• Title/Summary/Keyword: soil sediment

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Occurrence and Distribution of Heavy Metals and Natural Radioisotopes Recovered at the Abandoned Coal Mine Tailings (폐석탄광미에서 유래한 중금속과 자연방사능의 분포 및 발생 특성)

  • Chung, Doug-Young;Cho, Il-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.38 no.3
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    • pp.142-149
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    • 2005
  • This investigation was conducted to observe and verify the distribution and their occurrence between heavy metals and natural isotopes in the soil collected at the 40 locations from the abandoned coal mine areas to the sediment of Chungra reservoir located at Chungra-Myon Boryung city, Chungnam. The results of the investigation showed that there were distinctive differences of the contents for the heavy metals and the natural isotopes between the area influenced by the coal mine tailing and the non-influenced area. The amounts of the heavy metals were Pb ($1.32-29.96mg\;kg^{-1}$), Cd ($0.15-0.76mg\;kg^{-1}$), Cu ($0.28-49.67mg\;kg^{-1}$), and Cr ($1.31-13.18mg\;kg^{-1}$) while the averages were Cu ($12.43mg\;kg^{-1}$), Pb ($10.44mg\;kg^{-1}$), Cr ($4.87mg\;kg^{-1}$), Cd ($0.51mg\;kg^{-1}$). The standard deviations of Pb and Cu were significantly higher compared to other heavy metals investigated in this experiment. And the amounts of the natural isotopes measured from the dried soil samples were Pb-210 ($4.87dpm\;g^{-1}$), Th-234 ($3.52dpm\;g^{-1}$), Ra-226 ($2.88dpm\;g^{-1}$), Ra-228 ($7.30dpm\;g^{-1}$), K-40 ($58.06dpm\;g^{-1}$) for all locations whereas Cs-137 which is fall-out by nuclear experiment from atmosphere was rarely found. From these results we found that the amounts of natural isotopes such as Pb-210 (4.41%), Th-234 (3.60%), and Ra-226 (2.09%) were less than those found in the coal-tailing while the proportion of Ra-228 (266%) and K-40 (308%) were significantly higher than those in the coal-tailing. Also occurrence of correlations between the amounts of the heavy metals and the natural isotopes was proportionally related.

Characterization of Sedimentation and pH Neutralization as Pretreatment of Acid Contaminated Water (산 오염수 전처리용 침전 및 중화 특성)

  • Im, Jongdo;Lee, Sangbin;Park, Jae-Woo
    • Journal of the Korean GEO-environmental Society
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    • v.23 no.9
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    • pp.33-40
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    • 2022
  • Sedimentation and pH neutralization has been investigated as preteatment of acid contaminate water. The settling and neutralizing process derive more effective degradation efficiency as the pre-treatment process before the removal process of adsorption, volatile, biodegradation, or oxidation. Settling velocity, uniformity coefficient, coefficient of curvature, and grain size index can define in the sedimentation process for characteristics of the soil. The stainless steel sieve has been used to separate each particle size of the dry soil by assembling in order of 4, 10, 20, 40, 80, 100, and 200 mesh sizes. The soil from Gamcheon Port in Busan drops upper side of the sieve and shakes back and forth to separate each different size of the particle. The 1L of Imhoff cone and 200 mL of the mass cylinder were used as settling tanks to calculate settling velocity. Stokes' equation was used to figure out the average density of dry soil with a value from settling velocity. In the results, the average particle density and lowest settling velocity were 1.93 g/cm3 and 0.11 cm/s, respectively. These values can detect the range of settling points of sediment to prevent chemical accidents. In pH neutralization, the initial pH of 2, 3, 4, and 5 of nitric acid and sulfuric acid are used as an acid solution; 0.1, 0.01, and 0.001 M of sodium hydroxide and calcium hydroxide are used as a base solution. The main goal of this experiment is to figure out the volume percentage of the acid solution becomes pH 7. The concentration of 0.001 M of base solution exceeds all the conditions, 0.01 M exceeds partially, and 0.1 M does not exceed 5 v/v% except pH 2. Calcium hydroxide present less volume than sodium hydroxide at pH neutralization both sulfuric and nitric acid.

Studies on the Desertification Combating and Sand Industry Development(IV) - Technology Development for Sanddune Fixation and Sandy Land Conservation in China - (사막화방지(沙漠化防止) 및 방사기술개발(防沙技術開發)에 관한 연구(硏究)(IV) - 중국(中國)의 사구고정(沙丘固定) 및 방사공법분석(防沙工法分析) -)

  • Woo, Bo-Myeong;Lee, Kyung-Joon;Choi, Hyung-Tae;Lee, Sang-Ho;Park, Joo-Won;Wang, Lixian;Zhang, Kebin;Sun, Baoping
    • Journal of Korean Society of Forest Science
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    • v.90 no.3
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    • pp.277-294
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    • 2001
  • This study is aimed to analyze and to evaluate the technology development for sanddune fixation and sandy land conservation in China, resulting from the project of "Studies on the desertification combating and sand industry development". There are various types of sanddunes, including shrub-bunch type, dendritic, honey combed lattice, crescentic, parabolic, pyramid, complex and irregular types, domed, and so on. The height distribution ratios of these sanddunes are 13% of less than 5m, 17% of 6~10m, 18% of 11~25m, 14% of 26~50m, 28% of 51~100m, 10% of more than 100m, and so on. In dry land of China, shifting direction of the sanddune is mainly varying with main direction of wind, but types of shifting sanddunes have many differences in accordance with region, topography, size and shape of sanddunes. The main sanddune fixation technologies could be divided into the bio-ecological measures, physical measures and chemical measures. The bio-ecological measures include such vegetation measures as shrub-grasses measures, sandbreaks between sand dunes, sand fixation shelterblets and establishment of farmland shelterbelts, etc. The physical measures include establishment of high-sanddune stabilization walls and low-sanddune stabilization walls, sanddune fixation levees and coverage method with sediment clay, etc. The chemical measures include fixation-materials spraying and synthetical liquid spraying methods, etc. Besides, irrigation and sand settlement measures, shifting sand trapping channel, ditchsand fixation measures, etc. have been effectively applied.

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Study on Low Temperature Tolerant Methane-Producing Bacteria for the Treatment of Agricultural and Livestock Wastes;III. Isolation of Low Temperature Tolerant Methanogens (농축산(農畜産) 폐기물(廢棄物) 처리(處理)를 위(爲)한 저온내성(低溫耐性) 메탄 생성균(生成菌)의 특성(特性)에 관(關)한 연구(硏究);III. 저온내성(低溫耐性) Methanogens의 분리(分離))

  • Kim, Kwang-Yong;Kim, Jai-Joung;Daniels, Lacy
    • Korean Journal of Environmental Agriculture
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    • v.15 no.3
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    • pp.362-371
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    • 1996
  • This study was conducted to investigate the biochemical properties of isolated bacteria, low temperature tolerant methanogens which were selected for use as inoculum for anaerobic fermentation of agricultural and livestock wasted at low temperature. The results, obtained were summarized as follows: Low temperature tolerant methanogens were isolated from the samples which showed the high methanogenesis rate by enrichment culture at low temperature in methanol medium. These methanogens, Methanobacterium M-251 and Methanobacterium M-253 were isolated from swampy sediment at latitude $56.9^{\circ}$, Methanosarcina mazei M-372 from lake sediment IV at latitude $55.0^{\circ}$ N, and Methanobacterium formicicum M-375 from tidal land soil at latitude $37.0^{\circ}N$, respectively. The isolated anaerobic bacteria could not use sugars as carbon sources. The optimum pH value for the growth of M-251 and M-375 was 6.8, but those for M-253 and M-372 6.5 and 7.0, respectively. The minimum growth temperature of isolated, M-251 and M-253 were $8^{\circ}C$ and the optimum temperature $30^{\circ}C$, while the minimum of M-392 and M-395 were $13^{\circ}C$ and the optimum $37^{\circ}C$. The growth rate of isolates at $17.5^{\circ}C$ were lower by 32-50% than that of $30^{\circ}C$. The isolated Methanobacterium strains such as M-251, M-253, and M-375 have lower cell yield, 0.38-1.21g/1M $CH_4$ than 1.14-1.51g/1M $CH_4$ of Methanosarcina mazei M-372.

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The Effects of pH Change in Extraction Solution on the Heavy Metals Extraction from Soil and Controversial Points for Partial Extraction in Korean Standard Method (용출액의 pH 변화가 토양내 중금속 용출에 미치는 영향과 그에 따른 국내 토양 오염 공정시험방법의 문제점)

  • 오창환;유연희;이평구;이영엽
    • Economic and Environmental Geology
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    • v.36 no.3
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    • pp.159-170
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    • 2003
  • Heavy metals are extracted from Chonju stream sediment, roadside soils and sediments along Honam expressway, soils and tailings from mining area using three different methods (partial extraction in Standard Method, partial extraction method with maintaining 0.1 N of extraction solution and Sequential Extraction Method). In samples having buffer capacity against acid, pH 1 (0.1 N HCl) of extraction solution can not be maintained and pH of extraction solution increases up to 8.0 when partial extraction in Standard Method is used. The averages and ranges of HPE(heavy metals extracted using partial extraction in Standard Method)/HPEM(heavy metals extracted using partial extraction method with maintaining 0.1 N of extraction solution) values are 0.479 and 0.145~0.929 for Cd, 0.534 and 0.078~0.928 for Zn, 0.432 and 0.041~0.992 for Mn, 0.359 and 0.011~0.874 for Cu, 0.150 and 0.018~0.530 for Cr, 0.219 and 0.003~0.853 for Pb, and 0.088 and 1.73${\times}$10$^{-5}$~0.303 for Fe. These data indicate that the difference between HPE and HPEM is large in the order of Fe, Cr, Pb, Cu, Mn, Cd and Zn. The amounts of heavy metals extracted decreases in the follow order; Sum III(sum of fraction I, II, III in sequential extraction)>HPEM>Sum III (sum of fraction I and II)>HPE for Zn, Cd and Mn and Sum III>HPEM>HPE for Cr and Fe. In the case Cr, Sum II is lower than HPEM and higher than HPE. In case of Cu, extracted heavy metals is large in the order Sum IV>HPEM>Sum III HPE. HPE/HPEM value decreases with increasing the amount of HCl used for maintaining 0.1 N of extraction solution. For samples with high buffer capacity, HPE/HPEM value in all elements is lower than 0.2. On the other hand, for samples with low buffer capacity, HPE/HPEM value are over 0.2 and many samples have values higher than 0.6 for Zn, Cd Mn and Cu due to the small difference between Sum II and Sum III, and relatively higher mobility. However, for Fe and Cr, HPE/HPEM value is below 0.2 even for samples with low buffer capacity due to their low mobility and big difference between Sum II and Sum III. This study indicates that the partial extraction method in Korean Standard Method of soil is not suitable for an assessment of soil contamination in area where buffer capacity of soil can be decreased or lost because of a long term exposure to environmental damage such as acidic rain.

A study on slope protection works in cemetery establishment area ( I ) - The case of a public cemetery in Kangnung city - (묘지 조성사업지의 비탈면 보호공법에 관한 연구( I ) - 강릉시 시범 공설묘지 조성사업을 중심으로 -)

  • Chun, Kun-Woo;Yoo, Nam-Jae;Cha, Du-Song;Yi, Myong-Jong;Park, Wan-Geun;Han, Sang-Kyun
    • Journal of Forest and Environmental Science
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    • v.16 no.1
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    • pp.17-33
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    • 2000
  • The construction of a public cemetery in Kangnung city includes terraced graveyard with cutting or banking in mountain which has severe altitude differences with a slope of $30^{\circ}$. Therefore, there are scattered cutting and banking sections with vertical height more than 15m. Especially, if the slope failure or the loss of a graveyard happens after graveyard establishment due to surface flow and inflow around. it is difficult to repair, causing serious public censure. Accordingly, revegetation works were examined that need protection of slope. The specific content of the study was the selection of slopes requiring special care through blueprint and field investigation. the measurement of the physical property of slope and the situation of vegetative growth, the investigation of vegetation in slopes and the selection of vegetation. and the analysis of soil condition of slopes and the physical condition of slope sediment. On the basis of investigations some alternatives were proposed.

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An Analysis of Land Use Patterns in Riparian Zones for the Geumho River Watershed Management (금호강 유역관리를 위한 수변구역의 토지이용패턴분석)

  • Park, Kyung-Hun;Oh, Jeong-Hak;Jung, Sung-Gwan
    • Journal of the Korean Association of Geographic Information Studies
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    • v.8 no.2
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    • pp.157-165
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    • 2005
  • The purpose of this study is to examine the relationship between land use patterns of riparian zones and water quality in the Geumho River watershed. A GIS database included digital land use maps (1:25,000), stream network extracted from digital topographic maps (1:5,000) and riparian zones maps by multi-buffering method. Pearson's correlation analysis was used to explain the relationship between the environmental conditions of a 30 meter buffer strip on each side and water quality. According to the result of investigation of riparian-level land use patterns, sub-watersheds on the lower Geumho River including Daegu metropolitan city were mainly developed as urban area such as residential, commercial and industrial ones, while sub-watersheds on the middle Geumho River and the main course of Nakdong River, agricultural ones such as a paddy, a dry field and an orchard. Meanwhile, the area-rate of riparian forests which play an important role in filtering nitrogen, phosphorus and sediment was estimated below the average 16%. The proportion of urban area in a 30 meter riparian bufferstrip had a negative correlation with water quality in each sub-watershed. But the proportion of forest area had a positive correlation with water quality. Henceforth, it is necessary to establish landscape planning for preparing and restoring the riparian buffer zones, concerning land form, soil type, the present land use pattern and economic aspects.

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A study on colored water treatment at purification plant (정수장 색수의 처리기법에 관한 연구)

  • Park, S.I.;Lee, J.H.;Lee, H.H.;Kim, H.B.;Ahn, G.W.;Park, K.N.;Kim, Y.K.;Bae, J.S.;Mun, H.;Park, C.U.;Oh, E.H.;Seo, Y.G.
    • Journal of environmental and Sanitary engineering
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    • v.16 no.4
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    • pp.55-61
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    • 2001
  • There are many reservoirs used as the source of water supply and they show various specific characteristics in water quality depend seasonal. Especially, there were not a little variations of water quality in summer, as a natural consequence it follows that stratification occured phenomenon and changed anaerobic condition in the bottom of reservoir, and then accumulated Fe and Mn substance in soil and sediment were resolved into water, it attributes to coloration. G purification plant located in Y gun is very small plant in which coloration occurs by Fe and Mn in every summer. Using this plant as a model, the removal methods of Fe and Mn were studied. After prechlorination plus LAS coagulation, Fe, Mn, $NH_3-N$ were decreased from 7.290 mg/l to 0.080 mg/l, from 0.480 mg/l to 0.075 mg/l, from 0.55 mg/l to 0.04 mg/l. But $THM_{s}$ was increased from 0.050 mg/l to 0.044 mg/l. It shows that the prechlorination plus LAS coagulation treatment process in purification plant is effective to remove Fe and Mn ion.

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Burial Age and Flooding-origin Characteristics of Coastal Deposits at Gwangseungri, Gochanggun, Korea (고창군 광승리 연안 퇴적층의 퇴적 시기와 범람 기원 특성)

  • Kim, Jong Yeon;Yang, Dong Yoon;Shin, Won Jeong
    • Journal of the Korean earth science society
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    • v.36 no.3
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    • pp.222-235
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    • 2015
  • Samples were collected from both places including the coastal area within the height of 5 m above the mean sea level (msl) (DH) and the top of the coastal terrace of 10-15 m msl (KS) high in Gwangseungri, Gochanggun, Korea. To find the origin of the deposit in the coastal area, granulometric analysis and geochemical analysis were performed. The result showed that the DH samples were originated from the reddish soils overlaying weathered bedrock which presented gradual change of chemical composition from the bottom toward the top. Clay minerals were found from the DH samples. These results concluded that the DH samples were found as in-situ weathered materials. The KS samples were originated from the soil layer covering gravel layer at the foot slope of the hill along the coast. The KS samples contained different chemical compositions from the DH. It is inferred that some of this layer was disturbed or experienced the influx of foreign material. The particle size of the KS samples was different from those found on the beach. The particle size of lower parts of KS site was finer than that on the beach, but the particle size of middle part of the site was coarser than that on the beach. The sorting of the KS site was poorer than that on the beach. Thus, it is inferred that some parts of the layer were formed by short-lived high energy event rather than sustained and continuous action of tidal currents and/or waves. Analysis using an optically stimulated luminescence (OSL) method showed that the burial age of samples from KS site were found 0.65-0.71 ka. Though the characteristics of the sediment layer and forming event in this area should be further studied, it can be inferred that this sedimentary layer formed by coastal flooding with storm.

Contamination and Geochemical Speciation of Heavy Metals in Middle Cover Soils and Clay Liner from the Kumheung Landfill, Gongju City (공주 금흥매립지의 중간복토재 및 차수재(논토양)의 중금속 오염과 존재형태 연구)

  • 이평구;박성원;염승준
    • Economic and Environmental Geology
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    • v.34 no.3
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    • pp.283-299
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    • 2001
  • The middle cover soils and clay liners collected from the Kumheung landfill in Gongiu City were analysed for As, Ba, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, Sr, Ti and Zn concentrations using 0.] N HCl digestion and total/sequential extraction experiments followed by ICP-AES determination. The uncontaminated soil and sediment samples were also analyzed for the comparison. The results of sequential extraction showed that Cu was dominant in the oxidizable fraction, and As, Ni, Sr, Ba, and Mn were in the exchangeable fraction. Zinc and Mn occurred mostly in association with reducible, residual and carbonate fractions. Most of Cd and Pb were bound to the reducible and oxidizable fractions. The main carrier of Co, Cr, Fe and 11 was the residual fraction and another important carrier was the reducible fraction. The percentage of the metals of organically-bound form in the middle cover soils and clay liner was in the order of Cu(48%) > Ti(42%) > Pb(27%) > As(25%) > Cd(20%). As deduced from sequential extraction analysis, potential order of metal mobility in the middle cover soils and clay liner from the landfill was proposed: Cd > Sr > As > Ni > Mn > Ba > Cu > Pb > Zn » Co > 11 > Fe > Cr. Based on the 'geoaccumulation index' and the 'enrichment factor' normalized to A], the level of contamination of Cu, Ni and C1' was significant in the samples from Kumheung landfill and surrounding farmland. Their enrichments were attributed partly to anthropogenic pollutions.

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