• Title/Summary/Keyword: solution resistance

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Resistance of Alkali Activated Slag Cement Mortar to Sulfuric Acid Attack (알칼리 활성화 슬래그 시멘트 모르타르의 내황산성)

  • Min, Kyung-San;Lee, Seung-Heun
    • Journal of the Korean Ceramic Society
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    • v.44 no.11
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    • pp.633-638
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    • 2007
  • The setting time of alkali activated slag cement tends to be much faster than ordinary Portland cement, and its compressive strength had been higher from the 1 day but became lower than that of the cement on the 28 days. According to the results of the surface observation, weight loss, compressed strength, and erosion depth tests on the sulphuric acid solution. It has been drawn that alkali activated slag cement has a higher sulphate resistance than ordinary Portland cement, and in particular, the alkali activated slag cement added 5 wt% alumina cement has little deterioration on the sulphuric acid solution. The reason why the alkali activated slag cement has higher sulphate resistance than other hardened cement pastes is that it has no $Ca(OH)_2$ reactive to sulphate ion, and there is little $CaSO_4{\cdot}2H_2O$ production causing volume expansion, unlike other pastes. And it is supposed that $Al(OH)_3$ hydrates with high sulphate resistance, which is produced by adding the alumina cement increases the sulfate resistance.

Distribution and Preservative Effectiveness of Resin Element in Pine Wood Impregnated with Monoethylene Glycol Resin Solution (Monoethylene Glycol계(系) 수지액(收支液)을 주입(注入)한 소나무재(材)에 있어서 수지성분(樹脂成分)의 분포(分布)와 방부효과(防腐效果))

  • Lee, Jong-Shin
    • Journal of the Korean Wood Science and Technology
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    • v.23 no.2
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    • pp.77-82
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    • 1995
  • With the aim to utilize pine wood(Pinus densiflora Sieb. et Zucc.) as an interior building materials, such as flooring material, monoethylene glycol(MEG) resin solution was impregnated into greenwood. Specimens of three different qualities, that is, normal wood, resinous wood and compression wood, were prepared. Distribution of resin element(phosphorus) in MEG resin solution-impregnated woods and preservative effectiveness against brown rot fungi(Tyromyces palustris and Serpula lacrymans) of these woods were investigated. The results were as follows: 1. The concentration of phosphorus into cell walls of resinous wood and compression wood was lower compared to that of normal wood. This shows that the quality of wood has an influence on the penetration of MEG resin solution into the wood. It was shown from a leaching test that MEG resin could be leached out easily from the cell walls. 2. The resinous wood and compression wood, even without MEG resin solution impregnation had high decay resistance. For normal wood, significant improvement of preservative effectiveness was observed after impregnation of MEG resin solution. It was shown that MEG resin was leached out from the woods after leaching test, resulting in the reduction of preservative effectiveness. From this result, suitability of MEG resin solution-impregnated woods as an interior materials was recognized.

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An Experimental Study on the Resistance of Low-Heat Cement Mortar in Chemical Attack (저발열시멘트 모르터의 호학저항성에 대한 실험적 연구)

  • 문한영;신화철;김성수;강석화
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.04a
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    • pp.183-186
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    • 1998
  • This paper deals with 28, 56, 91 days age compressive strength and ratio of weight when OPC and Low-Heat cement mortar immersed in chemical solution. As a result of experiment, the resistance of Low-Heat Cement motar in chemical attack is more effective than that of OPC, because of lower $C_3$A content and Pozzolanic reactions. Especially in long term age compressive strength, Low-Heat cement mortar shows higher strength in all kind of chemical solution compared with compressive strength of OPC motar.

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Heat Transfer Analysis of Freezing Processes Including Thermal Resistance of Mold(I) - One - dimensional Analysis of Saturated Liquid - (용기를 고려한 응고과정의 열전달 해석(I) - 포화액의 일차원 해석 -)

  • Yoo, Jai Suk
    • The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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    • v.17 no.4
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    • pp.377-381
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    • 1988
  • Effects of thermal resistance of mold during freezing processes have been investigated. Saturated liquid is chosen to present one-dimensional quasi-steady solution and this solution is compared with numerical solutions. Front tracking finite element method has been applied for the numerical solutions. Results show that mold should be considered as well as phase change material except the cases when the very thin mold with relatively high thermal conductivity is used.

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The Effect of Temperature on Corrosion of Absorption Refrigeration Systems Using $LiBr-H_2O$ Working Fluids ($LiBr-H_2O$계 흡수식냉동기의 부식에 미치는 온도의 영향)

  • 임우조;정기철
    • Journal of Advanced Marine Engineering and Technology
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    • v.26 no.1
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    • pp.125-131
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    • 2002
  • This paper was studied on the effect of temperature on corrosion of absorption refrigeration systems using $LiBr-H_2O$ working fluids. In the fresh water and 62 % lithium bromide solution at $70^{\circ}C$, polarization test of SS 400, Cu(C1220T-OL) and Al-Ni bronze was carried out. And polarization behavior, polarization resistance characteristics, corrosion rate(mmpy) and corrosion sensitivity of materials forming absorption refrigeration systems was considered. The main results are as following: (1) As the experimental temperature increase, the change of corrosion rate of Al-Ni bronze become duller than SS 400 and Cu in 62% lithium bromide solution. (2) According as corrosion environment is changed from fresh water to 62% lithium bromide solution, potential change of Cu and Al-Ni bronze become less noble than SS 400. (3) The corrosion sensitivity of Al-Ni bronze was duller than that of Cu and SS 400 in 62% LiBr solution.

Corrosion Behavior of Rapidly Solidified Mg-Zn-Y Alloys in NaCl Solution

  • Izumi, Shogo;Yamasaki, Michiaki;Sekigawa, Takahiro;Kawamura, Yoshihito
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1043-1044
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    • 2006
  • Compositional dependence of corrosion behavior of rapidly solidified Mg-rich Mg-Zn-Y alloys in NaCl aqueous solution has been investigated. Mg-Zn-Y ternary alloys containing small amounts of Zn exhibited low corrosion rate, although the $Mg_{98}Y_2$ (at. %) binary alloy showed severe corrosion with violet evolution of hydrogen. The alloy with highest corrosion-resistance was $Mg_{97.25}Zn_{0.75_Y_2$, its corrosion rate was about 1 mm year-1 in 0.17 M (1.0 wt. %) NaCl solution. $Mg_{97.25}Zn_{0.75}Y_2$ alloy exhibited passive region in anodic polarization curves when immersed in NaCl solution. Rapidly solidification and small amount of Zn addition may bring about an increase in electrochemical homogeneity of Mg-Zn-Y alloys, resulting in enhancement of corrosion resistance.

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Magnetite film on iron (강재의 마그네타이트 피복에 관한 연구)

  • Kim, H. G.;Kang, T.
    • Journal of Surface Science and Engineering
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    • v.25 no.2
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    • pp.66-72
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    • 1992
  • Magnetite film on iron surface could be coated in strongly alkaline solution (12M NaH\OH) which contained additives such as NaHCO3, KCl and NaNO2, Iron plate was immersed in boiling solution ($130^{\circ}C$) contained above mentioned additives for 1 hour. There are some microcracks and these cracks proved to be the sites for the initiation of corrosion when immersed in 3% NaCl solution. To improve corrosion resistance of the coated steel plate, chromating was done as a post treatment. Chromate film was formed on magnetite oxide film potentiostatically at-918mV/SCE for five minutes at temperature of $70^{\circ}C$ in the alkaline solution containing 5g/l Na2Cr2O7.2H2O.Cr3O4 was electrodeposited on magnetite oxide film and Cr2O3 was electrodeposited on iron surface which was assumed as surface revealed due to microcracks. Increased corrosion resistance of chromated magnetite oxide film was proved in salt spray test & immersion test.

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Stability Tests on Anion Exchange Membrane Water Electrolyzer under On-Off Cycling with Continuous Solution Feeding

  • Niaz, Atif Khan;Lim, Hyung-Tae
    • Journal of Electrochemical Science and Technology
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    • v.13 no.3
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    • pp.369-376
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    • 2022
  • In this study, the stability of an anion exchange membrane water electrolyzer (AEMWE) cell was evaluated in an on-off cycling operation with respect to an applied electric bias, i.e., a current density of 500 mA cm-2, and an open circuit. The ohmic and polarization resistances of the system were monitored during operation (~800 h) using electrochemical impedance spectra. Specific consideration was given to the ohmic resistance of the cell, especially that of the membrane under on-off cycling conditions, by consistently feeding the cell with KOH solution. Owing to an excess feed solution, a momentary increase in the polarization resistance was observed immediately after the open-circuit. The excess feed solution was mostly recovered by subjecting the cell to the applied electric bias. Stability tests on the AEMWE cell under on-off cycling with continuous feeding even under an open circuit can guarantee long-term stability by avoiding an irreversible increase in ohmic and polarization resistances.

Solution of yielding steel arch supports used in mining

  • Lenka Koubova
    • Steel and Composite Structures
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    • v.51 no.5
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    • pp.575-586
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    • 2024
  • Steel arch supports are used in mines and underground structures to provide stability. Most of the supports are made up of overlapping arches. They can behave either yieldingly or unyieldingly. If the normal force at any point of overlapping equals the slip resistance, the slide occurs. This paper presents a solution procedure for determining the load-carrying capacity of steel arch supports in the yielding implementation. This solution considers the effects of several significant elements, including differing materials and the number of clamps in yielding friction joints. The direct stiffness method is applied. The solution contains geometric, physical, and structural nonlinearity. The results obtained from numerical modeling using the provided procedure are compared to laboratory tests conducted at GIG Katowice in 2012. They show a good correlation with previously collected data from equivalent laboratory conditions.

Research on the Solution and Properties of Ni-P/n-$Al_2O_3$ Electroless Composite Plating

  • Huang, Yan-bin;Liu, Fei-fei;Zhang, Qi-yong;Ba, Guo-zhao;Liang, Zhi-jie
    • Corrosion Science and Technology
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    • v.6 no.5
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    • pp.257-260
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    • 2007
  • In order to further improve the corrosion resistance and wear resistance of the Ni-P coatings of electroless plating, electroless Ni-P/n-$Al_2O_3$ composite deposits were prepared by adding some nano $Al_2O_3$ Particles in Ni-P plating bath. The bath composition and proproties were studied in this paper. The orthogonal test was applied in order to get the new composite solution, taking the initial stable potential as evaluation standard and considering the elements correlation at the same time. The processing parameters have been optimized by single factor experiment in which the depositing speed was chosen as the evaluation standard. The results showed that the process is stable and the composite Ni-P/n-$Al_2O_3$ deposits werebright and smooth, whose hardness and corrosion resistance are much better than simple Ni-P coatings. Furthermore the surface appearance and structure of the composite Ni-P/n-$Al_2O_3$ coating were investigated by SEM and XRD method. It was proved that the coating surface is typical cystiform cells and its structure is amorphous. All test results ofcomposite coating showed that all various physical coating properties had been improved by adding nano-particles. The hardness of optimal coating is more than 600HV and increases to 1000HV after heat-treating, and its hardness is 20~50% higher than Ni-P coating. The rust points appeared in 200 hour by immersing the coating into the 10%HCl solution and the corrosive speed is $3{\times}10^{-3}mg/(cm^2{\cdot}h)$which was obtained after 300 hour. In the same condition Ni-P coating is $5.6{\times}10^{-3}mg/(cm^2{\cdot}h)$. The salt spray resistance of the layers can exceed 600h with the thickness $20{\mu}m$.