• 한국분말재료학회지
• /
• 제16권3호
• /
• pp.191-195
• /
• 2009

The calcination and hydrogen-reduction behavior of Fe- and Ni-nitrate have been investigated. $Fe_2O_3$/NiO composite powders were prepared by chemical solution mixing of Fe- and Ni-nitrate and calcination at $350^{\circ}C$ for 2 h. The calcined powders were hydrogen-reduced at $350^{\circ}C$ for 30 min. The calcination and hydrogen-reduction behavior of Fe- and Ni-nitrate were analyzed by TG in air and hydrogen atmosphere, respectively. TG and XRD analysis for hydrogen-reduced powders revealed that the $Fe_2O_3$/NiO phase transformed to $FeNi_3$ phase at the temperature of $350^{\circ}$. The activation energy for the hydrogen reduction, evaluated by Kissinger method, was measured as 83.0 kJ/mol.

• Korea-Australia Rheology Journal
• /
• 제16권3호
• /
• pp.153-160
• /
• 2004

Open microcellular foams having small-sized cell and good mechanical properties are desirable for many practical applications. As an effort to reduce the cell size, the microcellular foams combining viscosity improvers into the conventional formulation of styrene and water system were prepared via high internal phase emulsion polymerization. Since the material properties of foam are closely related to the solution properties of emulsion state before polymerization, the flow behavior of emulsions was investigated using a controlled stress rheometer. The yield stress and the storage modulus increased as viscosity improver concentration and agitation speed increased, due to the reduced cell size reflecting both a competition between the continuous phase viscosity and the viscosity ratio and an increase of shear force. Appreciable tendency was found between the rheological data of emulsions and the cell sizes of polymerized foams. Cell size reduction with the concentration of viscosity improver could be explained by the relation between capillary number and viscosity ratio. A correlative study for the cell size reduction with agitation speed was also attempted and the result was in a good accordance with the hydrodynamic theory.

• International Journal of Air-Conditioning and Refrigeration
• /
• 제6권
• /
• pp.56-66
• /
• 1998

The absorption process of water vapor in a liquid film is an important process in LiBr-Water absorption system. The composition of the gas phase, in which a non-absorbable gas is combined with the absorbate, influences the transport characteristics. In the present work, the absorption processes of water vapor into aqueous solutions of lithium bromide in the presence of non-absorbable gas are investigated. The continuity, momentum, energy and diffusion equations for the solution film and gas are formulated in integral forms and solved numerically. It is found that the mass transfer resistance in gas phase increases with the concentration of non-absorbable gas. However the primary resistance to mass transfer is in the liquid phase. As the concentration of non-absorbable gas in the absorbate increases, the interfacial temperature and concentration of absorbate in solution decrease, which results in the reduction of absorption rate. The reduction of mass transfer rate is found to be significant for the addition of a small amount of non-absorbable gas to the pure vapor, especially at the outlet of tube where the non-absorbable gas accumulates. At higher non-absorbable gas concentration, the decrease of absorption rate seems to be linear to the concentration of non-absorbable gas.

• 한국지하수토양환경학회지:지하수토양환경
• /
• 제16권6호
• /
• pp.58-65
• /
• 2011

The bacterial uranium(VI) reduction and its resultant low solubility make this process an attractive option for removing U from groundwater. An impact of aqueous suspending iron phase, which is redox sensitive and ubiquitous in subsurface groundwater, on the U(VI) bioreduction by Shewanella putrefaciens CN32 was investigated. In our batch experiment, the U(VI) concentration ($5{\times}10^5M$) gradually decreased to a non-detectable level during the microbial respiration. However, when Fe(III) phase was suspended in solution, bioreduction of U(VI) was significantly suppressed due to a preferred reduction of Fe(III) instead of U(VI). This shows that the suspending amorphous Fe(III) phase can be a strong inhibitor to the U(VI) bioreduction. On the contrary, when iron was present as a soluble Fe(II) in the solution, the U(VI) removal was largely enhanced. The microbially-catalyzed U(VI) reduction resulted in an accumulation of solid-type U particles in and around the cells. Electron elemental investigations for the precipitates show that some background cations such as Ca and P were favorably coprecipitated with U. This implies that aqueous U tends to be stabilized by complexing with Ca or P ions, which easily diffuse and coprecipitate with U in and around the microbial cell.

• 설비공학논문집
• /
• 제13권12호
• /
• pp.1275-1281
• /
• 2001

Aqueous polymer solutions are known to have small pressure reduction. Paraffin slurries are known to have high thermal capacity. Paraffin particles are mixed into an aqueous polymer solution to make a new heat transfer fluid having high thermal capacity but low pressure reduction. The heat transfer characteristics of the new slurry was tested in a circular tube having a constant heat transfer boundary condition. The new slurry was found to have high Nusselt numbers as well as high thermal capacity and low pressure reduction in the laminar flow. The trends of the Nusselt numbers along the heating test section were studied for various heating conditions.

• Journal of Ceramic Processing Research
• /
• 제13권spc1호
• /
• pp.110-113
• /
• 2012

Ge-S and Li-Ge-S powders were synthesized via solution-based process in order to employ chalcogenide-based solid electrolyte for use in Li secondary batteries. GeCl4 and thioacetamide in combination result in Ge-S powders of which major crystalline phase becomes GeS2 where the tetragonal and orthorhombic phases coexist after heat treatment. A chemical treatment using NaOH brings about the reduction of chlorine in the powders obtained. However, the heat treatment at 300 ℃ is more effective in minimizing the chlorine content. When lithium chloride is used as the precursor of Li ions, the LiCl powders are agglomerated with an inhomogeneous distribution. When Li2S is used, the Li-Ge-S powders are distributed more uniformly and the orthorhombic GeS2 phase dominates in the powders.

• 한국재료학회지
• /
• 제33권3호
• /
• pp.95-100
• /
• 2023

This research examines the effect of adding aluminum on the structural, phasic, and magnetic properties of CoCrFe NiMnAl_x high-entropy alloys. To this aim, the arc-melt process was used under an argon atmosphere for preparing cast samples. The phasic, structural, and magnetic properties of the samples were characterized by x-ray diffraction (XRD), scanning electron microscopy (SEM), and vibrational magnetometry (VSM) analyses. Based on the results, the addition of aluminum to the compound caused changes in the crystalline structure, from FCC solid solution in the CoCrFeNiMn sample to CoCrFeNiMnAl BBC solid solution. It was associated with changes in the magnetic property of CoCrFeNiMnAl_x high-entropy alloys, from paramagnetic to ferromagnetic. The maximum saturation magnetization for the CoCrFeNiMnAl casting sample was estimated to be around 79 emu/g. Despite the phase stability of the FCC solid solution with temperature, the solid solution phase formed in the CrCrFeNiMnAl high-entropy compound was not stable, and changed into FCC solid solution with temperature elevation, causing a reduction in saturation magnetization to about 7 emu/g.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
• /
• pp.242-243
• /
• 2005

In this study, (La,Sr)$MnO_{3+\delta}$ powder used cathode material for SOFC was synthesized with precursor by GNP and the properties of powder, crystal phase, electric properties and deoxidization properties with precursor were investigated. The synthesis powder was prepared when oxidant/fuel mole and pH were 1 and 1, respectively and the synthesis powder was synthesized by GNP method using nitrate solution or oxide solution as precursor. Deoxidization peak of the nitrate solution was appeared lower temperature than the oxide solution, at $450^{\circ}C$. In this result, synthesis (La,Sr)$MnO_{3+\delta}$ powder using nitrate solution with Mn excess was suitable cathode material for SOFC due to had higher deoxidization properties. Also synthesis (La,Sr)$MnO_{3+\delta}$ powder according to precursor had difference electrical conductivity according to influence sintering density and crystal phase with precursor. Specially, the synthesis method and starting material had effect on deoxidization properties for SOFC.

• 한국표면공학회지
• /
• 제41권4호
• /
• pp.174-179
• /
• 2008

Nanosize tungsten powder was synthesized by ultrasonic spray pyrolysis method through a solution containing ammonium metatungstate hydrate $[(NH_4)_6W_{12}O_{39}{\cdot}H_2O]$ and reduction treatment. It was expected the improvement of mechanical properties due to increasing surface free energy and surface activity. Starting solutions with each concentration, reaction temperature and reduction treatment were significantly influenced on the formation of tungsten size and phase. It was found that particle size was decreased with concentration of starting solution and surface tension were decreased. The particle size was increased at thermal decomposition temperature above $600^{\circ}C$ by neck growth of interparticles. Tungsten particles were formed by reduction reaction in atmosphere of hydrogen gas at the temperature above $700^{\circ}C$.

• 전기학회논문지
• /
• 제66권7호
• /
• pp.1039-1046
• /
• 2017

Campus microgrid is designed and built by considering not only power generation but also power consumption management as connected microgrid type because the main goal of the campus microgrid is to save power consumption costs. There are many functions to achieve the goal and they are mainly to use generation-based functions such as islanding operation for peak management and for emergency events. In power distribution operation, Conservation Voltage Reduction (CVR) is applied in order to reduce power consumption. The CVR is defined as a function for load consumption reduction by voltage reduction in order to reduce peak demands and energy consumption. However, application of CVR to microgrid is difficult because the microgrid cannot control a tap of transformer in a substation and the microgrid normally is not designed with phase modifying equipment like a step-voltage-regulator which can control voltage in power distribution system operation. In addition, an impact of the CVR is depended on load characteristics such as a normal load, a rated power, and synchronous motors. Therefore, this paper proposes an application of CVR using linear voltage control based AVR in campus microgrid with power consumption reduction considering characteristics of load and component in the microgrid. The proposed system can be applied to each buildings by a configuration of power distribution cables; and the application results and CVR factor are presented in this paper.