• 제목/요약/키워드: soil solution concentration

검색결과 448건 처리시간 0.025초

석탄(石灰) 및 전분첨가(澱粉添加)에 따른 침수(湛水) 토양(土壤)의 규산흡수량(珪酸吸收量) 및 흡착특성(吸着特性) 변화(變化) (The Effect of Additions of Lime and Starch on the Silica Sorption Characteristics in Submerged Paddy Soil)

  • 윤정희;황기성
    • 한국토양비료학회지
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    • 제17권1호
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    • pp.35-38
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    • 1984
  • 실험실내(實驗室內)에서 유효규산함량(有效珪酸含量)이 다른 2개(個) 식양질(埴壤質) 토양(土壤)에 석회(石灰)와 전분(澱粉)을 첨가(添加)하고 $25^{\circ}C$로 1개월간(個月間) 담수항온(湛水恒溫) 처리(處理)한 뒤 토양(土壤)의 유효규산(有效珪酸)과 수용성(水溶性) 규산(珪酸)의 행동(行動)을 조사(調査)한 결과(結果)는 다음과 같다. 1. 담수토양(湛水土壤) 중(中) 유효규산함량(有效珪酸含量)은 pH상승(上昇)과 Eh저하(低下)에 의하여 증가(增加)되었고 동일(同一) pH조건(條件)에서는 Eh가 낮은 토양(土壤)에서 높았다. 2. 수용액(水溶液) 중(中) 규산(珪酸)이 토양(土壤)에 흡수(吸收)되는 량(量)은 전분처리(澱粉處理)로 현저(顯著)히 증가(增加)되었다. 3. 석회처리(石灰處理)에 의한 토양(土壤)의 규산흡수량(珪酸吸收量) 증감(增減)은 일정(一定)한 경향(傾向)을 보이지 않았으나 첨가용액(添加溶液)의 규산농도(珪酸濃度)가 낮은 경우(境遇)는 석회시용(石灰施用)으로 흡수량(吸收量)이 다소(多少) 증가(增加)되었다. 4. 답토양(畓土壤)의 규산흡수양상(珪酸吸收樣相)은 Langmuidr 등온흡착식(等溫吸着式)과는 전혀 달랐고 Freundlich 등온흡착식(等溫吸着式)과 유사(類似)하였다.

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달천광산 주변 토양 내 비소의 존재형태 및 토양세척법에 의한 제거 (Fractionation and the Removal of Arsenic-Contaminated Soils Around Dalchĕn Mine Using Soil Washing Process)

  • 한경욱;신현무
    • 한국환경과학회지
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    • 제17권2호
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    • pp.185-193
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    • 2008
  • This study has been carried out to examine the feasibility of soil washing process for reducing arsenic contamination level of soil around $Dalch\hat{e}n$ Mine. The results of physicochemical tests of the target soil showed that pH was weak alkalic ($pH{\simeq}7.8$), soil texture was coarse sand, and organic contents (5.7%) and CEC (Cation exchange capacity; 21.5 meq/100 g) were similar with those of soils generally found in Korea. Contamination levels of arsenic were found to over 201 mg/kg which exceed the Korea standard levels of countermeasure and concern. To investigate chemical partitioning of heavy metals, sequential extraction procedures were adopted and it was found that arsenic was predominantly associated with the residual fraction among five fractional forms as much as over 85%, which is demonstrating that only less than 15% of all might be vulnerable to a selected washing agents. Among 6 kinds of washing agents applied on the screening for arsenic-contaminated soil, HCl and $H_3PO_4$ solution were selected as promising washing agents. In comparison with HCl and $H_3PO_4$ solutions for arsenic washing by kinetic experiment in the change of pH, soil-solution ratio, temperature, and washing solution concentration, $H_3PO_4$ solution was determined to best one of agents tested, which showed faster washing rate than HCl to accomplish regulatory goal.

Remediation of heavy metal-contaminated soils using eco-friendly nano-scale chelators

  • Lim, Heejun;Park, Sungyoon;Yang, Jun Won;Cho, Wooyoun;Lim, Yejee;Park, Young Goo;Kwon, Dohyeong;Kim, Han S.
    • Membrane and Water Treatment
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    • 제9권3호
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    • pp.137-146
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    • 2018
  • Soil washing is one of the most frequently used remediation technologies for heavy metal-contaminated soils. Inorganic and organic acids and chelating agents that can enhance the removal of heavy metals from contaminated soils have been employed as soil washing agents. However, the toxicity, low removal efficiency and high cost of these chemicals limit their use. Given that humic substance (HS) can effectively chelate heavy metals, the development of an eco-friendly, performance-efficient and cost-effective soil washing agent using a nano-scale chelator composed of HS was examined in this study. Copper (Cu) and lead (Pb) were selected as target heavy metals. In soil washing experiments, HS concentration, pH, soil:washing solution ratio and extraction time were evaluated with regard to washing efficiency and the chelation effect. The highest removal rates by soil washing (69% for Cu and 56% for Pb) were achieved at an HS concentration of 1,000 mg/L and soil:washing solution ratio of 1:25. Washing with HS was found to be effective when the pH value was higher than 8, which can be attributed to the increased chelation effect between HS and heavy metals at the high pH range. In contrast, the washing efficiency decreased markedly in the low pH range due to HS precipitation. The chelation capacities for Cu and Pb in the aqueous phase were determined to be 0.547mmol-Cu/g-HS and 0.192mmol-Pb/g-HS, respectively.

간척지 벼 재배시 토양 및 관개수 염의 안전 한계농도 (Critical Saline Concentration of Soil and Water for Rice Cultivation on a Reclaimed Saline Soil)

  • 최원영;이규성;고종철;최송열;최돈향
    • 한국작물학회지
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    • 제48권3호
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    • pp.238-242
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    • 2003
  • 본 연구는 간척지 토양 염농도별(저염; 0.1-0.2%, 중염; 0.3~0.4%)로 분얼기 관개수 염수처리 농도에 따른 벼 생육 및 수량성을 검토하고자 시험한 결과를 요약하면 다음과 같다. 가. 토양 및 관개수 염농도가 높을수록 초장은 짧았고 주당경수도 적었으며, 특히 중염 토양에서 관개수 염농도 0.3% 이상에서는 모두 고사되었다. 나. 토양 및 관개수 염농도가 높을수록 출수는 지연되었으며, 토양 염농도간에는 중염 토양에서 저염 토양보다 2-5일 정도 늦었다. 다. 간장은 관개수 염농도가 높을수록 짧았고 중염 토양이 저염 토양보다 짧았으며. 수장도 같은 경향이었다. 라. 저염토양에서는 관개수 염농도가 높을수록 $\textrm{m}^2$ 당립수가 적고 등숙비율이 낮아, 쌀수량은 민물 관개 수량에 비해 관개수 0.l%는 92%, 0.3%는 84%, 0.5%는 56%, 0.7%는 36% 수준이었다. 중염토양의 쌀수량은 저염토양 민물 관개 수량에 비해 민물 관개는 62%, 0.1% 관개수에서는 30% 수준이었다. 따라서 관개수 염농도가 저염 토양은 0.7%, 중염 토양은 0.3%까지 생육은 가능하나 수량 감소가 커서, 소득지수로 볼때 간척지 쌀 생산 한계 관개수 염농도는 저염 토양은 0.5% 이하에서, 중염 토양은 민물 관개수에서 가능하였다.

Criteria of Nitrate Concentration in Soil Solution and Leaf Petiole Juice for Fertigation of Cucumber under Greenhouse Cultivation in Gyeonggi region

  • Park, Jung-Soo;Roh, Ahn-Sung;Jang, Jae-Eun;Kang, Chang-Sung;Kim, Hee-Dong
    • 한국토양비료학회지
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    • 제48권4호
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    • pp.295-304
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    • 2015
  • To develop a technique for efficient management of fertility for cucumber in greenhouse, a quick test method to quantify nitrate ($NO_3{^-}$) content in soil solution and leaf petiole juice using a simple instrument that are easy to use for farmers was investigated. N fertilizer (urea) was applied at 0, 50, 100 and 200% levels of the recommended application rate from 30 days after transplanting to harvest by soil fertigation treatments. Stable results were obtained from analysis of nitrate ($NO_3{^-}$) using top $10^{th}$ or $11^{th}$ leaf petioles collected between 10 to 11 am in the morning. Under the semiforcing culture, $NO_3{^-}$ content of leaf petiole juice was highest at 60 days after transplanting (DAT) at all fertigation treatments. Appropriate $NO_3{^-}$content of leaf petiole juice was $2,418{\pm}78{\sim}2,668{\pm}118$ at 45 DAT, $3,032{\pm}90{\sim}3,332{\pm}63$ at 60 DAT, $2,709{\pm}50{\sim}3,158{\pm}155$ at 75 DAT, $2,535{\pm}49{\sim}2,907{\pm}83$ at 90 DAT, and $2,242{\pm}48mg\;L^{-1}$ at 105 DAT. In addition, appropriate $NO_3{^-}$ content of soil solution was $167{\pm}9{\sim}212{\pm}15$ at 45 DAT, $83{\pm}10{\sim}112{\pm}12$ at 60 DAT, $49{\pm}3{\sim}92{\pm}6$ at 75 DAT, $71{\pm}9{\sim}103{\pm}9$ at 90 DAT, and $73{\pm}9mg\;L^{-1}$ at 105 DAT. The cucumber yield at 100% N level of fertigation was $7,770kg\;10a^{-1}$ and no difference in yield was found at 200% N level of fertigation. However, there was 12% decrease in yield at 50% N fertigation and, 17% decrease at 0% N fertigation. Under retarding culture, $NO_3{^-}$ concentration of leaf petiole juice was highest at 55 days after transplanting (DAT) at all fertigation treatments. Appropriate $NO_3{^-}$ content of leaf petiole juice was $2,464{\pm}102{\sim}2,651{\pm}33$ at 45 DAT, $3,025{\pm}71{\sim}3,314{\pm}84$ at 55 DAT and $2,488{\pm}92mg\;L^{-1}$ at 65 DAT, respectively. Appropriate $NO_3{^-}$ content of soil solution was $111{\pm}10{\sim}155{\pm}14$ at 45 DAT, $93{\pm}7{\sim}147{\pm}14$ at 55 DAT, $67{\pm}4mg\;L^{-1}$at 65 DAT, respectively. The cucumber yield at 50% N fertigation was not different from $1,697kg\;10a^{-1}$ of 100% N fertigation level and even with that of the 200% N fertigation. However, there was 21% decrease in yield at 0% N fertigation.

Degraded Paddy Soils. I. Theoretical Analysis on the Sultide Formation and the Effect of Iron Hydroxide Upon Removal of Sulfide from Solution

  • Cho, Chai-Moo
    • Applied Biological Chemistry
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    • 제2권
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    • pp.9-14
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    • 1961
  • The formation of sulfide from sulfate has been discussed from the thermodynamic principles. No mechanism of the reaction has been presented. From the stoichiometric and Nernst equations for the conversion of sulfate into sulfide, it was concluded that the formation of sulfide from sulfate can take place more readily if pH of a medium is low. The difficulty of this conversion increases with increasing pH. As pH of a medium increases, the degree of dissociation of H₂S into S= increases and this, in turn, renders the chance of precipitation of sulfide as FeS easier. Higher the pH of a soil or medium, greater is the S= concentration. The concentration of ferrous ion required to remove dissolved sulfide in a medium by forming insoluble FeS decreases with increasing pH. From the theory it was pointed out that an application of lime and iron rich foreign substances to a soil may be effective in causing the removal of dissolved sulfide from solution.

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프로테아제와 리파제가 직물의 세척에 미치는 영향 (The Effects of Protease and Lipase on the Detergency of Fabrics)

  • 이정숙;정소화
    • 한국의류산업학회지
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    • 제2권4호
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    • pp.339-345
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    • 2000
  • The effects of protease and/or lipase on the removal of protein soil and oily soil were investigated in this study. Cotton, rayon, nylon, and PET fabrics were soiled by padding of fresh bovine blood and spotting of mixed artificial sebum evenly. The soiled fabrics were aged at $130^{\circ}C$ for 30 minutes. The fabrics were washed by using Terg-O-Tometer at various conditions. Protease and/or lipase were added in the alcohol ethoxylate (AE) detergent solution. The removal efficiency was evaluated by analysis of protein and/or oil on the fabrics before and after washing, respectively. The detergency of protein and/or oil on the fabrics was discussed with enzyme concentration, washing time, washing temperature, pH of washing solution and fiber characteristics. The hydrolysis of protease improved effectively the removal of oil as well as protein by increasing removal of protein-oil mixed soil at the same time. The effect of lipase added detergent solution was slightly shown on the removal of oil and/or protein. The removal of mixed soils from cotton fabrics was very low because of large amount of residual soils caused by the physical characteristics of cotton fiber.

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침수상태(湛水狀態)에서 토양(土壤) 염분(鹽分) 확산(擴散) 상승(上昇) 해석(解析)에 Laplace변환 이용 (The Solution of Upward Salt Diffusion in Floodeol Soil using Laplace Transformation)

  • 오영택
    • 한국토양비료학회지
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    • 제28권3호
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    • pp.233-240
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    • 1995
  • Ficks의 확산 편미방을 Laplace 변환을 적용하여 초기 및 경계조건과 함께 종속 대수 함수로 변환하고 Burington의 역변환표를 활용하여 복귀하는 방법으로 Ficks의 확산 편미방의 해를 구하였다. 적용된 초기 및 정계조건은 일정깊이의 담수에로 무한 깊이의 일정 염농도의 균일한 간척지 토양에서 상향 염분확산 이동에 대한 것이었다. 유도된 해는 특이 조건에서의 비교법으로 오.등 및 Kirkham, 등이 보고 한 간단한 초기 빛 경계조건에서의 해와 일치함을 확인했다. Ficks의 확산식의 해로 계산된 완만한 제염 속도를 근거로하여 담수 제염 방법별 제염 속도와 토양중 염분분포를 추정할수있는 모형식을 제시하였다.

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Migration of calcium hydroxide compounds in construction waste soil

  • Shin, Eunchul;Kang, Jeongku
    • Advances in environmental research
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    • 제4권3호
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    • pp.183-196
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    • 2015
  • Migration of leachate generated through embankment of construction waste soil (CWS) in low-lying areas was studied through physical and chemical analysis. A leachate solution containing soluble cations from CWS was found to have a pH above 9.0. To determine the distribution coefficients in the alkali solution, column and migration tests were conducted in the laboratory. The physical and chemical properties of CWS satisfied environmental soil criteria; however, the pH was high. The effective diffusion coefficients for CWS ions fell within the range of $0.725-3.3{\times}10^{-6}cm^2/s$. Properties of pore water and the amount of undissolved gas in pore water influenced advection-diffusion behavior. Contaminants migrating from CWS exhibited time-dependent concentration profiles and an advective component of transport. Thus, the transport equations for CWS contaminant concentrations satisfied the differential equations in accordance with Fick's 2nd law. Therefore, the migration of the contaminant plume when the landfilling CWS reaches water table can be predicted based on pH using the effective diffusion coefficient determined in a laboratory test.

토양 및 오염물질의 물성치가 연직배수재에 의한 현장오염정화에 미치는 영향에 대한 수치해석적 연구 (Numerical Analysis of Effects of the Physical Properties of Soil and Contaminant Materials on In-situ Soil Remediation Using Vertical Drain)

  • 이행우;장병욱
    • 한국지반신소재학회논문집
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    • 제5권2호
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    • pp.1-8
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    • 2006
  • 오염토양의 현장정화에 있어서 지반 및 오염물질의 물성치는 정화에 소요되는 시간과 함께 매우 중요한 고려사항이다. Gabr 등(1996)은 연직배수재가 설치된 오염지반에서 시 공간적 변화에 따른 초기오염농도에 대한 오염농도비($C/C_0$)를 구하는 식을 유도하였다. 본 연구에서는 Gabr 등이 유도한 식의 전산모형 FLUSH1을 이용하여 오염지반 흙의 유효입경, 간극률, 형상계수, 밀도, 지반의 온도와 오염물질의 단위중량 및 점성계수가 오염정화에 미치는 영향을 알아보기 위하여 시 공간적 변화에 따른 오염농도비($C/C_0$)를 분석 하였다. 분석결과 연직배수재가 설치된 오염지반에서 정화에 크게 영향을 미치는 인자는 오염지반 흙입자의 유효입경인 것으로 나타났으며, 그 다음으로 오염물질의 점성, 오염지반 흙의 간극율, 형상계수, 지반의 온도, 오염물질의 단위중량, 흙의 밀도 순으로 분석되었다. 오염지반 흙의 밀도는 오염정화에 미치는 영향이 아주 작은 것으로 나타났다.

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