• Journal of Korea Water Resources Association
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• v.31 no.2
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• pp.123-132
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• 1998

Monitoring solute transport has been known to be difficult especially for the unsaturated soil. The object of this study is to investigate the TDR application to monitoring solute concentration in the vadose zone. The TDR calibration test was conducted for soil samples with various water contents and concentrations. The voltage attenuation of electromagnetic wave of TDR was used to estimate the bulk electrical conductivity of a soil. The relationship between the bulk soil electrical conductivity and the solute concentration was assumed to be linear at a constant volumetric soil water content. In this study four proposed relationships were compared using data obtained from KCI solution at three different concentrations. Relationships given by Topp, Daltaon, Yanuka showed the linearity between the bulk soil electrical conductivity and the solute concentration, which were more pronounced than Zegelin's. The three relationships were found to be useful to measure the solute concentration in the vadose zone. In addition, TDR method was proven to be a viable technique in monitoring solute transport through unsaturated soils in transient flow condition.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.7 no.2
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• pp.37-44
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• 1987

Adsorption characteristics of chloroform, carbon tetrachloride, and crystal violet were investigated in single-and bi-solute systems. Single-solute adsorption for each solute was well described by Freundlich equation. Severe inhibition was recorded in bi-solute adsorption systems despite of low solute concentration of less than 1 mg/l. Inhibition of chloroform adsorption by carbon tetrachloride, similar compound in chemical structure, was much higher than by crystal violet of which chemical structure is quite different. Highest inhibition was observed at crystal violet adsorption by chloroform. While, inhibition caused by each other was almost equal between chloroform and carbon tetrachloride. Bi-solute adsorption was well described by Friz-Schl${\ddot{u}}$nder model and by much simpler 3 parameter Freundlich equation.

• Membrane Journal
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• v.29 no.2
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• pp.111-121
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• 2019

An organic citrate series draw solute was synthesized using diethyl malonate for forward osmosis. The structure of the final compound potassium pentane-1,3,3,5-tetracarboxylate was confirmed by $^1H-NMR$ and $^{13}C-NMR$ analysis. Osmotic pressure, solubility, water permeability and reverse salt flux were measured for the properties of the draw solute. Forward osmosis results showed that the draw solute exhibited higher water flux than other draw solutes of trisodium citrate and tripotassium citrate. Reverse salt flux of all the organic daw solutes was much lower than that of NaCl. The osmotic pressure of the synthesized draw solute was 25% lower than that of NaCl. The solubility of the draw solute was 317 g/ 100 g water, which is 8.8 times higher than that of NaCl. A commercialized nanofiltration membrane was used for the recovery of the draw solute. The draw solute could be effectively recovered at low pressure.

• Journal of Korea Foundry Society
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• v.10 no.3
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• pp.219-224
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• 1990

In this, we have investigated the solute behavior in front of solid-liquid interface according to the change of the cooling rate in bronze alloy and phosphor bronze alloy. The conclusive summary is as follows: 1) The secondary dendrite arm spacing was decreased with increasing the cooling rate. 2) The minimum solute concentration happened to along centerline of primary arm, and the maximum solute concentration was found at the boundary of arm or between the arms the minimum solute concentration was increased with the cooling rate. 3) Segregation Index S was decreased with increasing the cooling rate and content of P. 4) The degree of the microsegregation was decreased with increasing the cooling rate. The effective distribution coefficient, Ke was increased with addition of P in Cu-Sn.

• Journal of Korean Society of Water and Wastewater
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• v.28 no.1
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• pp.83-89
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• 2014

The aim of this study is to investigate the sorption/ion exchange of radioactive nuclides such as $Cs^+$ and $Sr^{2+}$ by synthetic Na-micas. In order to prepare Na-micas, two natural micas (phlogopite and biotite) were used as precursor materials. XRD, SEM, and EDS analyses were used to examine material characterization of synthetic Na-micas. Analyses of materials revealed that Na-micas were successfully obtained from natrual micas by K removal treatment. On the other hand, single solute (Cs or Sr) and bi-solute (Cs/Sr) sorption experiments were carried out to determine sorption capacity of Na-micas for Cs and Sr under different pH and ionic strength conditions. Uptake of Cs and Sr by micas in bi-solute system was lower than in single-solute system. Additionally, Langmuir and Langmuir competitive models were applied to describe sorption isotherm of Na-micas. bi-solute system was well described by Langmuir competitive models. For the results obtained in this study, Na-micas could be promising sorbents to treat multi-radioactive species from water and groundwater.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2000.11a
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• pp.69-73
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• 2000

We systematically analyze the influence of fracture junction, solute transfer characteristics on transport patterns in discrete, two-dimensional fracture network models. Regular lattices and random fracture networks with power-law length distributions are considered in conjunction with particle tracking methods. Solute transfer probabilities at fracture junctions are determined from analytical considerations and from simple complete mixing and streamline routing models. For regular fracture networks, mixing conditions at fracture junctions are always dominated by either complete mixing or streamline routing end member cases. Moreover bulk transport properties such as the spreading and the dilution of solute are highly sensitive to the mixing rule. However in power-law length networks there is no significant difference in bulk transport properties, as calculated by assuming either of the two extreme mixing rules. This apparent discrepancy between the effects of mixing properties at fracture junctions in regular and random fracture networks is explained by the statistics of the coordination number and of the flow conditions at fracture intersections. We suggest that the influence of mixing rules on bulk solute transport could be important in systematic orthogonal fracture networks but insignificant in random networks.

• Environmental Engineering Research
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• v.23 no.1
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• pp.76-83
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• 2018

Spatial moment analysis has been performed on the concentration of the first species in a multispecies solute transport in porous media. Finite difference numerical technique was used in obtaining the solute concentration. A constant continuous source of contaminant was injected at the inlet of the domain. Results suggest that the decaying of solute mass increases as the magnitude of mean fluid velocity increases. The dispersion coefficient is highly time dependent under decaying of solutes with a complex behavior of mixing of solutes. The solute mobility and mixing varies non-linearly with time during its initial period, while the same ceases with higher decay rates of the first species much faster.

• Journal of the Korean GEO-environmental Society
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• v.7 no.5
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• pp.79-87
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• 2006

This paper presents the numerical model developed to simulate the solute transport in rough and smooth single fractures. The roughness of these fractures is represented by using the fractal surface method. In this study, the 3D transport model, which is based on the random walk technique, is used to simulate the dispersion process of a solute which is represented by numerical particles. As the simulation results, it can be observed that the dispersion of solute in the fracture is significantly affected by the fracture roughness and particle size.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2005.04a
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• pp.348-351
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• 2005

In this study, solute breakthrough curves through the unsaturated zone were predicted using artificial neural network (ANN) by numerical tests and laboratory experiments. In the numerical tests, applicability of ANN model to prediction of breakthrough curves was evaluated using synthetic data generated by HYDRUS-2D. An appropriate strategy of ANN application and input data form were recommended. The ANN model was validated by laboratory experiments comparing with HYDRUS-2D simulations. The results show that the ANN model can be an effective method for forecasting solute breakthrough curves through the unsaturated zone when hydraulic data are available.

• Advances in environmental research
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• v.5 no.4
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• pp.263-282
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• 2016

Contaminant transport in groundwater induces major threat and harmful effect on the environment; hence, the fate of the contaminant migration in groundwater is seeking a lot of attention. In this paper a two dimensional numerical flow and transport model through saturated layered soil is developed. Groundwater flow and solute transport has been simulated numerically using proposed model. The model implements the finite volume time splitting method to discretize the main equations. The performance, accuracy and efficiency of the out coming numerical models have been successfully examined by two test cases. The verification test cases consist of two-dimensional, groundwater flow and solute transport. The final purpose of this paper is to discuss and compare the shape of contaminant plume in homogeneous and heterogeneous media with different soil properties and control of solute transport using a zone for minimizing the potential of groundwater contamination; furthermore, this model leads to select the effective and optimum remedial strategies for cleaning the contaminated aquifers.