• Title/Summary/Keyword: solute

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Ranking and comparison of draw solutes in a forward osmosis process

  • Sudeeptha, G.;Thalla, Arun Kumar
    • Membrane and Water Treatment
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    • v.8 no.5
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    • pp.411-421
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    • 2017
  • Forward osmosis (FO) is an emerging technology which can possibly make the desalination process more cost and energy efficient. One of the major factors impeding its growth is the lack of an appropriate draw solute. The present study deals with the identification of potential draw solutes, and rank them. The comparison was carried out among ten draw solutes on the basis of four main parameters namely; water flux, reverse salt diffusion, flux recovery and cost. Each draw solute was given three 24 hour runs; corresponding to three different concentrations; and their flux and reverse salt diffusion values were calculated. A fresh membrane was used every time except for the fourth time which was the flux recovery experiment conducted for the lowest concentration and the change of flux and reverse salt diffusion values from the initial run was noted. The organic solutes inspected were urea and tartaric acid which showed appreciable values in other parameters viz. reverse salt diffusion, flux recovery and cost although they generated a lower flux. They ranked 5th and 8th respectively. All the experimented draw solutes were ranked based on their values corresponding to each of the four main parameters chosen for comparison and Ammonium sulfate was found to be the best draw solute.

Analysis on the solute redistribution in coarsening dendrite arms during solidification of binary metal alloys (수지상가지의 조대화를 고려한 이원합금의 응고과정동안 용질 재분배 해석)

  • Yu, Ho-Seon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.4
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    • pp.1437-1448
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    • 1996
  • This paper presents a simplified model for approximate analysis of the solute redistribution in coarsening dendrite arms during solidification of binary metal alloys. By introducing a quadratic concentration profile with a time-dependent coefficient, the integral equation for diffusion in the solid phase is reduced to a simple differential relation between the coefficient and the solid-liquid interface position. The solid fraction corresponding to the system temperature is readily determined from the relation, phase equilibrium and the overall solute balance in which the liquid phase is assumed to be completely mixed. In order to validate the developed model, calculations are performed for the directional solidification of Al-4.9 mass Cu alloy. The predicted eutectic fractions for a wide range of the cooling rate reasonably agree with data from the well-known experiment as well as sophisticated numerical analyses. Also, the results for the back diffusion limits are consistent with available references. Additional calculations show that the characteristic parameters such as the coarsening, density variation and nonlinarity in the phase diagram significantly affect the microsegregation. Owing to the simplicity, efficiency and compatibility, the present model may be suitable for the micro-macroscopic solidification model as a microscopic component.

A NUMERICAL STUDY ON CHARACTERISTICS OF FLUID FLOW AND SOLUTE TRANSPORT IN A SELF-AFFINE VARIABLE-APERTURE FRACTURE UNDER NORMAL COMPLIANCE EFFECT

  • JEONG WOOCHANG;HWANG MANHA;KO ICKHWAN;SONG JAIWOO
    • Water Engineering Research
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    • v.6 no.2
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    • pp.49-61
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    • 2005
  • This paper presents the numerical study to examine characteristics of fluid flow and solute transport in a rough fracture subject to effective normal stresses. The aperture distribution is generated by using the self-affine fractal model. In order to represent a nonlinear relationship between the supported normal stress and the fracture aperture, we combine a simple mechanical model with the local flow model. The solute transport is simulated using the random walk particle following algorithm. Results of numerical simulations show that the flow is significantly affected by the geometry of aperture distribution varying with the effective normal stress level while it is slightly affected by the fractal dimension that determines the degree of the fracture surface roughness. However, solute transport is influenced by the effective normal stress as well as the fracture surface roughness.

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The Effects of Solute Carbon Atoms in Ferrite on Austenitization and the Thermal Expansion Coefficients of Ferrite and Austenite (페라이트 내에 고용된 미량의 탄소가 오스테나이트화 거동 및 페라이트와 오스테나이트의 열팽창 계수에 미치는 영향)

  • Mun, Yumi;Park, Jihye;Kang, Singon;Jung, Jae-Gil;Lee, Sangmin;Lee, Young-Kook
    • Journal of the Korean Society for Heat Treatment
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    • v.26 no.6
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    • pp.300-305
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    • 2013
  • The effects of solute carbon atoms on the thermal expansion coefficients of ferrite and austenite as well as austenitization behavior were investigated by comparing carbon-free ferrite and carbon-containing ferrite. The thermal expansion coefficients and austenitization start and finish temperatures were measured using a dilatometer. Solute carbon atoms at elevated temperatures above the cementite dissolution temperature (650 K) decreased the thermal expansion coefficients of both ferrite and austenite. In addition, minute amount of carbon atoms dissolved in ferrite stimulated austenite nucleation during continuous heating, resulting in the lower starting temperature of austenitization.

Solute Transport Model with Cation Exchange under Redox Environment and its Application for Designing the Slow Infiltration Set-up

  • GUERRA, GINGGING;JINNO, KENJI;HIROSHIRO, YOSHINARI;NAKAMURA, KOJI
    • Proceedings of the Korea Water Resources Association Conference
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    • 2004.05b
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    • pp.90-101
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    • 2004
  • The present trend of disposing treated sewage water by allowing it to infiltrate the soil brings a new dimension to environmental problems. It is therefore necessary to identify the chemicals likely to be present in treated sewage water. A soil column experiment was conducted to determine the behavior of chemical species in soil columns applied with secondary treated sewage water. To predict the behavior of chemical species, a multicomponent solute transport model that includes the biochemical redox process and cation exchange process was developed. The model computes changes in concentration over time caused by the processes of advection, dispersion, biochemical reactions and cation exchange reactions. The solute transport model was able to predict the behavior of the different chemical species. The model reproduced the sequential reduction reaction. To design the safe depth of plow layer where $NO_3^-$ is totally reduced, a numerical study of $NO_3^-$ leach was done and it was found out that the pore velocity and concentration of $CH_2O$ at the inject water was found to affect $NO_3^-$ reduction in the mobile pore water phase. It is revealed that the multicomponent solute transport model is useful to design the land treatment system for $NO_3^-$ removal from wastewater.

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Rejection Properties of Aromatic Pesticides by a Hollow Fiber NF Membrane (중공사 나노여과막을 이용한 방향족 농약의 배제 특성)

  • Jung, Yong-Jun;Kiso, Yoshiaki;Park, Soon-Gil;Kim, Jong-Yong;Min, Kyung-Sok
    • Journal of Korean Society on Water Environment
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    • v.20 no.3
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    • pp.296-300
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    • 2004
  • The rejection properties of 6 aromatic pesticides were evaluated by a continuous flow system equipped with a hollow fiber NF membrane. Different from the separation experiment of batch cell, the rejection and the removal could be calculated exactly because the concentration of feed, permeate and retentate was separately obtained. The lowest and the highest rejection were found in carbaryl(54.8%) and methoxychlor(99.2%), respectively, and the removals were always shown higher than rejections. This may be caused by some reasons such as the solute adsorption on the membrane, the variation of feed concentration. Although molecular weight, molecular width regarded as solute characteristics and log P(n-octanol/water partition coefficient) as hydrophobicity could be applied to explain the rejection property, these factors should be considered together for better analysis. According to the higher relationship between log B(solute permeability) and molecular weight, it was revealed that the solute separation with this membrane was influenced more by molecular weight.

Corrosion analysis of the duplex aluminum alloys (듀플렉스 알루미늄 합금의 내식성 분석)

  • Choi, In Kyu;Kim, Si Myeong;Kim, Sang Ho
    • Journal of the Korean institute of surface engineering
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    • v.48 no.5
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    • pp.227-232
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    • 2015
  • Corrosion characteristic of the duplex Al-Mg-Si alloys with low, commercial and high solute contents were studied using an anodic polarization test in 1M NaCl solution at room temperature. Polarization range condition of the experiment were form .0.3V to .1.3V with a 0.2 mV scanning speed. The exchange current density means corrosion rate of the low solute alloy was low as about $16.29{\mu}A/cm^2$, and that of the high solute alloy was high as $84.92{\mu}A/cm^2$. The difference was mainly attributed to the inter-granular precipitates $Mg_2Si$ and Si which could make a galvanic corrosion on the aluminum base. The amount of precipitates was greater in high solute alloy at mainly in grain boundary. While, the extruded alloys had better corrosion resistance than the cast alloy because the silicon precipitates become coarse during the extrusion process.

Modeling of Cementite Precipitation Kinetics on Solute Carbon Content in Extra and Ultra Low Carbon Steels (극저탄소강의 고용 탄소 함량에 미치는 시멘타이트 석출 속도 모델링)

  • Choi, Jong Min;Park, Bong June;Kim, Sung Il;Lee, Kyung Sub;Lee, Kyung Jong
    • Korean Journal of Metals and Materials
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    • v.48 no.3
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    • pp.187-193
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    • 2010
  • The solute carbon content in ferrite is one of the important factors to obtain good formability in low carbon steels. Although most of the carbons are consumed by the formation of grain boundary cementite during coiling after hot-rolling, the carbon content after coiling is normally observed much more than that of equilibrium. In this study, a classical nucleation and growth model is used to simulate the precipitation kinetics of the grain boundary cementite from coiling temperature (CT) to room temperature (RT). The predicted precipitation behaviors depending on the initial carbon content and the cooling rate are compared with the reported. As a result, the lateral growth of thickening of cementite is a major factor for the sluggish reaction of grain boundary cementite. The reduction of solute carbon content after coiling is divided into three regions: a) increase due to no cementite precipitation, b) decrease due to the fast length-wise growth of cementite, c) increase due to the slow thickness-wise growth of cementite.

Analyses on Solute Transport with the Movement of an LNAPL on the Water Table (지하수면 위의 LNAPL 이동을 고려한 용질이동에 대한 분석)

  • 김지훈;최종근
    • Journal of Soil and Groundwater Environment
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    • v.8 no.3
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    • pp.1-7
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    • 2003
  • A modified model was developed for solute transport in porous media that can consider the movement of an LNAPL above the water table. From the results of sensitivity analyses with and without considering LNAPL movement, there are some differences according to the hydraulic gradient, the quantity of oil leakage and dispersivity. The mean deviation between the model in this study and a conventional model without LNAPL movement increases as the hydraulic gradient decreases and the quantity of oil leakage increases. Variation of dispersivity has no influence on the magnitude of the mean deviation. However, the spatial distribution of the deviation between the two models is wider as dispersivity increases. Furthermore, groundwater is at high risk of contamination in the vertical direction in the case that transverse dispersion value is large. A conventional model underestimates the concentration of solute in an aquifer where the movement of an LNAPL cannot be negligible: Based on the study results, it is important to understand how fast the LNAPL moves on the water table for realistic prediction of solute transport in an aquifer with the movable LNAPL on the water table.

The Expression of Solute carrier family members Genes in Mouse Ovarian Developments (생쥐의 난소 발달과정에서 Solute carrier family 유전자들의 발현양상)

  • O, Lee-Gyun;Park, Chang-Eun
    • Korean Journal of Clinical Laboratory Science
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    • v.49 no.1
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    • pp.40-47
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    • 2017
  • Granulosa cells, which surround the oocyte within the ovarian follicle, play an essential role in creating conditions required for the development of oocytes and follicles. The solute carrier family (SLC) is comprised of influx transporters of steroidal hormones, various drugs, and several other substrates. The differential expression of selected DEGs was confirmed using in situ hybridization analysis. SLC23A3 and SLC39A10 were highly expressed in the ovary. The SLC39A10 gene was expressed in the primordial follicle stage, but SLC23A3 was expressed in the growing follicle stage. Contrastingly, the expression of SLC23A3 was increased in granulosa cells at the growing follicle stage. The differential expressions of SLC23A3 and SLC39A10 between the primordial and primary follicles were additionally confirmed by using follicle isolations. The gene expression profile from the present study may provide insight for future studies on the mechanism(s) involved in primordial-primary follicular transition and suggestions to promote follicular development in ovarian dysfunction.