• 제목/요약/키워드: solid complex

검색결과 601건 처리시간 0.029초

고체추진제의 연소속도 증진기술 (Increasing the burning rate of solid propellants)

  • 김준형;임유진;김인철;박영철;서태석;정정용;유지창
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2009년도 춘계학술대회 논문집
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    • pp.169-172
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    • 2009
  • 본 연구에서는 고연소속도 고체추진제 개발을 위한 현재의 기술들과 연구동향을 분석하였고, 연소속도 조절제에 대한 추진제 적용 및 연소 특성에 대해 검토하였다. 또한 연소속도 조절제로bis(ethylenediamine)copper perchlorate(BECP)를 제조하였고 이의 연소특성이 Butacene/AP 추진제에서 평가되었다. 결과적으로, Butacene과 AP로 구성된 고연소속도 고체 추진제에서 금속배위화합물인 BECP는 고체추진제의 연소속도를 크게 증진시켰다.

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고상법을 활용한 리튬이차전지 폐양극활물질 재활용 기술 연구 (Research on recycling technology for spent cathode materials of lithium-ion batteries using solid-state synthesis)

  • 강동훈;임주원;고민성
    • 한국표면공학회지
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    • 제56권4호
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    • pp.259-264
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    • 2023
  • As the demand for lithium-ion batteries, a key power source in electric vehicles and energy storage systems, continues to increase for achieving global carbon neutrality, there is a growing concern about the environmental impact of disposing of spent batteries. Extensive research is underway to develop efficient recycling methods. While hydrometallurgy and pyrometallurgy methods are commonly used to recover valuable metals from spent cathode materials, they have drawbacks including hazardous waste and complex processes. Hence, alternative recycling methods that are environmentally friendly are being explored. However, recycling spent cathode materials still remains complex and energy-intensive. This study focuses on a novel approach called solid-state synthesis, which aims at regenerating the performance of spent cathode materials. The method offers a simpler process and reduces energy consumption. Optimal heat treatment conditions were identified based on experimental results, contributing to the development of sustainable recycling technologies for lithium-ion batteries.

오디의 안토시아니딘에 구리를 이용한 착화합물 합성 및 상주실크에 천연염색 (Analysis of Anthocyanidin in Mulberry of Cu Complex Compound and Natural Dyeing on Sangju Silk)

  • 이광우
    • 한국산업융합학회 논문집
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    • 제13권4호
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    • pp.191-196
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    • 2010
  • This study explores the solution of a variety of conditions of the natural dyeing with the Mulberry. To obtain this, the Cu complex compound was added into the extracts. The Mulberry extract was added the Copper acetate to obtain the Black sediment the metal complex compound of anthocyanidin. According to the result of using the complex compound of the solid material, the dyeing properties were excellent. The metal complex compound acted as a mordant, thus it reduced the process of mordanting in the natural dying.

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클로로프로파미드와 싸이클로덱스트린과의 포접 화합물에 관한 연구 (Inclusion Complexation of Chlorpropamide with Cyclodextrins)

  • 정경혜;김길수;구영순
    • 약학회지
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    • 제30권2호
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    • pp.87-95
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    • 1986
  • Inclusion complexation of $\alpha$-cyclodextrin($\alpha$-CD), $\beta$-cyclodextrin($\beta$-CD) and tri-O-methyl-$\beta$-cyclodextrin(tri-O-methyl-$\beta$-CD) with chlorpamide(CPA) in aqueous solution and in the solid state were studied by the solubility method, spectroscopy (UV, IR), differential scanning calorimetry (DSC) and powder X-ray diffractometry, and all their molar ratios were found to be 1:1. The solid complexes of CPA with three kinds of cyclodextrins were prepared by a freezedrying method, and their dissolution behaviors were examined. As a result, the release of CPA from the inclusion complexes was significantly improved. The intrinsic dissolution rate of CPA in cyclodextrin inclusion complexes was about 51 times ($\alpha$-CD inclusion complex) and 12 tmies ($\beta$-CD inclusion complex) larger than that of intact CPA.

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Spectrophotometric Determination of Palladium after Solid-liquid Extraction with 4-(2-Pyridylazo)-resorcinol at 90°C

  • Dong, Yanjie;Gai, Ke
    • Bulletin of the Korean Chemical Society
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    • 제26권6호
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    • pp.943-946
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    • 2005
  • An effective spectrophotometric determination of palladium with 4-(2-pyridylazo)-resorcinol (PAR) using molten naphthalene as a diluent has been studied. A red complex of palladium with PAR is formed at 90 ${^{\circ}C}$. In the range of pH 9.0-11.0, the complex is quantitatively extracted into molten naphthalene. The organic phase is anhydrously dissolved in $CHCl_3$ to be determined spectrophotometrically at 520 nm against the reagent blank. Beer’s law is obeyed over the concentration range of 0.1-2 ${\mu}g{\cdot}mL^{-1}$. The molar absorptivity and Sandell’s sensitivity are 8.0 ${\times}\;10^5\;L{\cdot}mol^{-1}{\cdot}cm^{-}1\;and\;0.49\;{\mu}g{\cdot}cm^{-2}$ respectively. From the results of tolerance limits, it was found that there was no interferences were observed for most of the ions examined and those somewhat high interferences by Co(II), Fe(II) and Bi(III) could be effectively masked by EDTA.

Topical delivery of smad3 antisense using cationic solid lipid nanoparticle(SLN): therapeutic potential use and prevention of keloids

  • Jin, Su-Eon;Park, Jeong-Sook;Kim, Chong-Kook
    • 대한약학회:학술대회논문집
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    • 대한약학회 2003년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.2-2
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    • pp.248.1-248.1
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    • 2003
  • Keloids are characterized by abnormal proliferation of fibroblasts and overproduction of collagen. Recently, it is reported that transforming growth factor beta (TGFb) and its signaling molecule, SMAD3 are related to the mitogenic effect of fibroblasts and a stimulatory factor for collagen synthesis. Cationic SLN was developed to improve the complex formation of DNA/SLN and enhance the uptake efficiency to cells. SLN was formulated by DC-Chol, DOPE, trimyristin as a solid core and other surfactant. The physical properties of the SLN and the ATS-SLN complex were characterized. (omitted)

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Isogeometric analysis of the seismic response of a gravity dam: A comparison with FEM

  • Abdelhafid Lahdiri;Mohammed Kadri
    • Advances in Computational Design
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    • 제9권2호
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    • pp.81-96
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    • 2024
  • Modeling and analyzing the dynamic behavior of fluid-soil-structure interaction problems are crucial in structural engineering. The solution to such coupled engineering systems is often not achievable through analytical modeling alone, and a numerical solution is necessary. Generally, the Finite Element Method (FEM) is commonly used to address such problems. However, when dealing with coupled problems with complex geometry, the finite element method may not precisely represent the geometry, leading to errors that impact solution quality. Recently, Isogeometric Analysis (IGA) has emerged as a preferred method for modeling and analyzing complex systems. In this study, IGA based on Non-Uniform Rational B-Splines (NURBS) is employed to analyze the seismic behavior of concrete gravity dams, considering fluid-structure-foundation interaction. The performance of IGA is then compared with the classical finite element solution. The computational efficiency of IGA is demonstrated through case studies involving simulations of the reservoir-foundation-dam system under seismic loading.

자유 곡면으로 구성되는 3차원 구조물에 대한 자동 요소 분할 (Automatic Mesh Generation for Three-Dimensional Structures Consisting of Free-Form Surfaces)

  • 이준성;;박면웅
    • 한국CDE학회논문집
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    • 제1권1호
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    • pp.65-75
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    • 1996
  • This paper describes an automatic finite element(FE) mesh generation for three-dimensional structures consisting of free-form surfaces. This mesh generation process consists of three subprocesses: (a) definition of geometric model, i.e. analysis model, (b) generation of nodes, and (c) generation of elements. One of commercial solid modelers is employed for three-dimensional solid and shell structures. Node is generated if its distance from existing node points is similar to the node spacing function at the point. The node spacing function is well controlled by the fuzzy knowledge processing. The Delaunay method is introduced as a basic tool for element generation. Automatic generation of FE meshes for three-dimensional solid and shell structures holds great benefits for analyses. Practical performances of the present system are demonstrated through several mesh generations for three-dimensional complex geometry.

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F$\ddot{o}$rst energy transfer 를 적용한 준고체 DSSC 의 효율향상 (Enhanced Light Harvesting from F$\ddot{o}$rst-type resonance Energy Transfer in the Quasi-Solid State Dye-Sensitized Solar Cells)

  • 천종훈;이정관;양현석;김재홍
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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    • pp.117.1-117.1
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    • 2011
  • We have demonstrated Forst-type resonance energy transfer (FRET) in the quasi-solid type dye-sensitized solar cells between organic fluorescence materials as an energy donor doped in polymeric gel electrolyte and ruthenium complex as an energy acceptor on surface of $TiO_2$. The strong spectral overlap of emission/absorption of energy donor and acceptor is required to get high FRET efficiency. The judicious choice of energy donor allows the enhancement of light harvesting characters of energy acceptor in quasi-solid dye sensitized solar cells which increase the power conversion efficiency. The enhanced light harvesting effect by the judicious choice/design of the fluorescence materials and sensitizing dyes permits the enhancement of photovoltaic performance of DSSC.

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Development of High-Performance FEM Modeling System Based on Fuzzy Knowledge Processing

  • Lee, Joon-Seong
    • International Journal of Fuzzy Logic and Intelligent Systems
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    • 제4권2호
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    • pp.193-198
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    • 2004
  • This paper describes an automatic finite element (FE) mesh generation for three-dimensional structures consisting of tree-form surfaces. This mesh generation process consists of three subprocesses: (a) definition of geometric model, (b) generation of nodes, and (c) generation of elements. One of commercial solid modelers is employed for three-dimensional solid structures. Node is generated if its distance from existing node points is similar to the node spacing function at the point. The node spacing function is well controlled by the fuzzy knowledge processing. The Voronoi diagram method is introduced as a basic tool for element generation. Automatic generation of FE meshes for three-dimensional solid structures holds great benefits for analyses. Practical performances of the present system are demonstrated through several mesh generations for three-dimensional complex geometry.