confirm that PIM can not only be an alternative manufacturing method for WC-Co parts economically but also provide a design freedom for more effieient cutting tools.

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선도장 컬러강판용 도료에 적용하기 위한 자가 광경화형 폴리우레탄 아크릴레이트 올리고머 합성 및 물성 (Synthesis and Properties of Self-photocuring Polyurethane Acrylate Oligomer for Color Pre-coated metal)

  • 박소영;천정미;정부영;이도혁;천제환
    • 접착 및 계면
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    • 제21권1호
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    • pp.14-19
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    • 2020
  • 본 연구에서는 Michael addition 반응을 통해 자가 광경화형 중간체를 합성하여 이를 적용한 폴리우레탄 아크릴레이트 올리고머를 합성하였다. 합성된 중간체와 폴리우레탄 아크릴레이트 올리고 머의 분석 및 물성은 FT-IR, NMR 및 UTM을 통해 확인하였다. 중간체의 함량이 증가할수록 인장강도는 증가하고 신율은 감소하였으며 필름이 소수성을 띄어 표면에너지가 감소하는 경향을 보였다. 중간체의 함량이 40 wt%일 때 부착성, 가공성, 연필경도가 우수했으며, 내용제성은 모두 우수한 결과를 나타내었다.

포토마스크가 필요 없는 스크린 제판 기술 개발(II) (A Development on the Non-Photomask Plate Making Technology for Screen Printing (II))

  • 박경진;강효진;김성빈;남수용;안병현
    • 한국인쇄학회지
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    • 제26권2호
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    • pp.45-54
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    • 2008
  • We have manufactured a photoresist which has excellent dispersity and good applying property due to 330 cps of viscosity for environment-friendly and economical maskless screen plate making. And the photoresist applied on the screen stretched was exposed with mask by UV-LED light source so we could manufacture the photoresist which proper for the UV light source. And it was developed by air spray with $1.7\;kgf/cm^2$ of injection pressure. Because of the excellence of power and resolution of the UV-LED light sourse, the pencil hardness and solvent resistance of curing photoresist film were excellent as those of conventional photoresist film. Moreover the $100{\mu}m$-width stripe image which has sharp edges was formed. So we confirmed a possibility of dry development process by air spray method.

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포토마스크가 필요 없는 스크린 제판 기술 개발(III) (A Development on the Non-Photomask Plate Making Technology for Screen Printing (III))

  • 강효진;박경진;김성빈;남수용;안병현
    • 한국인쇄학회지
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    • 제26권2호
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    • pp.55-64
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    • 2008
  • We designed a UV-LED exposure system which has 365nm dominant wavelength due to the environment-friendly and economical maskless screen plate making. And the photoresist applied on the screen stretched was exposed without mask by beam projector with UV-LED light source. Then it was developed by air spray with $1.7\;kgf/cm^2$ of injection pressure. The pencil hardness and solvent resistance of curing photoresist film were excellent as those of conventional photoresist film and the maximum resolution of line image formed by maskless screen plate making. was $100{\mu}m$, so we could establish the possibility of environment-friendly maskless screen plate making technology. But the sharpness of the patterns were ${\pm}40{\mu}m$ since the exposure system for maskless plate making has weak light intensity and the diffusion of light.

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