• Transactions of the Korean Society of Mechanical Engineers
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• v.13 no.3
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• pp.528-537
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• 1989

The objective of this paper is to investigate effects of the specific heat and the diameter of suspending particles on the heat transfer coefficient of two phase turbulent flow with suspension of solid particles in a circular tube with constant heat flux. Heat transfer coefficients of two phase turbulent flow in pipe with suspension of graphite powder were measured with variations of particle sizes and solid-gas loading ratio. Measured data were compared with predictions by numerical analysis in which the turbulece models are closed on the first order level. Results show that heat transfer coefficient increases with increasing the solid-gas loading ratio and the specific heat of suspending material, however, it decreases as the average diameter of particles decreases below $24{\mu}m$.

• Journal of Magnetics
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• v.16 no.1
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• pp.10-14
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• 2011

This study reports on Co/$Co_2$MnSn two-phase magnets. The Co/$Co_2$MnSn two-phase magnet has Co precipitates in a $Co_2MnSn$ Heusler alloy matrix, in which the two phases are exchange-coupled at the phase boundary. The as-casted Co/$Co_2$MnSn system, which has Co-Mn solid solution precipitates in a $Co_2$MnSn Heusler alloy matrix, showed that the Co solid solution precipitates are crystallographically coherent and there is exchange coupling at the phase boundary. To form pure Co precipitates by removal of Mn solute atoms in Co-Mn solid solution, annealing was carried out 48 hours at $870^{\circ}C$. After annealing, the low $T_c$ and low magnetization phase of the Co-Mn solid solution became a high $T_c$ and high magnetization phase of hexagonal Co.

• Progress in Superconductivity and Cryogenics
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• v.14 no.4
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• pp.28-31
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• 2012

We report the solid-liquid phase equilibria on the $GdBa_2Cu_3O_{7-{\delta}}$ (GdBCO) stability phase diagram in low oxygen pressures ($PO_2$) ranging from 1 to 100 mTorr. On the basis of the GdBCO stability phase diagram experimentally determined in low oxygen pressures, the isothermal sections of three different phase fields on log $PO_2$ vs. 1/T diagram were schematically constructed within the $Gd_2O_3-Ba_2CuO_y-Cu_2O$ ternary system, and the solid-liquid phase equilibria in each phase field were described. The invariant points on the phase boundaries include the following three reactions; a pseudobinary peritectic reaction of $GdBCO{\leftrightarrow}Gd_2O_3$ + liquid ($L_1$), a ternary peritectic reaction of $GdBCO{\leftrightarrow}Gd_2O_3+GdBa_6Cu_3O_y$ + liquid ($L_2$), and a monotectic reaction of $L_1{\leftrightarrow}GdBa_6Cu_3O_y+L_2$. A conspicuous feature of the solid-liquid phase equilibria in low $PO_2$ regime (1 - 100 mTorr) is that the GdBCO phase is decomposed into $Gd_2O_3+L_1$ or $Gd_2O_3+GdBa_6Cu_3O_y+L_2$ rather than $Gd_2BaCuO_5+L$ well-known in high $PO_2$ like air.

• Transactions of the Korean hydrogen and new energy society
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• v.8 no.3
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• pp.101-109
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• 1997

We propose a new concept of hydrogen absorbing alloy, "Laves phase related BCC solid solution". It was firstly found among the phases tormed in multicomponent nominal $AB_2$ alloys which consisted of Zr and Ti for the A metal site and 5A, 6A and 7A transition metals for the B metal sites. In these alloys a BCC solid solution often coexisted with a Laves phase. It showed stability of hydrides and reaction kinetics almost identical to intermetallics such as Laves phase alloys. We prepared an almost pure "Laves phase related BCC solid solution" and found that it had a large hydrogen capacity (more than 2 mass%) and fast hydrogen absorption and desorption kinetics at ambient temperature and pressure. This new hydrogen absorbing alloy may open a new era of hydrogen related application such as hydrogen vehicles.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 1999.04a
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• pp.5-5
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• 1999

The Principal deficiency of the existing notion about the sintering-mixtures consists in the fact that almost no attention is focused on the Phenomenon of alloy formation during sintering, its connection with dimensional changes of powder bodies, and no correct ideas on the driving force for the sintering process in the stage of establishing chemical equilibrium in a system are available as well. Another disadvantage of the classical sintering theory is an erroneous conception on the dissolution mechanism of solid in liquid. The two-particle model widely used in the literature to describe the sintering phenomenon in solid state disregards the nature of the neighbouring surrounding particles, the presence of pores between them, and the rise of so called arch effect. In this presentation, new basic scientific principles of the driving forces for the sintering process of a two-component powder body, of a diffusion mechanism of the interaction between solid and liquid phases, of stresses and deformation arising in the diffusion zone have been developed. The major driving force for sintering the mixture from components capable of forming solid solutions and intermetallic compounds is attributed to the alloy formation rather than the reduction of the free surface area until the chemical equilibrium is achieved in a system. The lecture considers a multiparticle model of the mixed powder-body and the nature of its volume changes during solid-state and liquid-phase sintering. It explains the discovered S-and V-type concentration dependencies of the change in the compact volume during solid-state sintering. It is supposed in the literature that the dissolution of solid in liquid is realised due to the removal of atoms from the surface of the solid phase into the melt and then their diffusicn transfer from the solid-liquid interface into the bulk of liquid. It has been shown in our experimental studies that the mechanism of the interaction between two components, one of them being liquid, consist in diffusion of the solvent atoms from the liquid into the solid phase until the concentration of solid solutions or an intermetallic compound in the surface layer enables them to pass into the liquid by means of melting. The lecture discusses peculimities of liquid phase formation in systems with intermediate compounds and the role of the liquid phase in bringing about the exothermic effect. At the frist stage of liquid phase sintering the diffusion of atoms from the melt into the solid causes the powder body to grow. At the second stage the diminution of particles in size as a result of their dissolution in the liquid draws their centres closer to each other and makes the compact to shrink Analytical equations were derived to describe quantitatively the porosity and volume changes of compacts as a result of alloy formation during liquid phase sinteIing. Selection criteria for an additive, its concentration and the temperature regime of sintering to control the density the structure of sintered alloys are given.

• Journal of computational fluids engineering
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• v.6 no.4
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• pp.8-14
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• 2001

The phenomena of two-phase suspension flows appear widely in nature and industrial processes. Hence, it is of great importance to understand the mechanism of the gas-solid two-phase flows. In the present study, the numerical simulation has been approached by utilizing the Eulerian-Lagrangian methodology for describing the characteristics of the fluid and particulate phases in a vertical pipe and a 90°square-sectioned bend. The continuous phase(gas phase) is described by the Eulerian formulation and a κ-ε turbulence model is employed to find mean and turbulent properties of the gas phase. The particle properties(velocity and trajectory) are then described by a Lagrangian approach and computed using the mean velocity and turbulent fluctuating velocity of the gas phase. The predictions are compared with measurements by laser-Doppler velocimeter for the validation. As a result, the calculated results show good agreements.

• Korean Journal of Materials Research
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• v.16 no.1
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• pp.50-57
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• 2006

Phase mixtures of Titanium boride, nitride, and carbide powder were produced by the reduction of a mixture of titanium and boron oxides with carbon via a gas-solid phase reaction. Boron oxides produce a vapour phase or decompose to a metal sub-oxide gaseous species when reduced at elevated temperature. The mechanism of BO sub-oxide gas formation from $B_2O_3$ and its subsequent reduction to titanium diboride for the production of uniform size hexagonal platelets is explained. These gaseous phases are critical for the formation of boride, nitride and carbide ceramics. For the production of ceramic phase composite microstructures, the nitrogen partial pressure was the most critical factor. Some calculated equilibrium phase fields has been verified experimentally. The theoretical approach therefore identifies conditions for the formation of phase mixtures. The thermodynamic and kinetic factors that govern the phase constituents are also discussed.

• Journal of Powder Materials
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• v.8 no.4
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• pp.258-267
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• 2001

In this work, the conventional transient liquid phase(TLP) bonding was modified. An attempt was made of using a liquid phase sintered alloy, which will be a liquid phase coexisting with a solid phase at the bonding temperature, as an interlayer for bonding metals. With an aim of revealing the fundamental features of this modified TLP bonding, the kinetics concerned with the growth of solid particles and the isothermal solidification process in Fe-1.16wt%B and Fe-4.5wt%P interlayers for the bonding pure iron, as well as the morphological change of the solid particle, were investigated.

• Journal of Advanced Marine Engineering and Technology
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• v.24 no.1
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• pp.88-93
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• 2000

In this study, the mixing process of two-phase flow generated by two jets with height difference is analyzed. The primary jet is jetted on the condition of the state mixed pulverized solid particles with air. The height difference between the main jet and the secondary jet is changed into three kinds(0, 32.5, 47.5mm). The velocity vector field, concentration field and turbulent properties of solid particles are measured by using 3-Dimensional Particles Dynamics Analyzer. As the height difference of two jets through the two nozzles increases, the solid particle recirculation zone and the dense zone in the combustion chamber become large. The solid particle concentration at the center of the combustion chamber gets dense because the particle velocity remains slow due to the existence of the solid particle recirculation zone. The particle concentration in the combustion chamber can also be influenced by the hight difference of two jets.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2001.05a
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• pp.124-128
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• 2001

Two-dimensional solidification analysis during rheology forming process of semi-solid aluminum ahoy has been studied Two-phase fluid flow model to investigate the velocity field and temperature distribution is proposed. The unposed mathematical model is applied to the die shape of the two type. To calculate the velocities and temperature fields during rheology forming process, the each governing equation correspondent to the liquid and solid region are adapted. Theoretical model on the basis of the two-phase flow model is the mixture rule of solid and liquid phases. This approach is based on the liquid and solid viscosity.