• Title/Summary/Keyword: solid yields

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Hot Atom Chemistry of Aromatic Halides : Scavenger, Temperature and Oxygen Effect (芳香族할라이드의 Hot Atom Chemistry 스캐벤져, 溫度 및 酸素의 效果)

  • Choi, Jae-Ho;Park, Yong-Chan;Son, Mi-Ja
    • Journal of the Korean Chemical Society
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    • v.9 no.2
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    • pp.78-80
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    • 1965
  • The organic yields(i.e., fraction of nuclear events resulting in organic compound formation) of the radioactive neutron capture reactions of the halogens in purified aromatic halides have been determined in the liquid and solid state, in the presence of scavenger, elemental halogen for thermal atoms, and in the presence of oxygen. Among the important results are; (1) organic yields of the halides are due in part to hot processes and in part to thermal processes; (2) temperature (from liquid state to solid state); (3) the organic yield of chlorobenzene is the same in the solid phase as in the liquid phase whereas the yields of the bromo-and iodobenzene are higher in the solid.

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Lithium Aluminum Hydride Reduction Studies of Rigid $\alpha$-Oximino Ketones

  • Kim, Jack C.;Lee, Young-Tae;Kim, Min-Sook;Woo, Young-Min;Shin, Hong-Dae;Cho, In-Seop
    • Bulletin of the Korean Chemical Society
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    • v.3 no.3
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    • pp.119-122
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    • 1982
  • Rigid ${\alpha}$-oximino ketones containing two functional groups such as 2-oximino-1-acenaphthenone and 2-oximino-1-indanone were synthesized and the simultaneous reduction of the two functional groups of ${\alpha}$-oximino ketones by $LiAlH_4$ gave the corresponding amino alcohols, 2-amino-1-acenaphthenol and 2-amino-1-indanol. The yields of the reduction products of the ${\alpha}$ -oximino ketones remarkably increased, as the increase of molar ratio of hydride used to the reactant. The use of 24 moles of $LiAlH_4$ was found to afford the best result in the reduction of the rigid ${\alpha}$-oximino ketones to the corresponding amino alcohols. The yields was not affected by the variation of solvents such as ether, THF and diglyme.

Carbon-Based Solid Acid as an Efficient and Reusable Catalyst for the Synthesis of 1,8-Dioxodecahydroacridines Under Solvent-Free Conditions

  • Davoodnia, Abolghasem;Khojastehnezhad, Amir;Tavakoli-Hoseini, Niloofar
    • Bulletin of the Korean Chemical Society
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    • v.32 no.7
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    • pp.2243-2248
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    • 2011
  • Carbon-based solid acid catalyst was found to be highly efficient, eco-friendly and recyclable heterogeneous catalyst for the multicomponent reaction of dimedone, aromatic aldehydes, and a nitrogen source (ammonium acetate or aromatic amines) under solvent-free conditions, giving rise to 1,8-dioxodecahydroacridines in high yields. The present methodology offers several advantages, such as a simple procedure with an easy work-up, short reaction times, high yields, and the absence of any volatile and hazardous organic solvents.

Effects of Polysaccharide Hydrolase on Solids Yields and Viscosity of Aqueous Extracts of Sea Mustard (다당류 분해효소의 첨가가 미역 추출액의 수율 및 점도에 미치는 영향)

  • Choi, Hee-Sook;Kim, Woo-Jung
    • Korean Journal of Food Science and Technology
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    • v.25 no.5
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    • pp.589-591
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    • 1993
  • Effects of enzymatic hydrolysis of polysaccharides with using three commercial mixed enzymes (Ultrazyme, Celluclast, Viscozyme) were investigated on supernatant ratio, solid yields and viscosity of sea mustard extracts. The result showed that enzymatic hydrolysis prior to extraction increased the solids concentration up to 27.3% and the solids yield up to 14.0%. However the supernatant ratio after centrifugation of the sea mustard suspension was rather reduced. The viscosity of the extracts was significantly increased during initial enzymatic hydrolysis.

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Solid-Phase Synthesis of 2-Arylbenzothiazole Using Silica Sulfuric Acid under Microwave Irradiation

  • Niralwad, Kirti S.;Shingate, Bapurao B.;Shingare, Murlidhar S.
    • Bulletin of the Korean Chemical Society
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    • v.31 no.4
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    • pp.981-983
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    • 2010
  • The condensation of several aromatic/heteroaromatic aldehydes with 2-aminothiophenol catalyzed by silica sulfuric acid under microwave irradiation afforded 2-arylbenzothiazoles in high yields and short reaction times under solvent-free conditions. The major advantages of the present method are good yields, ecofriendly, reusable catalyst, mild and solvent-free reaction conditions.

Simulation of Sediment Yield from Imha Watershed Using HSPF (HSPF를 이용한 임하호 유역 유사량 모의)

  • Jeon, Ji-Hong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.52 no.6
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    • pp.39-48
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    • 2010
  • Sediment yields from Imha watershed were simulated during 1993-2008 using Hydrologic Simulation Program-Fortran (HSPF). Using observed daily stream flow for 2004-2008 and hourly suspended solid concentration for three events during 2006, HSPF was calibrated and validated at the sites of Imha and Youngyang for stream flow and Dongchun and Jangpachun for sediment yield. The calibration and validation results represented high model efficiency for simulating daily stream flow and hourly suspended solid. The determination coefficients of calibration and validation were 0.90 and 0.81 for daily stream flow, and 0.91 and 0.86 for monthly stream flow, respectively. Based on model tolerances for calibration and validation of stream flow, HSPF performance for simulating stream flow represented 'very good'. The determination coefficients of calibration and validation were 0.94-0.96 and 0.95 for hourly sediment yields, respectively. The average yearly sediment yield during 1993-2008 was 122,290 ton/year and most of sediment yield (77 % of total yield) were generated from June to August. The calibrated HSPF simulated well the movement of water and eroded soil within Imha watershed.

The Experiments for the Enhancement of Regression Rate of Hybrid Rocket Fuel

  • Shin Kyung-Hoon;Lee Changjin;Yu Yung H.
    • Journal of Mechanical Science and Technology
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    • v.19 no.10
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    • pp.1939-1949
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    • 2005
  • Many studies have been conducted to increase regression rate of solid fuel in hybrid rocket. One of them resorts to swirl flow since it can extend the residence time of oxidizer in the fuel grain. Also, metal wires may lead to increase the regression rate of solid fuel as shown in solid propellants. In this study, a series of experiments was designed to investigate the enhancement of regression rate of solid fuel by embedded metal wires and by fuel port grain. And fuel port was designed with a helical configuration to attempt to induce swirl flow. PMMA with gaseous oxygen is the solid fuel used for investigation. Test results showed that embedded metal wires turned out to be ineffective method because only $3-4\%$ increases in regression rate were observed. However, fuel port grain configuration yields higher burning performance of up to $50\%$ increase in regression rate. Also pitch number as well as total impulse was found to be a design variable.

Etching of an Al Solid by SiCl$_4$ Molecules at 600 eV

  • Seung Chul Park;Chul Hee Cho;Chang Hwan Rhee
    • Bulletin of the Korean Chemical Society
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    • v.11 no.1
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    • pp.1-7
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    • 1990
  • We present a theoretical investigation on the etching of an Al solid by $SiCl_4$ molecules at a collision energy of 600 eV. The classical trajectory method is employed to calculate Al etching yields, degree of anisotropy, kinetic energy distribution and angular distribution. The calculated results are compared with the reaction of a Cu solid by $SiCl_4$. The major products of the reaction are aluminum monomers and dimers together with considerable quantities of multimers. The Al solid shows better etching yield and better anisotropy than the Cu solid. This is consistent with the problem in the CMOS micro-fabrication of the CuAl and CuAlSi alloys. The relevance of these calculations for the dry etching of CuAl alloy is discussed.

Comparison of Liquid and Solid-State Fermentation Processes for the Production of Enzymes and Beta-Glucan from Hulled Barley

  • Lee, Se Yeon;Ra, Chae Hun
    • Journal of Microbiology and Biotechnology
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    • v.32 no.3
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    • pp.317-323
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    • 2022
  • Solid-state fermentation using hulled barley was carried out to produce enzymes and β-glucan. The one-factor-at-a-time experiments were carried out to determine the optimal composition of the basal medium. The modified synthetic medium composition in liquid-state fermentation was determined to be 70 g/l hulled barley, 0 g/l rice bran, 5 g/l soytone, and 6 g/l ascorbic acid. Optimal pretreatment conditions of hulled barley by solid-state fermentation were evaluated in terms of maximum production of fungal biomass, amylase, protease, and β-glucan, which were 1.26 mg/g, 31310.34 U/g, 2614.95 U/g, and 14.6% (w/w), respectively, at 60 min of pretreatment condition. Thus, the solid-state fermentation process was found to enhance the overall fermentation yields of hulled barley to produce high amounts of enzymes and β-glucan.

Comparison Study of Extraction Properties of Solids, Protein and Color Pigments of Several Soybean Varieties (콩 품종에 따른 고형분, 단백질, 색소의 추출 특성의 비교)

  • Kim, Dong-Hee;Kim, Seok-Dong;Kim, Woo-Jung
    • Applied Biological Chemistry
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    • v.33 no.1
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    • pp.8-13
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    • 1990
  • The solid and protein yields and extraction properties of color pigments were compared for 7 varieties of soybeans during soaking in water at $4-100^{\circ}C$. The varieties investigated were Paldal, Danyeob, Jangbaek, Baegun, Jangyeob and 2 cultivars of Local 1 and Local 2. The Hunter values showed that Jangbaek was the highest in 'L' value while other varieties except Local 1 and Local 2 were comparatively high in 'L' value. Local 1 and Local 2 were low in 'b' value. The yields of solid and protein during water extraction showed that most of solids and proteins were recovered with three consecutive extractions. The cumulated yields were 73.2 % for solid and 83.2 % for protein. Extraction of color pigments of seed coats in $4-100^{\circ}C$ water showed that the extraction rate was very much dependent on extraction time and temperature. A linear relationship of A=aT+b was obtained for equilibrated absorbance(A) and extraction temperature(T). The activation energy calculated from initial extraction rate of cole. pigments and temperature had two different values of low($4-60^{\circ}C$) and high($60-100^{\circ}C$) temperature range.

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