Lee, Chang Hoon;Kang, Seong Soo;Kim, Myung Sook;Kim, Yoo Hak
한국토양비료학회지
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제48권1호
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pp.30-35
/
2015
This study was conducted to investigate investigated the effect of nitrogen fertilizer on nitrate concentration in soil solution and to determine the relationship between yield and nitrate concentration in soil solution for cucumber cultivation under plastic film house. Nitrogen as urea was applied at rates of 0, 120, 240, 360, and $480kg\;N\;ha^{-1}$ as an additional fertilizer by trickle irrigation during cucumber cultivation. Monitoring of nitrate concentration in soil solution was investigated using porous cups at 25 cm depth under soil surface. Nitrate concentration in soil solution increased with increasing the rate of additional nitrogen. Correlation coefficient between EC value and nitrate concentration was positive in soil and soil solution (p<0.05). An additional nitrogen of about $300kg\;ha^{-1}$ was shown the highest yield of cucumber, and improved yield by 5% compared to N recommendation of $240kg\;N\;ha^{-1}$. The highest yield was determined at nitrate concentration of $82mg\;L^{-1}$ in soil solution by regression equation ($Y=74.2+0.73X+0.000504X^2$, $R^2=0.629^*$). These results means indicate that nitrate concentration in soil solution would be useful method to rapid determination for additional nitrogen during cucumber cultivation under plastic film house.
Soil moisture is an important factor for the availability and circulation of nutrients in arable soil. The purpose of this study was to set thresholds moisture content on soil nitrate concentration in the solution for real-time diagnosis. Sandy loam, silt loam, and sandy loam was filled with $1.2g\;cm^{-3}$ at Wagner pots, 0, 100, and $200mg\;L^{-1}$ of $KNO_3$ was saturated. Nitrate in standard solution was recovered about 95% by passing the porous cup. Nitrate concentrations in sampling of soil solution were examined by using a porous cup. The soil solution was higher in accordance with sandy loam> silt loam> clay loam, limited water filled pore space for sampling soil solution was 33.7, 56.4, and 62.2%, respectively. Nitrate concentration in the soil solution was negligible at sandy loam and silt loam during sampling periods, which was decreased about 50~82% in clay loam compared to the initial $NO_3$-N concentration in the saturated $KNO_3$ solution. Over limitation of soil solution sampling, soil EC and $NO_3$-N content were increased with the saturated $NO_3$-N concentration, regardless of soil texture (p<0.05). Conclusively, soil solution by using a porous cup was possible, regardless of the soil texture, which was useful for the diagnosis in nitrate concentration of soil solution. However, because nitrate concentration of soil solution in a clay loam changes, it was necessary for careful attention in order to take advantage for the real-time diagnosis of nitrogen management in soil.
In order to investigate the growth response of grasses to chitosan solution amended soil were studied from the standpoint of estimating the growth stimulating adequate concentrations of chitosan solution amended soil in each grass. Three species in this experiment used were orchardgrass, tall fescue and reed canarygrass. Six different concentrations of chitosan solution amended soil were 0%(control), 0.01%, 0.05%, 0.1%, 0.5% and 1.0%, respectively. The resulte obtained were as follows ; 1. Leaf area(LA), dry weight of leaf(LW), dry weight of shoot(SHW), biological yield(BY), C/f ratio and T/R ratio were significantly different between species. 2. Growth stimulating effect by chitosan solution amended soil were found in plant length(PL) and T/R ratios of grasses. 3. Adequate concentrations of chitosan solution amended soil were different between species. The highest values of yield components and dry weight of plant parts were obtained at 0.01% in orchardgrass, 0,05% in reed canarygrass and 1.0% in tall fescue, respectively. 4. The growth response of grasses to chitosan solution amended soil were different between species. Thus, an increase in leaf area(LA) and dry weight of leaf(LW) by chitosan solution amended soil was mainly contributed to increase in dry weight of shoot(SHW) and biological yield(BY) in orchardgrass. Chitosan solution amended soil also stimulated growth of shoot and increased in biological yield(BY) in tall fescue. In reed canarygrass contributed to increase in C/F ratios. 5. Adequate concentrations of chitosan solution amended soil for an economical benefit of cultivation and dry matter production of grasses were ranged from 0.01% to 0.05% levels.
Porous ceramic cups are used for monitoring ion concentration in soil solutions in various time course and depth. A soil solution sampler was constructed in laboratory by inserting pliable perfluoroalkoxy(PFA) tubings into porous cup through holes in PVC rod segment which plugged top opening of the porous cup. The system was installed in drip irrigated soil in a vertical position, and nitrogen movement below the drip basin was monitored. To collect soil solution, vacuum in the cup was applied with a hand vacuum pump. The samples obtained were sufficient enough to run quantitative analyses for a number of chemicals. Nitrogen transformation and movement could be well defined, and the system seemed to be relevant to the other soil solution samplers in monitoring chemical movement in soil. Although this system has general deficiencies found in the other samplers using ceramic cup, it could be easily constructed at a low cost. Since the tubing was pliable, the cups could be installed in horizontal position, and this allows installations of the cups at more precise depth increments and also more precise samplings of soil solution at each depth.
This study investigates the effect of mixed characteristics of oily soil such as mixed ratio, polarity of oily soil on contact angle of fabric, removal of oily and particulate soil from PET fabric in oily/particulate soil mixed system. The contact angle of fabric in the surfactant solution with suspended oily soil was examined as a fundamental environment of detergency of soil from fabrics. Detergency was investigated as function of mixed ratios of oily/ particulate soil, type of oily soil, surfactants concentration, surfactant type and temperature of detergency in surfactant solution. The contact angle of fabric in surfactant solution sharply increased with mixing nonpolar oily soil; in addition, the contact angle slightly increased with increasing contents of oily soil and decreased with increasing surfactant concentration. The removal of oily and particulate soil from fabric was higher in the solution mixed with polar versus nonpolar oily soil. The detergency increased with increasing surfactant concentration and the increased temperature of surfactants solution that were relatively improved in NPE compared to DBS solutions, The results indicated that the detergency of oily and particulate soil showed a similar trend in oily/ particulate mixed soil systems. The general contact angle of fabric was well related with the detergency of oily and particulate soil in oily/particulate mixed soil system, therefore, the primary factor determining the detergency of soil in oily/particulate mixed soil system may be the contact angle of fabric caused by wettability.
Current methods of evaluating soil contamination by heavy metals rely on analyzing samples for total contents of metals or quantities recovered in various chemical extracting solutions. Results from these approaches provide only an index for evaluation because these methodologies yield values not directly related to bioavailability of soil-borne metals. In addition, even though concentrations of metals may be less than those required to cause toxic effects to biota, they may cause substantial effects on soil chemical parameters that determine soil quality and sustainable productivity. The objective of this research was to characterize effects of Cu or Cd additions on soil solution chemistry of soil quality indices, such as pH, EC, nutrient cation distribution and quantity/intensity relations (buffer capacity). Metals were added at rates ranging from 0 to 400 mg/kg of soil. Soil solution was sequentially extracted from saturated pastes using vacuum. Concentrations of Cu or Cd remaining in soil solutions were very low as compared to those added to the soils, warranting that most of the added metals were recovered as nonavailable (strongly adsorbed) fractions. Adsorption of the added metals released cations into soil solution causing increases of soluble cation contents and thus ionic strength of soil solution. At metal additions of 200~400 mg/kg, EC of soil solution increased to as much as 2~4 dS/m; salinity levels considered high enough to cause detrimental effects on plant production. More divalent cations (Ca+Mg) than monovalent cations (K+Na) were exchanged by Cu or Cd adsorption. The loss of exchangeable nutrient cations decreased long-term nutrient supplying capacity or each soil. At 100 mg/kg or metal loading, the buffering capacity was decreased by 60%. pH of soil solution decreased linearly with increasing metal loading rates, with a decrement of up to 1.3 units at 400 mg Cu/kg addition. Influences of Cu on each of these soil quality parameters were consistently greater than those of Cd. These effects were of a detrimental nature and large enough in most cases to significantly impact soil productivity. It is clear that new protocols are needed for evaluating potential effects of heavy metal loading of soils.
The effect of solution temperature and nitrogen form on cucumber (Cucumis sativus L.) growth, photosynthesis and nitrogen metabolism was investigated in hydroponic culture. Cucumber plants were grown for 35 days in a greenhouse at three constant solution temperatures ($15^{\circ}C$, $20^{\circ}C$, and $25^{\circ}C$) within a natural aerial temperature ($15-30^{\circ}C$). Four nitrate:ammonium ($NO{_3}^-:NH{_4}^+$) ratios (10:0, 8:2, 5:5, and 2:8 $mmol{\cdot}L^{-1}$) at constant nitrogen (N) concentration of $10mmol{\cdot}L^{-1}$ were applied within each solution temperature treatment. Results showed an increasing solution temperature enhanced plant growth (height, dry weight, and leaf area) in most N treatments. Dry weight accumulation was greatest at the 10:0 $NO{_3}^-:NH{_4}^+$ ratio in the $15^{\circ}C$ solution, the 5:5 ratio in the $20^{\circ}C$ solution and the 8:2 ratio in the $25^{\circ}C$ solution. Photosynthetic rate (Pn) response to solution temperature and $NO{_3}^-:NH{_4}^+$ ratio was similar to that of plant growth. Probably, the photosynthate shortage played a role in the reduced biomass formation. Increasing solution temperature enhanced the nitrate reductase (NR) activity, and further reduced shoots nitrate content. Our results indicate that the optimal ratio of nitrate to ammonium that promotes growth in hydroponic cucumber varies with solution temperature.
The objective of this research was to characterize effects of Cu or Cd additions on chemistry of soil quality indices, such as pH, EC, cation distribution and buffering capacity. Metals were added at rates ranging from 0 to 400 mg $kg^{-1}$ of soil. Soil solution was sequentially extracted from saturated pastes using vacuum. Concentrations of Cu or Cd remaining in soil solutions were very low as compared to those added to the soils, warranting that most of the added metals were recovered as nonavailable fractions. Adsorption of the added metals released cations into soil solution causing increases of ionic strength of soil solution. At metal additions of $200{\sim}400\;mg\;kg^{-1}$, EC of soil solution increased to as much as $2{\sim}4\;m^{-1}$; salinity levels considered high enough to cause detrimental effects on plant production. More divalent cations than monovalent cations were exchanged by Cu or Cd adsorption. The nutrient buffering capacity of soils was decreased due to the metal adsorption and release of cations. pH of soil solution decreased linearly with increasing metal loading rates, with a decrement of up to 1.3 units at 400 mg Cu $kg^{-1}$ addition. Influences of Cu on each of these soil quality parameters were consistently greater than those of Cd. These effects were of a detrimental nature and large enough in most cases to significantly impact soil productivity. It is clear that new protocols are needed for evaluating potential effects of heavy metal loading of soils.
Surfactant enhanced in-situ soil flushing was peformed to remediate the soil and groundwater at an oil contaminated site, and the effluent solution was treated by the chemical treatment process including DAF(Dissolved Air Flotation). A section from the contaminated site(4.5m$\times$4.5m$\times$6.0m) was selected for the research, which was composed of heterogeneous sandy and silt-sandy soils with average Hydraulic conductivity of 2.0$\times$10$^{-4}$ cm/sec. Two percent of sorbitan monooleate(POE 20) and 0.07% of iso-prophyl alcohol were mixed for the surfactant solution and 3 pore volumes of surfactant solution were injected to remove oil from the contaminant section. Four injection wells and two extraction wells were built in the section to flush surfactant solution. Water samples taken from extraction wells and the storage tank were analyzed by GC(gas-chromatography) for TPH concentration with different time. Five pore volumes of solution were extracted while TPH concentration in soil and groundwater at the section were below the Waste Water Discharge Limit(WWDL). Total 18.5kg of oil (TPH) was removed from the section. The concentration of heavy metals in the effluent solution also increased with the increase of TPH concentration, suggesting that the surfactant enhanced in-situ flushing be available to remove not only oil but heavy metals from contaminated sites. Results suggest that in-situ soil flushing and chemical treatment process including DAF could be a successful process to remediate contaminated sites distributed in Korea.
A fraction of TRIGA contaminated soil whose decontamination is practicable by soil washing was about 34.2 %. It appeared from results of first decontamination experiment that decontamination efficiency using (NH$_4$)$_2$SO$_4$, H$_2$C$_2$O$_4$, and NaOH solution were high. Meanwhile, the most suitable ratio of contaminated soil mass(g) to decontamination solution volume(ml) appeared to be 1:10 according to experiment results. And the most suitable concentration of oxalic acid used as a decontamination solution appeared to be 0.5 M.
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