• Title/Summary/Keyword: solvent system

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The Characteristic prediction of kinematic viscosity and components pattern by adulterated diesel fuel (유사원료 혼입에 따른 경유 동점도 조성분포 변화 예측)

  • Lee, Don-Min;Jung, Choong-Sub;Kim, Jong-Ryeol;Yim, Eui-Soon
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2010.04a
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    • pp.175-175
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    • 2010
  • Adulterated Fuel is one of the most controversial issues due to its adverse effects to engine system and make it difficult to build up the sound distribution system. Typically, Solvent dissolved type among adulterated diesel fuel need much time and efforts to figure out through the experiments. In this paper, we analysis major properties(Kinematic viscosity and components pattern) of suspicious solvents and establish the correlations to substitute the experiments

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Characteristics of Thermal Hazard in Methylthioisocyanate Synthesis Reaction Process (Methylthioisocyanate 합성반응 공정의 열적위험 특성)

  • Han, In-Soo;Lee, Keun-Won;Lee, Joo-Yeob
    • Journal of the Korean Society of Safety
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    • v.27 no.5
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    • pp.77-87
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    • 2012
  • Compared to a batch reactor, where all reactants are initially charged to the reactor, the semi-batch reactor presents serious advantages. The feed of at least one of the reactants provides an additional way of controlling the reaction course, which represents a safety factor and increases the constancy of the product quality. The aim of this study was to investigate the characteristics of thermal hazard such as a feed time, catalysis concentration and solvent concentration in methylthioisocyanate(MTI) synthesis reaction process. The experiments were carried out by the Multimax reactor system and Accelerating rate calorimeter(ARC). The MTI synthesis reaction process has many reaction factors and complicated reaction mechanism of multiphase reaction. Through this study, we can use as a tool for assessment of thermal hazard of other reaction processes by applying experiment method provided.

Development of Poly(D,L-lactic acid) Microspheres Containing Lorazepam (로라제팜을 함유한 poly(D,L-lactic acid) 마이크로스피어 개발)

  • Choi, Han-Gon;Yoo, Bong-Kyu;Rhee, Jong-Dal;Kim, Jung-Ae;Kwon, Tae-Hyub;Woo, Jong-Soo;Yong, Chul-Soon
    • Journal of Pharmaceutical Investigation
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    • v.36 no.3
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    • pp.175-184
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    • 2006
  • Poly(D,L-lacic acid)(PLA) microshperes containing loazepam were prepared by a solvent-emulsion evaporation method and their release patterns were investigated in vitro. Various batches of microspheres with different size and drug content were obtained by changing the ratio of lorazepam to PLA, PLA concentration in the dispersed phase and stirring rate. Rod-like lorazepam crystals on microsphere surface, which were released rapidly and could act as a loading dose, were observed with increasing drug content. The release rate was increased with increase in drug contents and decrease in the molecular weight of PLA. The release rate of lorazepam for long-acting injectable delivery system in vitro, which would aid in Predicting in vivo release Profile, could be controlled by properly optimizing various factors affecting characteristics of microspheres.

Overexpression, Purification, and Preliminary X-ray Crystallographic Analysis of Human Brain-Type Creatine Kinase

  • Bong, Seung-Min;Moon, Jin-Ho;Jang, Eun-Hyuk;Lee, Ki-Seog;Chi, Young-Min
    • Journal of Microbiology and Biotechnology
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    • v.18 no.2
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    • pp.295-298
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    • 2008
  • Creatine kinase (CK; E.C. 2.7.3.2) is an important enzyme that catalyzes the reversible transfer of a phosphoryl group from ATP to creatine in energy homeostasis. The brain-type cytosolic isoform of creatine kinase (BB-CK), which is found mainly in the brain and retina, is a key enzyme in brain energy metabolism, because high-energy phosphates are transfered through the creatine kinase/phosphocreatine shuttle system. The recombinant human BB-CK protein was overexpressed as a soluble form in Escherichia coli and crystallized at $22^{\circ}C$ using PEG 4000 as a precipitant. Native X-ray diffraction data were collected to $2.2{\AA}$ resolution using synchrotron radiation. The crystals belonged to the tetragonal space group $P4_32_12$, with cell parameters of a=b=97.963, $c=164.312{\AA},\;and\;{\alpha}={\beta}={\gamma}=90^{\circ}$. The asymmetric unit contained two molecules of CK, giving a crystal volume per protein mass $(V_m)$ of $1.80{\AA}^3\;Da^{-1}$ and a solvent content of 31.6%.

Causes of Asphalt Waterproofing Membrane Dissolution due to the Addition of the Solvent in Hybrid Water-proofing System (복합방수공법에 있어서 용제 첨가에 따른 아스팔트층 용해원인에 관한 연구)

  • Kim, Dong-Bum;Seo, Hyun-Jae;Song, Je-Young;Kwak, Kyu-Sung;Bae, Kee-Sun;Oh, Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2010.05a
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    • pp.53-56
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    • 2010
  • In this study, we conducted an impact assessment of the amount of volatile organic solvents addition on hybrid water-proofing system of urethane waterproof coating material and modified asphalt sheet. Also, we conducted a comparative assessment of whether modified asphalt sheet is dissolved or not and oil leakage by dissolution in order to perform a comparative analysis of characteristics of the impact on modified asphalt sheet according to the volatility of volatile organic solvents included in urethane waterproof coating material. The test was carried out by adding the same amount of organic solvents into each experimental group which is subject to volatility and non-volatility of organic solvents, respectively. The results of the test showed that in both experimental groups modified asphalt sheet was dissolved when adding over 10 percent of organic solvents regardless of volatility, and oil leakage observed only in the experimental group subject to volatility.

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The Initial Irreversible Capacity of the First Doping/Undoping of Lithium into Carbon

  • Doh, Chil-Hoon;Kim, Hyun-Soo;Moon, Seong-In
    • Carbon letters
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    • v.1 no.3_4
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    • pp.148-153
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    • 2001
  • The initial irreversible capacity, $Q_i$, is one of the parameters to express the material balancing of the cathode to anode. We introduced new terms, which are the initial intercalation Ah efficiency (IIE) and the initial irreversible specific capacity at the surface ($Q_{is}$), to express precisely the irreversibility of an electrode/electrolyte system. Two terms depended on kinds of active-materials and compositions of the electrode, but did not change with charging state. MPCF had the highest value of IIE and the lowest value of $Q_{is}$ in 1M $LiPE_6$/EC + DEC (1 : 1 volume ratio) electrolyte. IIE value of $LiCoO_2$ electrode was 97-98%, although the preparation condition of the material and the electrolyte were different. $Q_{is}$ value of $LiCoO_2$ was 0~1 mAh/g. MPCF-$LiCoO_2$ cell system had the lowest of the latent capacity. $Q_{is}$ value increased slightly by adding conductive material. IIE and $Q_{is}$ value varied with the electrolyte. By introducing PC to EC+DEC mixed solvent, IIE values were retained, but $Q_{is}$ increased. In case of addition of MP, IIE value increased and $Q_{is}$ value also increased a little.

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A Study on the Drag Reduction by Shear-thinning Fluid in Turbulent Flow Fields (난류유동장에서 Shear - thinning 유체에 의한 마찰저항 감소에 관한 연구)

  • 차경옥;김재근;오율권
    • Journal of Advanced Marine Engineering and Technology
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    • v.21 no.2
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    • pp.126-135
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    • 1997
  • Drag reduction in polymer solutions is the phenomenon where by extremely dilute solutions of high molecular weight polymers exhibit frictional resistance to flow much lower than the pure solvent. This effect, largely unexplained as yet, has attracted the attention of polymer scientists and fluid flow specialists. Although applications are beginning to appear, the principle interest to data has been in attempting to relate the effect to the fluid mechanics of turbulent flow. Drag reduction in two phase flow can be applied to the transport of crude oil, phase change system such as chemical reactor, and pool and boiling flow. But the research on drag reduction in two phase flow is not intensively investigated. Therefore, experimental investigations have been carried out to analyze the drag reduction produced by polymer addition in the single phase and two phase flow system. The objectives of the proposed investigation are primarily in identifying and developing high performance polymer additives for fluid transportations with the benefits of turbulent drag. Also we want to is to evaluate the drag reduction in horizontal flow by measuring pressure drop and mean velocity. Experimental results show higher drag reduction using co - polymer(A611P) then using polyacrylamide (PAAM) and faster degradation using PAAM than using A611P under the same superficial velocity.

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Standardization and Seasonal Variation of Quercetin Glycoside in Eucommiae Folium (두충엽 함유 퀘르세틴배당체의 함량 표준화 및 계절적 변화)

  • Ham, In-Hye;Lee, Seung-Jae;Kim, Ho-Hyun;Kang, In-Ho;Jin, Hee-Ouk;Whang, Wan-Kyunn
    • Korean Journal of Pharmacognosy
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    • v.33 no.3 s.130
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    • pp.194-199
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    • 2002
  • The radix and folium of Eucommia ulmoides(Eucommiaceae) has been used for backache, atrophy of the leg and knee, enuresis, hypertension. In order to evaluate to quality of folium, we have been isolated a main compound as a standard compound, which was elucidated $quercetin-3-O-{\beta}-D-xylopyranosyl(l{\rightarrow}2)-{\beta}-D-glucopyranoside$ through it's physicochemical data and IR, FAB-Mass, $^{13}C-NMR$ and $^{1}H-NMR$ analysis. It was analyzed by HPLC system using 17% $CH_3CN$ as a solvent system. The amount of $quercetin-3-O-{\beta}-D-xylopyranosyl(l{\rightarrow}2)-{\beta}-D-glucopyranoside$ from Eucommiae folium was in the range of $0.056{\pm}0.022$ mg(n=7) and also from the results of analysis through seasonal variation$(June{\sim}October)$ September and October have been evaluated to be very high in it's content.

Effects of Various Polyols on Antiseptic System in Emulsions (에멀젼 제형에서 수종의 폴리올이 방부 시스템에 미치는 영향)

  • Cho, Wan-Goo;Cho, Young-Jin
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.4
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    • pp.477-484
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    • 2008
  • It is inevitable to use chemical germicidal agents like paraben, imidazolidinyl urea and phenoxyethanol to preserve the emulsions which is usually used in cosmetics. Although these chemical preservatives are good enough to reduce the microbiological contamination, they are irritative, allergenic to the skin. Several kinds of polyols are used in cosmetics as moisturizer and solvent. In this study, we evaluate the effects of polyols on anti-microbial activities, safety and resistant index. MIC(minimal inhibitory concentration) of polyols determined against 6 germs including Staphylococcus aureus. The order of MIC was PG $\cong$ DPG $\cong$ 1,3BG > HG > 1,2-PD > 1,2-HD $\cong$ 1,2-OD. The $2{\sim}3\;wt%$ of 1,2-HD(hexanediol) shows good anti-microbial effects in emulsions without allergenic response. Resistant index of 1,2-HD was less than 2 and this value was smaller than that of chemical preservatives. The mechanism of antimicrobilogical effect might be disturb the membrane of germs by investigating using electron microscope. Added to that, using this paradigm, low preservative contents, paraben-free system, and even preservative-free systems can be expected from these results.

Synthesis and Properties of Polyester System Polyurethane without Solvent (무용제 반응에 의한 폴리에스테르계 폴리우레탄의 합성 및 특성)

  • Kwak Noh-Seok;Yang Yun-Kyu;Jeong Boo-Young;Hwang Taek-Sung
    • Polymer(Korea)
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    • v.29 no.4
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    • pp.344-349
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    • 2005
  • Polyurethanes(PUs) were synthesized by reaction of isophorone diisocyanate, acetylbutyl citrate, and 3 types of polycaprolactone diol. Their structures were confirmed by FT-IR and NMR spectrometer. And, their thermal and mechanical properties were measured by TGA ud UTM. The effective network chain lengths ($\bar{M}_c$), measured by compressive modulus apparatus, were about $8000\~24000$ g/mol. As crosslinking density and amount of hard segment increased, tensile strength increased and elongation decreased. As the crosslinking density of PUs increased, thermal property inproved. When the ratio of NCO/OH is 1.1, maximum crosslinking density was achieved.