• Korean Chemical Engineering Research
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• v.47 no.3
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• pp.337-343
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• 2009

To apply to novel two-interconnected fluidized beds system for selective solid circulation, a solid separator and a solid circulation system were developed. The solid separation rate increased as the gas velocity through the solid injection nozzle, solid height, and diameter of solid injection nozzle increased. However, the effect of the fluidization velocity was negligible. Coarse($212{\sim}300{\mu}m$) and fine($63{\sim}106{\mu}m$) particles were separated using the solid separator and the solid separation rate was ranged from 66 to 453 g/min. The solid circulation rate increased as the gas velocity through the solid injection nozzle, solid height, and the number of solid intake holes increased. However, the effect of the fluidization velocity was negligible. Fine particle was circulated using the solid circulation system and the solid circulation rate was ranged from 65 to 390 g/min. We also proposed two interconnenced fluidized beds system for selective solid circulation equipped with the developed solid separator and the solid circulation system. Long-term operation of continuous solid circulation up to 20 hours has been performed to check feasibility of stable operation. The pressure drop profiles in two beds and the solid separation rate were maintained steadily, and therefore, we could conclude that solid circulation was smooth and stable.

• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.393-397
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• 2001

The innovatory process, that is the direct separation and recovery of the iron and zinc metals contained in the high temperature exhaust gas generated from the electric arc furnace fer the inn scrap melting and/or the dust treatment, has been proposed. This proposed process consists of the moving coke bed filter that is directly connected to the electric furnace, and the following heavy metal condenser. The exhaust gas passes through the filter and the condenser right after exhausting from the electric furnace. The moving coke bed filter is being controlled at about 1000℃ and collects iron and slag components contained in the high temperature exhaust gas. Heavy metals such as zinc and lead pass through the filter as vapor. Based on the thermodynamic considerations, the iron oxide and the zinc oxide are reduced in the filter. The solution loss reaction rate is comparatively low at about 1000℃ in the coke bed filter by the analysis using the mathematical simulation model. The heavy metal condenser is installed in the position after the coke bed filter, and rapidly cools the gas from about 1000℃ to 450℃ by a full of the cooling medium like the solid ceramic ball in addition to the cooling from the wall. The zinc and lead vapor condense and separate f개m the gas in a liquid state. The investigation of the characteristics of the exhaust gas of the commercial electric arc furnace, the fundamental experiments of the laboratory scale and the bench scale ensured the formation of this proposed process. A small-scale pilot plant examination is carrying out at present to confirm the formation of the process. It is certain that the dust generation of the electric arc furnace is extremely decreased, and it can save the energy consumption of usual dust treatment processes by the realization of this process.

• Advances in environmental research
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• v.3 no.3
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• pp.231-251
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• 2014

The present study examines the phosphate adsorption potential and behavior of mixture of Ground Burnt Patties (GBP), a solid waste generated from cooking fuel used in earthen stoves and Red Soil (RS), a natural substance in fixed bed column mode operation. The characterization of adsorbent was done by Proton Induced X-ray Emission (PIXE), and Proton Induced ${\gamma}$-ray Emission (PIGE) methods. The FTIR spectroscopy of spent adsorbent reveals the presence of absorbance peak at $1127cm^{-1}$ which appears due to P = O stretching, thus confirming phosphate adsorption. The effects of bed height (10, 15 and 20 cm), flow rate (2.5, 5 and 7.5 mL/min) and initial phosphate concentration (5 and 15 mg/L) on breakthrough curves were explored. Both the breakthrough and exhaustion time increased with increase in bed depth, decrease in flow rate and influent concentration. Thomas model, Yoon-Nelson model and Modified Dose Response model were used to fit the column adsorption data using nonlinear regression analysis while Bed Depth Service Time model followed linear regression analysis under different experimental condition to evaluate model parameters that are useful in scale up of the process. The values of correlation coefficient ($R^2$) and the Sum of Square Error (SSE) revealed the Modified Dose Response model as the best fitted model to the experimental data. The adsorbent mixture responded effectively to the desorption and reusability experiment. The results of this finding advocated that mixture of GBP and RS can be used as a low cost, highly efficient adsorbent for phosphate removal from aqueous solution.

• Carbon letters
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• v.7 no.3
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• pp.180-187
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• 2006

The treatment of piggery wastes was carried out at pilot scale using a multilayered metal-activated carbon system followed by carbon bed filtration. The physicochemical properties were obtained from treated samples with aqueous solutions containing metallic ions such as $Ag^+$, $Cu^{2+}$, $Na^+$, $K^+$ and $Mn^{2+}$, which main obsevations are subjected to inspect surface properties, color removal properties by Uv/Vis and EDX. Multilayered metal-activated carbons were contacted with waste water to investigation of the simultaneous catalytic effect for the COD, BOD, T-N and T-P removal. The removal results for the piggery waste using multilayered metal-activated carbon bed was achieved the satisfactory removal performance under permitted values of Ministry of Environment of Korea. The high efficiency of the multilayered metal-activated carbon bed was determined by the performance of this material for trapping, catalytic effect and adsorption of organic solid particles.

• Food Science and Biotechnology
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• v.18 no.5
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• pp.1071-1075
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• 2009

Allyl isothiocyanate (AI), a volatile compound of mustard, has excellent antimicrobial effects, but its volatility hinders its wide usage as an ingredient of food products. Microencapsulation technique, therefore, was applied for delaying the release time of AI. For delaying the release time of AI, the mustard powder, which contained AI, was microencapsulated with 5% modified starch by using fluidized bed processing. The efficiency of the controlled release of AI at various pH was analyzed by the head space (HS) analysis and solid phase microextraction (SPME) method using gas chromatography (GC). Also, modified starch encapsulated powder was added into kimchi for applying in food industry. As the result, the release time of AI was delayed by microencapsulation with modified starch and the higher pH could be the faster release of AI. Also, the period until the pH values and total acidity of kimchi reached up to 4.5 and 0.6%, which give its malsour taste, was extended by microencapsulation. These results showed that modified starch encapsulated powder could prolong the preservation in food system.

• Journal of the Korean Society of Safety
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• v.14 no.1
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• pp.78-85
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• 1999

The removal characteristics of H$_2$S from IGCC process over the natural manganese ore(NMO) containing several metal oxides($MnO_x$ : 51.85%, $FeO_y$ : 3.86%, CaO : 0.11%) were carried out in a batch type fluidized bed reactor(I.D.=40mm, height=0.8m). The $H_2S$ breakthrough curves were obtained as a function of temperature, initial gas velocity, initial gas concentration, and aspect ratio. The effect of particle size ratio and particle mixing fraction on $H_2S$ removal were investigated with binary system of different particle size. From this study, the adsorption capacity of $H_2S$ increased with temperature but decreased with excess gas velocity. The breakthrough time for $H_2S$ is reduced as the gas velocity is increased which leaded to gas by-passing and gas-solid contacting in a fluidized bed reactor. The results of the binary particle system with different size in batch experimental could predict to improve the behavior of continuous process of $H_2S$ removal efficiency. The natural manganese ore could be considered as potential sorbent in $H_2S$ removal.

• Journal of Industrial and Engineering Chemistry
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• v.67
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• pp.219-230
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• 2018

The present study examined a moving bed biofilm reactor (MBBR) bioreactor on a laboratory scale for simultaneous removal of atrazine, organic carbon, and nutrients from wastewater. The maximum removal efficiency of atrazine, chemical oxygen demand (COD), total phosphorus (TP) and total nitrogen (TN) were 83.57%, 90.36%, 90.74% and 87.93 respectively. Increasing salinity up to 40 g/L NaCl in influent flow could inhibit atrazine biodegradation process strongly in the MBBR reactor.Results showed that MBBR is so suitable process for efficiently biodegrading of atrazine and nitrogen removal process was based on the simultaneous nitrification-denitrification (SND) process.

• Nuclear Engineering and Technology
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• v.56 no.3
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• pp.959-965
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• 2024

The High Temperature Test Unit (HTTU) was an experimental set-up to conduct separate and integral effects tests of the Pebble Bed Modular Reactor (PBMR) core. The annular core consisted of a randomly packed bed of uniform spheres. Natural convection tests using both nitrogen and helium, and forced convection tests using nitrogen, were conducted. The maximum material temperature achieved during forced convection testing was 1200 ℃. This paper presents the numerical analysis of the flow and temperature distribution for a forced convection test using 3D CFD as well as a 1D systems-CFD computer code. Several modelling approaches are possible, ranging from a fully explicit to a semi-implicit method that relies on correlations of their associated phenomena. For the comparison between codes, the analysis was performed using a porous media approach, where the conduction and radiative heat transfer were lumped together as an effective thermal conductivity and the convective heat transfer was correlated between the solid and gas phases. The results from both codes were validated against the experimental measurements. Favourable results were obtained, in particular by the systems-CFD code with minimal computational and time requirements.

• Korean Chemical Engineering Research
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• v.60 no.4
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• pp.535-543
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• 2022

A CPFD (Computational particle fluid dynamics) model of solar fluidized bed receiver of silicon carbide (SiC: average d_p=123 ㎛) particles was established, and the model was verified by comparing the simulation and experimental results to analyze the effect of particle behavior on the performance of the receiver. The relationship between the heat-absorbing performance and the particles behavior in the receiver was analyzed by simulating their behavior near bed surface, which is difficult to access experimentally. The CPFD simulation results showed good agreement with the experimental values on the solids holdup and its standard deviation under experimental condition in bed and freeboard regions. The local solid holdups near the bed surface, where particles primarily absorb solar heat energy and transfer it to the inside of the bed, showed a non-uniform distribution with a relatively low value at the center related with the bubble behavior in the bed. The local solid holdup increased the axial and radial non-uniformity in the freeboard region with the gas velocity, which explains well that the increase in the RSD (Relative standard deviation) of pressure drop across the freeboard region is responsible for the loss of solar energy reflected by the entrained particles in the particle receiver. The simulation results of local gas and particle velocities with gas velocity confirmed that the local particle behavior in the fluidized bed are closely related to the bubble behavior characterized by the properties of the Geldart B particles. The temperature difference of the fluidizing gas passing through the receiver per irradiance (∆T/I_DNI) was highly correlated with the RSD of the pressure drop across the bed surface and the freeboard regions. The CPFD simulation results can be used to improve the performance of the particle receiver through local particle behavior analysis.

• 한국연소학회:학술대회논문집
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• 2014.11a
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• pp.165-166
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• 2014

The application of particle reaction model in the packed bed process modeling is discussed for iron ore pellet induration process. Combustion of coke breeze in the pellet is estimated by using shrinking unreacted-core model and grain model in which the progress of chemical reaction is described in different concepts. Under the identical inlet gas and solid conditions, the calculation using shrinking core model showed deviated results in terms of temperature profile and conversion fraction, which may imply the significance of selecting proper particle reaction model in consideration of particle characteristics and process operation conditions.