• Title/Summary/Keyword: solid removal

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Nitrogen-doped carbon nanosheets from polyurethane foams and removal of Cr(VI)

  • Duan, Jiaqi;Zhang, Baohua;Fan, Huailin;Shen, Wenzhong;Qu, Shijie
    • Carbon letters
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    • v.22
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    • pp.60-69
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    • 2017
  • Nitrogen-doped carbon nanosheets with a developed porous structure were prepared from polyurethane foams by hydrothermal carbonization following $ZnCl_2$ chemical activation. Scanning electron microscopy, thermogravimetric analysis, Fourier transform infrared spectroscopy, solid state $^{13}C$ nuclear magnetic resonance (NMR) spectra and X-ray photoelectron spectroscopy were used to characterize the nitrogen-doped carbon nanosheet structure and composition. The removal of Cr(VI) by the N-doped carbon nanosheets was investigated. The results showed that the maximum removal capacity for chromium of 188 mg/g was found at pH=2.0 with PHC-Z-3. pH had an important effect on Cr(VI) removal and the optimal pH was 2.0. Moreover, amino groups and carboxyl groups in the nitrogen-doped carbon nanosheet played important roles in Cr(VI) removal, and promoted the reduction of Cr(VI) to Cr(III).

Removal of Cu(II) and Pb(II) by Solid-Phase Extractant Prepared by Immobilizing D2EHPA with Polysulfone (D2EHPA를 Polysulfone으로 고정화하여 제조한 고체상 추출제에 의한 Cu(II)와 Pb(II)의 제거)

  • Kam, Sang-Kyu;Jeon, Jin-Woo;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.23 no.11
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    • pp.1843-1850
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    • 2014
  • PS-D2EHPA beads were prepared by immobilizing di-2-ethylhexyl-phosphoric acid (D2EHPA) with polysulfone (PSf). The removal experiments of Cu(II) and Pb(II) by the prepared PS-D2EHPA beads were conducted batchwise. The removal efficiency of Cu(II) and Pb(II) by PS-D2EHPA beads was increased with increasing pH of solution. The removal rate of Cu(II) and Pb(II) was well described by the pseudo-second-order kinetic model. The maximum removal capacity of Cu(II) and Pb(II) obtained from Langmuir isotherm were 2.58 mg/g and 12.63 mg/g, respectively. External mass transfer coefficients for the removal of Cu(II) and Pb(II) by PS-D2EHPA beads were obtained $0.61{\times}10^{-2}{\sim}5.87{\times}10^{-2}/min$ and $1.55{\times}10^{-2}{\sim}8.53{\times}10^{-2}/min$, respectively and diffusion coefficients were obtained $1.32{\times}10^{-4}{\sim}3.98{\times}10^{-4}cm^2/min$ and $1.80{\times}10^{-4}{\sim}2.28{\times}10^{-4}cm^2/min$, respectively.

A Study on Hair Removal Characteristics Using a Long-pulsed Alexandrite Laser

  • Choi Jin-Young;Kim Sang-Gil;Park Jong-Woong;Park Sung-Joon;Kim Hee-Je
    • KIEE International Transactions on Electrophysics and Applications
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    • v.5C no.1
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    • pp.33-38
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    • 2005
  • Recently, lasers have become widely used throughout the medical treatment field. Several types of lasers have been used for the purpose of hair removal since the Alexandrite laser was approved by the FDA (Food & Drug Administration) for clinical epilation. In this study, a long-pulsed Alexandrite laser system for hair removal adopting a multi-discharge method in which three flash lamps are turned on consecutively was designed and fabricated. This laser system shows the technology that makes it possible to create extended pulse by turning on three flash lamps consecutively. With this technique, the pulse width can be varied from 4ms∼10ms. Then using this Alexandrite laser system with the pulse width 10ms and the beam size 7mm, hair removal was performed on the back portion of a human hand and leg. This study shows that treatment by the long-pulsed Alexandrite laser produces hair removal with no relevant side effects.

Optimal Operation Condition of Spray Drying Sorber for Simultaneous Removal of Acidic and Organic Gaseous Pollutants (산성 및 유기성 가스의 동시제거를 위한 준건식 세정시스템의 적정 운전 조건)

  • 백경렬;구자공
    • Journal of Environmental Science International
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    • v.10 no.1
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    • pp.59-64
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    • 2001
  • The effect of major operating parameters in spray drying sorber(=SDS) for automatic control for the simultaneous removal of acidic and organic gaseous pollutants from solid waste incinerator was performed. The field experiment was carried out in pilot scale test for the quantification of major operating parameters of hydrophilic and the hydrophobic pollutants. The removal efficiencies of $SO_2$and HCI in the 5wt% slurry condition were being increased with the increase of the stoichiometric ration which is the molecular ratio of lime to the pollutant concentration, and with the decrease of inflow flue gas temperature in the pilot SDS reactor. The removal efficiency along the height of spray drying sorber was closely related to the temperature profile, and more than 90% of total removal efficiency was achieved in an absorption region. For the removal of acidic gas the optimum operating condition considering the economics and a stable operation is the 5wt% of slurry concentration, 1.2 of stoichiometric ratio and 25$0^{\circ}C$ of inflow flue gas temperature. For the organic gases of benzene and toluene the removal efficiencies were 20-60% which is much lower than that of acidic gas. The best removal efficiency was obtained at 1.5 of stoichiometric ratio and 25$0^{\circ}C$ of inflow flue gas temperature. The organic\`s removal efficiency along the height of spray drying sorber was quite different from that of acidic gas, that is, more than 60% of the total removal efficiency for benzene and 90% of the total removal for toluene were achieved in the dried adsorption region, which was formed at the lower or exit part of the reactor.

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Evaluation of Downflow Granular Media Filtration for Stormwater Treatment (강우유출수에 의한 비점오염 저감을 위한 하향류식 입상여과 효율 평가)

  • Lim, Chan-Su;Kim, Do-Gun;Ko, Seok-Oh
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.10
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    • pp.684-693
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    • 2012
  • The stormwater runoff from the increasing paved roads and vehicles resulted in the increase in the pollutants load to adjacent water bodies. The granular media filtration facilities are the most widely adopted to minimize the non-point source pollution from motorways. It is essential to consider the severe variation of hydraulic condition, suspended solid (SS) characteristics, and the medium characteristics for stormwater management filter. In this study, different types of media, including sand, were tested and the performance of downflow sand filters was investigated under various linear velocity and influent solid particle size. Results showed that the best medium is the coarse sand with large grain size, which showed the specific SS removal before clogging of more than $8.498kg/m^2$, the SS removal of higher than 95%, and minimum head loss. Linear velocity did not affect the total solid removal, while the performance was improved when fine solid was introduced. It is suggested that the life of a downflow sand filter bed can be extended by deep bed filtration when influent particles are fine. However, the captured particles can be washed out after a long period of operation.

A Study on the Multiphase Flow Characteristics in an Mud System (머드시스템의 다상 유동 특성 연구)

  • Lee, Wang-Do;Han, Sang-Mok;Chun, Joong-Ho
    • Journal of the Korean Society of Industry Convergence
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    • v.24 no.6_2
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    • pp.737-744
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    • 2021
  • An investigation is conducted to study a solid-liquid mixture vertically upward hydraulic transport of solid particles by non-Newtonian fluids in the Mud system. Rheology of particulate suspensions in viscoelastic fluids is of importance in many applications such as particle removal from surfaces, transport of proppants in fractured reservoir and cleaning of drilling holes, etc. In this study a clear acrylic pipe was used in order to observe the movement of solid particles. Annular velocities varied from 0.4 m/s to 1.2 m/s. The mud systems which were utilized included aqueous solution of sodium carboxymethyl cellulose (CMC) solutions. Main parameters considered in the study were inner-pipe rotary speed, fluid flow regime and particle injection rate. Solid volumetric concentration and pressure drops were measured for the various parameters such as inclination angle, flow rate, and rotational speed of inner cylinder.

An Experimental Study on the Treatment of Organic Wastewater by Soil Microbes Using Three-phase Fluidized Bed (삼상유동층 반응기에서 토양미생물에 의한 유기성 폐수처리에 관한 연구)

  • Choung, Youn Kyoo;Chun, Yang Kun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.12 no.1
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    • pp.207-217
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    • 1992
  • In this study, isolated and cultured nitrogen fixed microbes were seeded in the three-phase fluidized bed in which gas, solid and liquid were contacted directly. Input velocity was varied from 8.12 cm/hr to 16.32 cm/hr. And upflow gas pressure was fixed to 80 psi. Return ratios were from 0.2 to 0.6 with the each experimental condition. According to these condition, movement of media, growth of biofilm and removal efficiency were measured. As the results, in case of briquette ash, biofilm was developed to $170{\mu}m$ when velocity was 8.12 cm/hr and return ratio was 0.6. In this condition, COD removal efficiency was 97% and $NH_4$-N removal efficiency was 83%. At the same condition, biofilm thickness of glass bead was $17.59{\mu}m$ and its COD and $NH_4$-N removal efficiency was 83% and 72%. Nitrogen fixed microbes have following characters: it formed dark-brownish sludge, excellent adhesive force, easy solid-liquid separation and low oxygen uptake ratio, but sensitive to DO concentration. Not only it endured shock loading, but required short time to steady state.

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Removal of Chlorine from Fly Ash in Municipal Solid Waste Incineration Ash by Water Washing (수세에 의한 생활폐기물 소각재 중 비산재로부터 염소성분의 제거)

  • 안지환;한기천;김형석
    • Resources Recycling
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    • v.10 no.5
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    • pp.36-43
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    • 2001
  • The chlorine component in fly ash from municipal solid waste incineration ash was removed by water washing for the purpose of recycling fly ash as a raw material of ordinary portland cement. The samples were a different kind of 리y ashes using $Ca(OH)_2$and NaOH as media of wet scrubber for flue gas cleaning. The content of soluble salts of fly ash using $Ca(OH)_2$and NaOH was 32.8%, 50.1% and the content of chlorine component, 22.9% and 26.0% respectively, which was KCl, NaCl, CaC1OH mainly. When each fly ash was washed using water under conditions of a agitation speed of 300 rpm, a liquid to solid ratio of 10, most soluble salts in fly ash were dissolved within 30 minutes and the content of chlorine component in ash was diminished to the content of 4.4%, 2.O% at $20^{\circ}C$ and 1.7%, 0.8% at $50^{\circ}C$ respectively. And the main compound of residual chlorine component in ash after water washing was friedel`s salt ($3CaO.A1_2$$O_3$.$CaCl_2$.$10H2$O). From analysis results of water quality for wastewater by water washing, the components exceeding discharged wastewater standard were only Pb and Cd. But As pH was controlled to 10 with addition of $CO_2$(g) or $Na_2$$_CO3$in water, the concentration of heavy metals such as Pb and Cd was also under discharged wastewater standard.

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Characteristics of Solid Culm and Solidness Variation in Winter Wheat and Triticale (Solid형 맥류의 줄기의 특성과 Solidness 변이)

  • 강양순;하용웅;박광근;허화영
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.36 no.6
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    • pp.501-505
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    • 1991
  • To evaluate the suitability of solid-culm crops for silage, culm characteristics and the variation of solidness in several solid-culm and hollow-culm cultivars of wheat and triticale were examined both in the field and greenhouse. The degree of culm solidness and the voiume of air space in each internodes were measured at heading. The solidness of solid-culm were increased by the development of pith connected with vascular bundles. There was a variation in solidness among the crops tested. The degree of solidness in hollow -culm crops was 14.6% and 15.0% for 'Wonkwang' wheat and 'Shinkihomil' triticale, whereas in solid-culm crops the degree was 77.0-100% for durum wheats, 61. 0-95.8% for bread wheats and 18,7-57,0% for triticales. For 'Golden ball' which had the most solid culms among durum wheats tested higher solidness was observed in the greenhouse than the field, in the high internodes than low ones and in tiller culms than main stems. The solid-culm crops had a smaller air volume in internodes (1.01-2.30ml) than did 'Shinkihomil' (4.85ml) and this characteristics was considered to be advantageous for air removal and lactic fermentation at ensilaging.

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The Kinetic Analysis on Organic Substrate Removal and Nitrification in Anoxic-Anaerobic-Aerobic Process (무산소-혐기-호기법에서 유기기질제거와 질산화의 동역학적 해석)

  • Chae, Soo Kwon
    • Journal of Korean Society on Water Environment
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    • v.23 no.5
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    • pp.689-696
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    • 2007
  • Kinetic analysis was important to develope the biological nutrient removal process effectively. In this research, anoxic-anaerobic-aerobic system was operated to investigate kinetic behavior on the nutrient removal reaction. Nitrification and denitrification were important microbiological reactions of nitrogen. The kinetics of organic removal and nitrification reaction have been investigated based on a Monod-type expression involving two growth limiting substrates : TKN for nitrification and COD for organic removal reaction. The kinetic constans and yield coefficients were evaluated for both these reactions. Experiments were conducted to determine the biological kinetic coefficients and the removal efficiencies of COD and TKN at five different MLSS concentrations of 5000, 4200, 3300, 2600, and 1900 mg/L for synthetic wastewater. Mathematical equations were presented to permit complete evaluation of the this system. Kinetic behaviors for the organic removal and nitrification reaction were examined by the determined kinetic coefficient and the assumed operation condition and the predicted model formulae using kinetic approach. The conclusions derived from this experimental research were as follows : 1. Biological kinetic coefficients were Y=0.563, $k_d=0.054(day^{-1})$, $K_S=49.16(mg/L)$, $k=2.045(day^{-1})$ for the removal of COD and $Y_N=0.024$, $k_{dN}=0.0063(day^{-1})$, $K_{SN}=3.21(mg/L)$, $k_N=31.4(day^{-1})$ for the removal of TKN respectively. 2. The predicted kinetic model formulae could determine the predicted concentration of the activated sludge and nitrifier, investigate the distribution rate of input carbon and nitrogen in relation to the solid retention time (SRT).