• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.2 no.2
• /
• pp.77-82
• /
• 1992

When a crystal is grown by FZ process, the melt zone is located at between the solid of upper and lower side and is kept by the solid-liquid interface tension. On the surface of the melt zone, a surface tension gradient is occured by the difference of temperature and solute concentration, it is the driving force of marangoni flow. The crystal even in the steady state growth can become imperfect for the dislocation distribution and the solute concentration in the peripheral region of the crystal are higher than those in the inner part and the probability of the formation of the defects such as voids, bubble penetration, secondary phase creation and crack is high near the solid-liquid interface. This is because the solid -liquid interface becomes irregular because of the local variation of temperature in that region due to marangoni convection.

• Membrane and Water Treatment
• /
• v.13 no.2
• /
• pp.63-72
• /
• 2022

Choline chloride-glycerol (1:2 mol), a natural deep eutectic solvent (NADES) is examined as a draw solution in forward osmosis (FO) for dewatering application. The NADES is easy to prepare, low in toxicity and environmentally benign. A polyamide thin film composite membrane was used. Characterization of the membrane confirmed porous membrane structure with good hydrophilicity and a low structural parameter (722 ㎛) suitable for FO application. A dilute solution of 20% (v/v) NADES was enough to generate moderate water flux (14.98 L m^-2h^-1) with relatively low reverse solute flux (0.125 g m^-2h^-1) with deionized water feed. Application in dewatering industrial wastewater feed showed reasonably good water flux (11.9 L m^-2h^-1) which could be maintained by controlling the external concentration polarization and fouling/scaling mitigation via simple periodic deionized water wash. In another application, clarified sugarcane juice could be successfully concentrated. Recovery of the draw solute was accomplished easily by chilling utilizing thermo responsive phase transition property of NADES. This study established that low concentration NADES can be a viable alternative as a draw solute for dewatering of wastewater and other heat sensitive applications along with a simple recovery process.

• Economic and Environmental Geology
• /
• v.29 no.6
• /
• pp.713-724
• /
• 1996

The time-series resident solute concentrations, monitored at two field plots using the automated 144-channel TDR system by Kim (this issue), are used to investigate the dominant transport mechanism at field scale. Two models, based on contradictory assumptions for describing the solute transport in the vadose zone, are fitted to the measured mean breakthrough curves (BTCs): the deterministic one-dimensional convection-dispersion model (CDE) and the stochastic-convective lognormal transfer function model (CLT). In addition, moment analysis has been performed using the probability density functions (pdfs) of the travel time of resident concentration. Results of moment analysis have shown that the first and second time moments of resident pdf are larger than those of flux pdf. Based on the time moments, expressed in function of model parameters, variance and dispersion of resident solute travel times are derived. The relationship between variance or dispersion of solute travel time and depth has been found to be identical for both the time-series flux and resident concentrations. Based on these relationships, the two models have been tested. However, due to the significant variations of transport properties across depth, the test has led to unreliable results. Consequently, the model performance has been evaluated based on predictability of the time-series resident BTCs at other depths after calibration at the first depth. The evaluation of model predictability has resulted in a clear conclusion that for both experimental sites the CLT model gives more accurate prediction than the CDE model. This suggests that solute transport at natural field soils is more likely governed by a stream tube model concept with correlated flow than a complete mixing model. Poor prediction of CDE model is attributed to the underestimation of solute spreading and thus resulting in an overprediction of peak concentration.

• Proceedings of the Korean Society for Food Science of Animal Resources Conference
• /
• 2005.05a
• /
• pp.297-302
• /
• 2005

Physicochemical properties were compared between freeze concentrated and vacuum evaporated milk through colour, brix, viscosity, freezing point and pH measurement. Brix and viscosity in each concentrated milk significantly increased due to solute concentration(p<0.05), and there was not much difference between freeze concentrated and evaporative one. Brix results were numerically modeled with the logarithmic regression: Y=-33.460+18.4513 ${\cdot}$ ln(X), $R^2=0.9798$ and this model was fairly fit to predict the solute concentration in the middle of freeze concentration process. Freezing point significantly decreased according to concentration increment(p<0.05) and there was not the significant difference between freeze concentrated and evaporated one. Whereas, in colour and pH value, there were some differences between freeze concentrated and evaporative milk. Vacuum evaporated milk expressed higher discoloration comparing to freeze concentrated one. In pH values, evaporated milk showed the significantly decreased results comparing to freeze concentrated sample, whereas the pH value of freeze concentrated sample expressed the similar value to the reference milk.

• Membrane and Water Treatment
• /
• v.8 no.5
• /
• pp.411-421
• /
• 2017

Forward osmosis (FO) is an emerging technology which can possibly make the desalination process more cost and energy efficient. One of the major factors impeding its growth is the lack of an appropriate draw solute. The present study deals with the identification of potential draw solutes, and rank them. The comparison was carried out among ten draw solutes on the basis of four main parameters namely; water flux, reverse salt diffusion, flux recovery and cost. Each draw solute was given three 24 hour runs; corresponding to three different concentrations; and their flux and reverse salt diffusion values were calculated. A fresh membrane was used every time except for the fourth time which was the flux recovery experiment conducted for the lowest concentration and the change of flux and reverse salt diffusion values from the initial run was noted. The organic solutes inspected were urea and tartaric acid which showed appreciable values in other parameters viz. reverse salt diffusion, flux recovery and cost although they generated a lower flux. They ranked 5th and 8th respectively. All the experimented draw solutes were ranked based on their values corresponding to each of the four main parameters chosen for comparison and Ammonium sulfate was found to be the best draw solute.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.20 no.4
• /
• pp.1437-1448
• /
• 1996

This paper presents a simplified model for approximate analysis of the solute redistribution in coarsening dendrite arms during solidification of binary metal alloys. By introducing a quadratic concentration profile with a time-dependent coefficient, the integral equation for diffusion in the solid phase is reduced to a simple differential relation between the coefficient and the solid-liquid interface position. The solid fraction corresponding to the system temperature is readily determined from the relation, phase equilibrium and the overall solute balance in which the liquid phase is assumed to be completely mixed. In order to validate the developed model, calculations are performed for the directional solidification of Al-4.9 mass Cu alloy. The predicted eutectic fractions for a wide range of the cooling rate reasonably agree with data from the well-known experiment as well as sophisticated numerical analyses. Also, the results for the back diffusion limits are consistent with available references. Additional calculations show that the characteristic parameters such as the coarsening, density variation and nonlinarity in the phase diagram significantly affect the microsegregation. Owing to the simplicity, efficiency and compatibility, the present model may be suitable for the micro-macroscopic solidification model as a microscopic component.

• 한국전산유체공학회:학술대회논문집
• /
• 2001.10a
• /
• pp.112-117
• /
• 2001

A numerical investigation is made of unsteady double-diffusive convection of a Boussinesq fluid in a rectangular cavity subject to time-periodic thermal excitations. The fluid is initially stratified between the top endwall of low solute concentration and the bottom endwall of high solute concentration. A time-dependent heat flux varying in a square wave fashion, is applied on one sidewall to induce buoyant convection. The influences of the imposed periodicity on double-diffusive convection are scrutinized. A special concern is on the occurrence of resonance that the fluctuations of flow and attendant heat and mass transfers are mostly amplified at certain eigenmodes of the fluid system. Numerical solutions are analyzed to illustrate the characteristic features of resonant convection.

• Journal of computational fluids engineering
• /
• v.7 no.1
• /
• pp.36-43
• /
• 2002

A numerical investigation is made of unsteady double-diffusive convection of a Boussinesq fluid in a rectangular cavity subject to time-periodic thermal excitations. The fluid is initially stratified between the top endwall of low solute concentration and the bottom endwall of high solute concentration. A time-dependent heat flux varying in a square wave fashion, is applied on one sidewall to induce buoyant convection. The influences of the imposed periodicity on double-diffusive convection are examined. A special concern is on the occurrence of resonance that the fluctuations of flow and attendant heat and mass transfers are mostly amplified at certain eigenmodes of the fluid system. Numerical solutions illustrate that resonant convection results in a conspicuous enhancement of time-mean mass transfer rate.

• Korean Chemical Engineering Research
• /
• v.56 no.5
• /
• pp.679-686
• /
• 2018

Reverse osmosis (RO) concentration of sodium chloride, sodium acetate, and sodium citrate solutions has been performed by polyamide RO membrane. Concentration polarization phenomena was also studied by changing pressure, solute kinds, and initial solution concentration. Pressure effect on permeation flux was that the increase of flux was accompanied by the increase of pressure. Flux increase was observed by the decrease of initial solution concentration. Surface concentration on the RO membrane increases and so flux declines due to the concentration polarization. In the later phase of concentration, concentration polarization effect was decreased by the back diffusion of solute from the polariztion layer. In case of sodium citrate, its large ion size and charge density resulted in the discrepancy between theory and experimental data of concentration polarization. It may be due to electric repulsion on the membrane surface.

• Journal of Soil and Groundwater Environment
• /
• v.8 no.3
• /
• pp.1-7
• /
• 2003

A modified model was developed for solute transport in porous media that can consider the movement of an LNAPL above the water table. From the results of sensitivity analyses with and without considering LNAPL movement, there are some differences according to the hydraulic gradient, the quantity of oil leakage and dispersivity. The mean deviation between the model in this study and a conventional model without LNAPL movement increases as the hydraulic gradient decreases and the quantity of oil leakage increases. Variation of dispersivity has no influence on the magnitude of the mean deviation. However, the spatial distribution of the deviation between the two models is wider as dispersivity increases. Furthermore, groundwater is at high risk of contamination in the vertical direction in the case that transverse dispersion value is large. A conventional model underestimates the concentration of solute in an aquifer where the movement of an LNAPL cannot be negligible: Based on the study results, it is important to understand how fast the LNAPL moves on the water table for realistic prediction of solute transport in an aquifer with the movable LNAPL on the water table.