• Title/Summary/Keyword: solution strength

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Effect of metal primers and tarnish treatment on bonding between dental alloys and veneer resin

  • Choo, Seung-Sik;Huh, Yoon-Hyuk;Cho, Lee-Ra;Park, Chan-Jin
    • The Journal of Advanced Prosthodontics
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    • v.7 no.5
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    • pp.392-399
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    • 2015
  • PURPOSE. The aim of this study was to evaluate the effect of metal primers on the bonding of dental alloys and veneer resin. Polyvinylpyrrolidone solution's tarnish effect on bonding strength was also investigated. MATERIALS AND METHODS. Disk-shape metal specimens (diameter 8 mm, thickness 1.5 mm) were made from 3 kinds of alloy (Co-Cr, Ti and Au-Ag-Pd alloy) and divided into 4 groups per each alloy. Half specimens (n=12 per group) in tarnished group were immersed into polyvinylpyrrolidone solution for 24 hours. In Co-Cr and Ti-alloy, Alloy Primer (MDP + VBATDT) and MAC-Bond II (MAC-10) were applied, while Alloy Primer and V-Primer (VBATDT) were applied to Au-Ag-Pd alloys. After surface treatment, veneering composite resin were applied and shear bond strength test were conducted. RESULTS. Alloy Primer showed higher shear bond strength than MAC-Bond II in Co-Cr alloys and Au-Ag-Pd alloy (P<.05). However, in Ti alloy, there was no significant difference between Alloy Primer and MAC-Bond II. Tarnished Co-Cr and Au-Ag-Pd alloy surfaces presented significantly decreased shear bond strength. CONCLUSION. Combined use of MDP and VBATDT were effective in bonding of the resin to Co-Cr and Au-Ag-Pd alloy. Tarnish using polyvinylpyrrolidone solution negatively affected on the bonding of veneer resin to Co-Cr and Au-Ag-Pd alloys.

Effect of PVOH or polyDADMAC Addition on Surface Sizing with Oxidized Starch (PVOH와 polyDADMAC 첨가에 의한 산화전분의 표면사이징 효과 변화)

  • Seo, Dongil;Jeong, Young Bin;Jeong, Kwang Ho;Lee, Hak Lae;Youn, Hye Jung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.4
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    • pp.1-8
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    • 2013
  • High loading of printing and writing grades with fillers has many advantageous aspects in papermaking because it allows decreasing fiber use and reducing manufacturing cost. High loading technology, however, has some disadvantageous aspects as well. It decreases physical properties of papers, especially strength properties. The problem associated with high loading can be reduced by applying surface sizing starch solution onto paper surface. It is important to control the penetration of the surface sizing starch solution into paper web to obtain the desired property improvement. In this study, the effect of the addition of two polymers into starch solution on paper properties has been examined. PVOH and polyDADMAC were used as polymeric additives for surface sizing with oxidized starch. Viscosity of starch solutions and surface roughness of dried starch films on glass slides showed that some interactions between polymeric additives and oxidized starch have been occurred and the most extensive interaction with starch solution was obtained with high molecular weight polyDADMAC. Low molecular weight PVOH was most effective in improving folding endurance and internal bond strength. On the other hand, polymer addition showed no effect on surface strength of paper. This indicates that not the level of starch holdout but the bonding strength of starch itself has predominant influence on surface strength of paper.

Interfacial Electrical Studies on Adhesion of Hematite Particle to Polyester Fabric and its Removal from the Fabric(Part I) -The interaction energy between particle and fabric- (Polyester직물에의 Hematite입자의 부착과 제거에 관한 계면전기적 고찰(제1보) -기질과 입자간의 상호작용에너지-)

  • Kang, In-Sook;Kim, Sung-Reon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.17 no.3
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    • pp.380-390
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    • 1993
  • Effect of interfacial electrical conditions on adhesion of ${\alpha}-Fe_2O_3$ particles to PET fabric and the removal of ${\alpha}-Fe_2O_3$ particles from PET fabric, were investigated as functions of pH, electrolyte and ionic strength. The ${\zeta}$ potential of PET fiber and ${\alpha}-Fe_2O_3$ particles in the electrolyte solution were measured by streaming potential and microelectrophoresis methods respectively. The potential energy of interaction between ${\alpha}-Fe_2O_3$ particles and PET fabric were calculated by using the heterocoagulation theory for a sphere-plate model. The negative ${\zeta}$ potential of ${\alpha}-Fe_2O_3$ particle and PET fiber increased with pH, and then decreased certain pH and isoelectric points of ${\alpha}-Fe_2O_3$ particles and PET fiber were pH 6.5 and pH 3.5, respectively. The negative ${\zeta}$ potential of ${\alpha}-Fe_2O_3$ particle and PET fiber affected by electrolytes, were relatively high with polyanion electrolytes in solutions and were low with neutral salts. However, at surfactant solution, ${\zeta}$ potential was levelled off. The influence of the ionic strength on the ${\zeta}$ potential of ${\alpha}-Fe_2O_3$ particle was small but the negative ${\zeta}$ potential of PET fiber increased with the ionic strength. In the presence of anionic surfactant, the ${\zeta}$ potential of ${\alpha}-Fe_2O_3$ particle and PET fiber increased regardless of solution conditions. The interaction energy between ${\alpha}-Fe_2O_3$ particle and PET fabric increased with pH. The interaction energy was relatively high with polyanion electrolytes in solution, and the influence of ionic strength on the interaction energy was small, and the effective thickness of electrical double layer increased with decreasing the ionic strength.

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A Study on the Properties and Utilization of Chitosan Coating 1. Affecting Factors on the Rheological Properties of Chitosan Film as a Coating Agent (게껍질에서 추출한 chitosan 필름의 이용에 관한 연구 1. 도포재로써의 chitosan 물성에 영향을 미치는 인자)

  • SON Byung-Yil;PARK Seong-Min;KIM Hyonng-Seub;LEE Keun-Tai
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.32 no.4
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    • pp.395-398
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    • 1999
  • Chitin was isolated from red snow crab (Chinonecetes japonicus) and deacetylated by boiling alkaline solution to produce chitosan. The physical properties of chitosan solution and its film properties was examined, As the molecular weights of chitosan was increased from 297Kpa to 319Kpa, the tensile strength, degree of elongation and water permeability of chitosan film were increased. As the degree of deacetylation of chitosan was increased, the tensile strength, the degree of elongation and water permeability of chitosan film were increased. As the concentration of chitosan solution was increased, the degree of elongation and water permeability of film were increased, whereas the tensile strength of film was decreased, As the pH of chitosan solution was increased, the tensile strength and water permeability of film were decreased, whereas the degree of elongation of film was increased.

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Crack-healing Behavior and Corrosion Characteristics of SiC Ceramics (SiC 세라믹스의 균열치유거동 및 부식특성)

  • Hwang, Jin Ryang;Kim, Dae Woong;Nam, Ki Woo
    • Journal of Ocean Engineering and Technology
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    • v.27 no.5
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    • pp.10-15
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    • 2013
  • The crack-healing behavior and corrosion resistance of SiC ceramics were investigated. Heat treatments were carried out from $900^{\circ}C$ to $1300^{\circ}C$. A corrosion test of SiC was carried out in acid and alkaline solutions under KSL1607. The results showed that heat treatment in air could significantly increase the strength. The heat-treatment temperature has a profound influence on the extent of crack healing and the degree of strength recovery. The optimum heat-treatment temperature was $1100^{\circ}C$ for one hour at an atmospheric level. In the two kinds of solutions, the cracks in a specimen were reduced with increasing time, and the surface of the crack healed specimen had a greater number of black and white spots. The strength of the corroded cracked specimen was similar to that of the cracked specimen. The strength of the corroded crack healed specimen decreased 47% and 75% compared to that of the crack healed specimen in the acid and alkaline solutions, respectively. Therefore, the corrosion of SiC ceramics is faster in an alkaline solution than in an acid solution.

Mechanism of change in compressive strength of geopolymers by immersion method (침지방법에 따른 지오폴리머의 압축강도 변화 메커니즘)

  • Kim, Hakmin;Kim, Yootaek
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.32 no.2
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    • pp.68-76
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    • 2022
  • This study was performed to investigate the mechanism of the change in compressive strength of autoclave cured geopolymers. Specimens were immerged in distilled water, 2M, 8M, and 14M alkaline solutions for 3, 7, and 21 days. The change in the specimens immersed in a short period of time was not significant, but the compressive strength of the specimens immersed in the distilled water and 8M alkali solution) for 21 days increased more than twice as much as before immersion because of additional geopolymerization. However, compressive strength decreased due to the alkaline aggregate reaction when alkaline solution was supplied more than a certain level of concentration. Therefore, immersing the specimens for more than 21 days in the distilled water or 8M alkaline solution would be desirable for the improvement of compressive strength of autoclave cured specimens.

Hydration Properties of High Volume Cement Matrix Using Blast Furnace Slag and Alkaline Aqueous by Electrolysis (고로슬래그 및 전기분해한 알칼리 수용액을 사용한 하이볼륨 시멘트 경화체의 수화특성)

  • Kim, Sun-A;Park, Sun-Gyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.1
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    • pp.8-13
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    • 2017
  • This experimental study is purposed to analyze the effect of alkaline aqueous solution by electrolysis on strength development in order to develop high volume cement matrix using industrial by-products. Blast furnace slag was used a binder, and an alkaline aqueous solution obtained by electrolyzing pure water was used as an alkali activator. The hydration properties of these specimens were then investigated by compressive strength test, XRD and observation of micro-structures using SEM. As a result, we found that compressive strength increased with the addition of alkaline aqueous solution which cement matrix incorporating blast furnace slag. But those strength decreased reversely when replacing ratio of blast furnace slag was increased. It is judged that results of engineering properties evaluation on the binder and alkaline aqueous solution are useful as a basic data for mixtures design and evaluation properties of high volume cement matrix using by-products.

Effect of Immediate Setting with Lateral Branch Cuttings on Growth and Yield of Cherry Tomatoes in Soilless Culture (삽수 직접정식이 방울토마토 양액재배에 있어서 생육 및 수량에 미치는 영향)

  • 장전익;박용봉;지성한;양희준
    • Journal of Bio-Environment Control
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    • v.5 no.1
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    • pp.79-88
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    • 1996
  • The purpose of this research was to develop labor-saving cultural practices of cherry tomatoes in the deep flow technique (DFT) by omitting the process of raising seedling. Three cultivars, ‘Pepe’, ‘Pico’ and ‘Koko’ were propagated by the immediate setting of cuttings(lateral shoots) to the culture bed and by setting seedlings obtained by raising cuttings for 15 days, and grown in the standard and half - strength solution. 1. The immediate setting resulted in higher plants, larger number of leaves and larger leaf area during the early growth stage. And the harvest time was hastened by six days in the direct setting than that in the seedling setting. It was also earlier in ‘Pepe’, but not significant by different between two strengths of nutrient solution. 2. The average fruit weight was affected only by cultivars, but not by the type of cutting and the strength of nutrient solution. The highest yields were obtained from the immediate setting of ‘Pepe’ in other cultivars grown in the nutrient solution of standard strength. 3. Brix degree of treated cherry tomato juice was higher in ‘Pepe’ tomato cultured by immediate setting than others.

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Study on the Durability of GFRP Composites in Alkaline Environment(1) (알칼리 환경에 대한 GFRP 복합재료의 내구성에 관한 연구(1))

  • Moon, Yong-Jae;Park, Chang-Ho;Moon, Chang-Kwon
    • Journal of Ocean Engineering and Technology
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    • v.22 no.1
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    • pp.58-63
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    • 2008
  • The effect of alkaline environmental condition on durability of GFRP composites according to additives was investigated. Additives used were polyvinyl alcohol(PVA), kaolin and alumina powder. Weight gains increased with immersion time in all GFRP composites at $80^{\circ}C$. But weight gain of specimen added PVA did not differ through the wlwle immersion time in both tap water and alkaline solution at 20 and $80^{\circ}C$. Tensile strength decreased with immersion time in all environment conditions. Tensile strength of GFRP composites regardless of additives decreased rapidly up to 5 days of immersion and then decreased slowly up to 30 days in alkaline solution environment at $80^{\circ}C$. Weight gains had not. much difference in both tap water and alkaline solution at $20^{\circ}C$. And weight gain of GFRP composites added polyvinyl alcohol had smaller than the others through the whole immersion time in both tap water and alkaline solution at $20^{\circ}C$ and $80^{\circ}C$. Tensile strength of GFRP composites added polyvinyl alcohol had higher than the others through the whole immersion time in both tap water and alkaline solution at $20^{\circ}C$ and $80^{\circ}C$.

SHEAR BOND STRENGTH OF ORTHODONTIC BONDING RESINS TO PORCELAIN; AN IN VITRO STUDY (도재에 대한 교정용 브라켓 접착 레진의 전단접착강도에 관한 연구)

  • Ko, Jin-Hwan;Lee, Ki-Soo
    • The korean journal of orthodontics
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    • v.22 no.1
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    • pp.43-65
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    • 1992
  • Bonding orthodontic adhesive resins to glazed porcelain surface is not attainable. The aim of this investigation was to examine, in vitro, the effect of three methods of porcelain surface pretreatment on the shear bond strength of orthodontic adhesives, and to compare the shear strength of orthodontic bracket bonding to porcelain surface by the best results that to human enamel. Porcelain disks ($Ceramco^{(TM)}$ and $Vita^{(TM)}$) baked in the laboratory were roughened by sandpapers, #320, #600, #800, #1000 and #1200, and were pretreated with silane and dried at the various temperatures, room temperature, $50^{\circ}C$, $70^{\circ}C$ and $90^{\circ}C$, and were etched by 3% hydrofluoric acid solution for 1, 3, 5, 7, and 9 minutes, orthodontic adhesives (System $1+^{(TM)}$ and $Unite^{(TM)}$) were applied on them, and shear bond strengths were measured by Instron. The best results of pretreatment of each method were determined by the shear bond strengths. Again, porcelain disks were pretreated by the determined best results and human enamel were etched by 37% hydrofluoric acid solution, orthodontic brackets were bonded on them by the orthodontic adhesives, and the shear bond strengths were measured and compared between them. 1. Roughening porcelain surfaces with coarse sandpaper (#300) showed higher shear bond strength than that with finer sandpapers, but it $(22.44Kgf/cm^2)$ was distinguishably low compared to that from etched human enamel $(144.11Kgf/cm^2)$. 2. There were disparities in shear bond strengths upon the orthodontic resins, which was presumably related to the contents of fillers in orthodontic adhesive resins. Also there were disparities in shear bond strength upon the porcelains which had different composition. 3. Silane enhanced the shear bond strength of orthodontic resins to porcelain surfaces ($25.20Kgf/cm^2$ at $50^{\circ}C$), which was markedly low compared to that from etched human enamel. 4. Etched porcelain surface with 3% hydrofluoric acid solution for 1 to 9 minutes showed no difference in shear bonding strength of orthodontic adhesive resins. Shear bond strength from etched porcelain $(97.43-120.72Kgf/cm^2)$ were as high as clinically available, but low compared to that from etched human enamel. 5. Roughening with #300 sandpaper and etching by 3% hydrofluoric acid followed silane application on porcelain surface showed lower shear bond strength than etched human enamel, but were as high as clinically useful. 6. The results suggest that etching porcelain surface by 3% hydrofluoric acid solution might provide comparatively high shear bond strength as much as clinically favorable.

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