• Title/Summary/Keyword: solid complex

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A resistivity anomaly at 380 K in reproduced LK-99

  • Sangjin Kim;Kwang-Tak Kim;Jeonghun Kang;Dong-Hyeon Gim;Yoon Han Lee;Kee Hoon Kim
    • Progress in Superconductivity and Cryogenics
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    • v.25 no.4
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    • pp.10-13
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    • 2023
  • To confirm the room-temperature superconductivity at ambient pressure as claimed in recent arXiv preprints by Lee et al., we followed the original authors' systematic solid-state synthesis recipe to reproduce Cu-doped Pb-apatite, known as LK-99. Using X-ray diffraction and Raman spectroscopy, we identified inclusion of various impurities alongside the apatite phase in our sample. While the sample exhibited an overall semiconducting behavior in electrical transport, an intriguing resistivity anomaly at 380 K was observed, possibly originating from a structural phase transition of the Cu2-δS impurity. Based on the transport and magnetization measurements, we conclude that the sample is a non-magnetic semiconductor, with absence of superconductivity.

Numerical and Experimental Study of Semi-solid A356 Aluminum Alloy in Rheo-Forging process

  • Kim, H.H.;Kang, C.G.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.10a
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    • pp.371-374
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    • 2009
  • Die casting process has been used widely for complex automotive products such as the knuckle, arm and etc. Generally, a part fabricated by casting has limited strength due to manufacturing defects by origin such as the dendrite structure and segregation. As an attempt to offer a solution to these problems, forging has been used as an alternative process. However, the forging process provides limited formability for complex shape products. Rheo-forging of metal offers not only superior mechanical strength but also requires significantly lower machine loads than solid forming processes. This paper presents the results of an A356 aluminum alloy sample, which were obtained by experiment and by simulation using DEFORM 3D. Samples of metal parts were subsequently fabricated by using hydraulic press machinery.

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The Design and Implementation of Implicit Object Classes for Geometric Modeling System (형상 모델링을 위한 음함수 객체의 설계 및 구현)

  • Park, Sang-Kun;Chung, Seong-Youb
    • Korean Journal of Computational Design and Engineering
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    • v.13 no.3
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    • pp.187-199
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    • 2008
  • This paper describes a C++ class hierarchy of implicit objects for geometry modeling and processing. This class structure provides a software kernel for integrating many various models and methods found in current implicit modeling areas. The software kernel includes primitive objects playing a role of unit element in creating a complex shape, and operator objects used to construct more complex shape of implicit object formed with the primitive objects and other operators. In this paper, class descriptions of these objects are provided to better understand the details of the algorithm or implementation, and its instance examples to show the capabilities of the object classes for constructive shape geometry. In addition, solid modeling system shown as an application example demonstrates that the proposed implicit object classes allow us to carry out modern solid modeling techniques, which means they have the capabilities to extend to various applications.

Pharmaceutical Studies on Improved Bioavailability of Indoprofen by ${\beta}-Cyclodextrin$ Complexation ( II ) (난용성약물(難溶性藥物)인 Indoprofen의 ${\beta}-Cyclodextrin$복합체(複合體) 형성(形成)에 따른 생체이용률(生體利用率)의 개선(改善)에 관한 약제학적(藥劑學的) 연구(硏究) (제2보)(第二報))

  • Han, Kun;Lee, Min-Hwa;Kim, Shin-Keun
    • Journal of Pharmaceutical Investigation
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    • v.14 no.1
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    • pp.19-30
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    • 1984
  • The pharmaceutical characteristics of solid indoprofen inclusion complex such as dissolution, permeation through a cellophane membrane, model analysis of interfacial tranesfer, absorption behaviors in rat intestine, and the plasma concentration of indoprofen after oral administrations to rabbits were examined in comparison with those indoprofen alone. The inclusion complex obtained by freeze-drying method showed the higher dissolution rate and membrane permeability among the test powders, and increased significantly the amont of indoprofen absorbed in rat intestine and the levels of plasma concentration of indoprofen after oral adminstrations to rabbits. The increase of bioavailability of $indoprofen-{\beta}-cyclodextrin$ complex was considered due to the increased solubility and dissolution rate of solid powder form.

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Solid Particle Behavior Analysis in Rheology Material by Fortran 90 (레오로지 소재의 고상입자 변형거동 해석)

  • Kwon, K.Y.;Kang, C.G.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.10a
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    • pp.234-237
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    • 2008
  • It was reported that the semi-solid forming process has many advantages over the conventional forming process, such as a long die life, good mechanical properties and energy savings. It is very important, however, to control liquid segregation to gain mechanical property improvement of materials. During forming process, Rheology material has complex characteristics, thixotropic behavior. Also, difference of velocity between solid and liquid in the semi-solid state material makes a liquid segregation and specific stress variation. Therefore, it is difficult for a numerical simulation of the rheology Process to be Performed. General Plastic or fluid dynamic analysis is not suitable for the behavior of rheology material. The behavior and stress of solid particle in the rheology material during forging process is affected by viscosity, temperature and solid fraction. In this study, compression experiments of aluminum alloy were performed under each other tool shape. In addition, the dynamics behavior compare with Okano equation to Power law model which is viscosity equation.

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Decomposition-Based Simplification of Machined Part in Solid Model (볼륨분해를 이용한 절삭가공부품 솔리드 모델의 단순화)

  • Woo, Yonn-Hwan
    • Korean Journal of Computational Design and Engineering
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    • v.12 no.2
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    • pp.101-108
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    • 2007
  • As 3D solid modeling has been widely used in designing products, solid models of the products are directly used in various applications such as engineering analysis and process planing. However, the fully-detailed solid models may not be necessary in some application. For example, it is often more efficient to use simplified model of part of engineering analysis. Generation of mesh for the complex original model requires a quite amount of time, and the consequence of finite element analysis may not be desirable due to small and detailed geometry in the model. In this paper, a method to simplify solid models of machined part is presented. This method decomposes the delta volume of machined part, and uses the decomposed volumes to simplify the solid model. Since this method directly recognizes the features to be removed from the final model, it is independent of not only design features of specific CAD system, but also designer's design practice of design sequences.

Thixoforging Process of Rheology Materials fabricated by Spiral Mechanical Stirring (나선형 기계 교반 레오로지 소재의 이용한 Thixoforging 공정)

  • Han, S.H.;Jung, I.K.;Bae, J.W.;Kang, C.G.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2007.05a
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    • pp.131-134
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    • 2007
  • A semi-solid forming technology has a lot of advantages compared to the die casting, squeeze casting and hot/cold forging, so semi-solid forming has been studied actively. Semi-solid forming has two methods. One is thixoforming with reheating of prepared billet, the other is rheoforming with cooled melt until semi-solid state. Thixoforging technology can produce non-dendritic alloys for semi-solid forming complex shaped parts in metal alloys. In this study, the thixoforging was experimented with made rheology materials by the spiral stirrer equipment. Rheology materials for forging were made by A356 casting aluminum alloy and A6061 wrought aluminum alloy. After experiment, forged samples were measured microstructure and were heat treated for high mechanical properties.

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Modeling of 2D/3D Solid Rocket Combustion Using Preconditioning Method (예조건 알고리즘을 적용시킨 고체로켓의 2D/3D 연소해석)

  • Lee, S.N.;Baek, S.W.
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03b
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    • pp.547-550
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    • 2008
  • A solid rocket motor has quite complex physical condition such exothermal chemical reaction in subsonic area and supersonic ex pansion in a converging-diverging nozzle. To introduce a simulation tool for compressible flow in supersonic range as well as incompressible chemical reaction zone in a whole rocket nozzle is a essential demand. Since the flow vary subsonic to super sonic, the convergence in computation becomes very low and unstable in a whole domain of rocket motor. This paper reports the 2-D Axisymmetric and simple 3-D solid propellant combustion and flow of gases in rocket motor by using a precondi tioning, shear stress turbulence modeling, AUSM(p). To simulate the simplified combustion process, Double base solid propellant is used to calculate reaction of solid propellant.

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Molecular Recognition : ${\alpha}$-Cyclodextrin and Aspirin Inclusion Complexation

  • Hee Sook Choi
    • Bulletin of the Korean Chemical Society
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    • v.13 no.5
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    • pp.474-479
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    • 1992
  • Molecular interaction between ${\alpha}$-cyclodextrin and aspirin was studied by UV, $^2H$-NMR and $^2H$-NMR spectroscopy analyses for solution complex and by FT-IR analyses for solid complex. The inclusion structure provides a basic understanding of the aspirin and ${\alpha}$-cyclodextrin interaction.

Method for Measurement of Complex Relative Permittivity of Semi-Solid Materials Using Novel Cavity Resonator Design (캐비티 공진기를 이용한 반고체 상태 물질의 복소 비유전율 측정 방법)

  • Park, Rae-Seoung;Jang, Jihyun;Park, Byungdeok;Kim, Junhwan;Park, Sangbok;Chung, Young-Seek;Cheon, Changyul
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.25 no.8
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    • pp.872-878
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    • 2014
  • This paper proposes a measurement method of the complex relative permittivity of semi-solid materials using a new cavity structure. Semi-solid materials are positioned in the proposed cavity where an aperture exists on each corner of the upper part and a ground plane is separated. In order to show the validation of the proposed method, we measured the complex relative permittivity of distilled water and 0.9 % saline by sensing a shift of resonant frequency and using Critical-Points Method, and compared the results with those derived from the Cole-Cole equation.