• Journal of Electrochemical Science and Technology
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• 제2권1호
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• pp.26-31
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• 2011

We have prepared siloxane polymers grafted with trifluoromethane-sulfonylamide and oligoether side chains for solid polymer electrolytes with enhanced ionic conductivity. The grafted trifluoromethane sulfonylamide groups seem to be effective as an anion recepting site to enhance the ionic conductivity of the solid polymer electrolyte. The anion receptor grafted siloxane polymers showed one order of magnitude higher ionic conductivity than the siloxane polymers without anion receptor grafts. The fitting parameter A of the VTF plot which was related to the carrier density of the electrolyte increased with increasing the number of grafted anion receptor. The results of experiment indicate that the anion-complexing site of the anion receptor grafted polymer host effectively traps the anions. The anion receptor grafted polymer was found to be a promising material for lithium polymer batteries.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.63-64
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• 2006

The solid state dye-sensitized solar cells (DSSCs) employing polymer electrolytes show high overall energy conversion efficiency as high as 4.5 % at 1 sun conditions. The improved efficiency may be primarily due to the enlarged interfacial contact area between the electrolyte and dyes in addition to the increased ionic conductivity, which were done by utilizing liquid oligomers, followed by in situ self-solidification, to form the solid DSSCs: "Oligomer Approach". The effect of the charge transfer resistance at the counter electrode side on the efficiency has also been investigated.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2007년도 춘계학술대회
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• pp.231-234
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• 2007

The solid state dye-sensitized saolrc cells (DSSCs) employing polymer electrolytes show high overall energy conversion efficiency as high as 4.5% at 1 sun conditions. The improved efficiency may be primarily due to the enlarged interfacial contact area between the electrolyte and dyes in addition to the increased ionic conductivity, which were done by utilizing liquid oligomers, followed by in situ self-solidification, to form the solid DSSCs "Oligomer Approach". The effect of the charge transfer resistance at the counter electrode side on the effciency has also been investigated.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.275-275
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• 2006

A series of organoboron polymer electrolytes were prepared and their ion conductive characteristics was investigated in detail. Alkylborane type polymer electrolytes prepared by hydroboration polymerization exhibited improve lithium transference number due to efficient anion trapping of alkylborane unit. A lithium borate type polymer/salt hybrid was also successfully prepared by dehydrocoupling polymerization of lithium mesitylhydrorate. Ionic conductivity of single ion conductive polymer/salt hybrid was further improved in the case of comb like polymer/boron stabilized imido anion hybrid prepared via polymer reaction of poly(organoboron halide) with hexylamine and PEO monomethylether and subsequent neutralization with lithium hydride.

• Journal of Electrochemical Science and Technology
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• 제8권3호
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• pp.257-264
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• 2017

A polymeric ionic liquid, poly(1-methyl 3-(2-acryloyloxypropyl) imidazolium iodide) (PMAPII), was synthesized as a single-iodide-ion-conducting polymer and employed in a gel polymer electrolyte. Gel polymer electrolytes prepared from iodine, 4-tert-butylpyridine, ${\gamma}$-butyrolactone, and PMAPII were applied in quasi-solid-state dye-sensitized solar cells (DSSCs). The addition of 16 wt.% PMAPII provided the most favorable environment, striking a compromise between the iodide ion concentration and the ionic mobility, which resulted in the highest conversion efficiency of the resulting DSSCs. The quasi-solid-state DSSC assembled with the optimized gel polymer electrolyte exhibited a relatively high conversion efficiency of 7.67% under AM 1.5 illumination at $100mA\;cm^{-2}$ and better stability than that of the DSSC with a liquid electrolyte.

• Journal of Electrochemical Science and Technology
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• 제9권2호
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• pp.126-132
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• 2018

For the first time, an innovative approach using P(VDF-TrFE) as a polymer electrolyte for high efficiency, all-solid-state supercapacitors is presented. The polymer electrolyte was successfully achieved by dissolving P(VDF-TrFE) copolymers in dimethylformamide (DMF). Thermal analysis and infrared spectroscopy revealed excellent thermal stability up to $400^{\circ}C$ and copolymer's interaction with DMF. Electrochemical capacitors fabricated using P(VDF-TrFE) in DMF and ZnO NWs demonstrated high capacitive performance. Furthermore, the gel electrolyte-based supercapacitors demonstrated excellent mechanical durability up to a bend angle of $120^{\circ}$. Novel P(VDF-TrFE) electrolytes could be a promising approach for applications in flexible, fabric-based, and high-efficiency energy devices.

• 한국세라믹학회지
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• 제32권2호
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• pp.155-162
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• 1995

Solid oxide electrolytes of the MCe1-xGdxO3-x/2 (M: Ba, Mg. x=0.0-0.20) system were prepared using powders synthesized by the "liquid mix" method and calcined from the cross-linked polyacrylic polymer. The specimens were analyzed using XRD and SEM with EDX, and the sintering behavior of the electrolytes and their electrical conductivity were also studied. Although Mg-cerate is relatively inferior to Ba-cerate in the sinterability and chemical homogenity(EDX analysis data), both the Ba- and the Mg-cerate electrolytes at 80$0^{\circ}C$ show their maximum conductivities at x=0.10 and their values are in the same order of magnitude, i.e., 3.5$\pm$0.17.10-2(ohm.cm)-1.ohm.cm)-1.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.67-68
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• 2006

Solid polymer electrolyte is very important in the applications to high energy density lithium batteries of high safety. In this work, solid polymer electrolytes based on PE non-woven matrix, hybrid salt, and anion receptor were successfully prepared. They could provide high ion conduction phase with maintaining mechanical strength. They also showed high electrochemical stability and lithium ion transference number. This new type of solid polymer electrolyte is expected to be a good candidate for rechargeable solid state lithium secondary batteries.

• 전기화학회지
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• 제14권4호
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• pp.208-213
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• 2011

합성된 $BF_3LiMA$ 리튬염을 단량체로 사용하는 고체 고분자전해질을 제조하고 $BF_3LiMA$의 농도가 이온전도도에 미치는 영향 및 전기화학적 안정성을 교류임피던스 측정법과 선형전위주사법을 통하여 평가하였다. 그 결과 $BF_3LiMA$가 12.9 wt%인 고체 고분자전해질에서 $7.71{\times}10^{-6}S\;cm^{-1}$의 가장 높은 $25^{\circ}C$ 이온전도도가 관찰되었으며 이 값을 전후로 이온전도도는 다소 감소하는 경향이 나타났다. 이러한 결과는 저농도의 $BF_3LiMA$에서 발생할 수 있는 리튬염의 부족과 고농도의 $BF_3LiMA$에서는 발생할 수 있는 고분자기질의 유동성 감소가 원인으로 해석된다. 또한 $BF_3LiMA$ 기반의 고체 고분자전해질은 음이온이 고정되어 있는 자기-도핑형 계열로서 $60^{\circ}C$에서 6.0 V까지 우수한 전기화학적 안정성을 보여주었다.

• 폴리머
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• 제34권4호
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• pp.357-362
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• 2010

Poly(ethyleneglycol diacrylate)(PEGDA) 혹은 2-ethylhexyl acrylate(2EHA)를 기반으로 하는 고체함 량 8~54 wt%의 젤 고분자 전해질(GPE)을 합성하여 상온 이온전도도 및 전기화학적 특성을 평가하였다. 그 결과 투명하고 균일한 젤을 형성하는 21 wt%의 PEGDA계에서 $1\times10^{-3}$ S/cm 이상의 높은 상온 이온전도도를 얻을 수 있었다. 하지만 GPE는 액체전해액에 비해 낮은 전압안정성을 보여주었는데, 고분자 합성과정에서 개시제인 AIBN 에 원인이 있음을 제안하였다. 그 결과 BPO를 개시제로 사용하여 전압안정성이 향상된 GPE를 확보할 수 있었다. 또한 음극에서 리튬이온의 삽입과 탈리가 용이하면서 환원분해전위에 안정한 계면피막이 형성되었음을 확인하였다.