• The Journal of Engineering Geology
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• v.25 no.4
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• pp.533-545
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• 2015

Spatial and seasonal variations in hydrogeochemical characteristics and the factors affecting the deterioration in quality of shallow portable groundwater in an agricultural area are examined. The aquifer consists of (from the surface to depth) agricultural soil, weathered soil, weathered rock, and bedrock. The geochemical signatures of the shallow groundwater are mostly affected by the NO₃⁻ and Cl⁻ contaminants that show a gradual downward increase in concentration from the upper area, due to the irregular distribution of contamination sources. The concentrations of the major cations do not varied with the elapsed time and the NO₃⁻ and Cl⁻ ions, when compared with concentrations in background groundwater, increase gradually with the distance from the upper area. This result suggests that the water quality in shallow groundwater deteriorates due to contaminant sources at the surface. The contaminations of the major contaminants in groundwater show a positive linear relationship with electrical conductivity, indicating the deterioration in water quality is related to the effects of the contaminants. The relationships between contaminant concentrations, as inferred from the ternary plots, show the contaminant concentrations in organic fertilizer are positively related to concentrations of NO₃⁻, Cl⁻, and SO₄²⁻ ions in the shallow portable groundwaters, which means the fertilizer is the main contaminant source. The results also show that the deterioration in shallow groundwater quality is caused mainly by NO₃⁻ and Cl⁻ derived from organic fertilizer with additional SO₄²⁻ contaminant from livestock wastes. Even though the concentrations of the contaminants within the shallow groundwaters and the contaminant sources are largely variable, it is useful to consider the ratio of contaminant concentrations and the relationship between contaminants in groundwater samples and in the contaminant source when analyzing deterioration in water quality.

• Journal of Soil and Groundwater Environment
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• v.10 no.3
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• pp.24-31
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• 2005

This study presents a contaminant transport model suitable for a 2-dimensional heterogeneous aquifer with multiple contaminant sources. It uses a streamline simulation, which transforms a multi-dimensional problem into multiple 1dimensional problems. It runs flow simulation, streamline tracking, and calculation of contaminant concentrations by turns. The model is verificated with a Visual MODFLOW by comparing contaminant concentration distributions and breakthrough curves at an observation well. Due to its fast simulation, it can be applied to time consuming simulations such as in a fine-grided aquifer, an inverse modeling and other applications.

• Journal of Soil and Groundwater Environment
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• v.8 no.1
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• pp.35-41
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• 2003

Laboratory procedures are available for estimating contaminant migration from sediment into caps by diffusion, but diffusion may not be the major process affecting capping effectiveness. Movement of contaminated pore water from sediment into caps due to sediment consolidation during and after cap placement may be much more significant than contaminant diffusion into caps. To verify this phenomenon, model tests were conducted by utilizing a research centrifuge. In this study, test was modeled for 22.5 hours at 100 g, which modeled a contaminant migration time of 25 years for a prototype that was 100 times larger than the centrifuge model. Centrifuge test results illustrate that advection and dispersion due to consolidation are dominating the migration of contaminants.

• Journal of Korea Soil Environment Society
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• v.3 no.3
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• pp.3-10
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• 1998

Acid/Base buffer capacity of soil is very important in prediction of contaminant transport for its direct impact on pH change of the system composed of soil-contaminant-water, In this research, diffuse double layer theory as well as two layer electrostatic adsorption model are applied to develop a theoretical model of buffer capacity of soil. Model application procedures are presented as well. Buffer capacity of Georgia kaolinite and Milwhite kaolinite was measured by acid-base titration. Model prediction and experimental results are compared.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.09a
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• pp.280-282
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• 2002

In analysis of pumping test data, generally infinite domain has been assumed. However, in many cases, this assumption was not readily satisfied. Some boundaries conditions and natural heterogeneity of hydrogeologic properties would play critical roles on groundwater flow and contaminant transport. This study examined effects of some boundary conditions and heterogeneity on the groundwater flow and contaminant transport with basic numerical groundwater modeling, which provides implications for remediation of contaminated groundwater.

• Proceedings of the Korean Geotechical Society Conference
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• 2002.03a
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• pp.3-38
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• 2002

This paper presents a general review of the literature on electrokinetic (EK) remediation of contaminated soil. Lab-scale tests were investigated and contaminant transport mechanism were examined. And also major factors affecting to the EK process were discussed. Enhanced techniques as a method to solve the problems that frequently occurred during traditional EK process were examined. And last, field implemented case and commercially applied case were described.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.32 no.4B
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• pp.261-266
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• 2012

In this study, soil environmental impact assessment using risk-based approach was compared with that using concentration-based approach. For this, heavy metal contaminant exposure was characterized in an abandoned mine area. According to the estimated carcinogenic and non-carcinogenic risks, soil ingestion was identified as the most dominant exposure pathway. When contaminant concentrations exceeded the Korean Soil Contamination Warning Standards, their corresponding risk values also exceeded the Total Soil Risk Standard. Even the cases of satisfying the Korean Soil Contamination Warning Standards mostly showed higher risk levels than the Total Soil Risk Standard, re-confirming a more sensitivity of the risk-based assessment than concentration-based assessment. However, the in-depth analysis of the estimated non-carcinogenic risk values revealed a few cases for soil contact pathway showing contaminant concentrations higher than the Korean Soil Contamination Warning Standards although their non-carcinogenic risk values satisfied the level of Hazard Index Standard. The findings from this study support a necessity of shifting policy paradigm from concentration-based approach into risk-based approach for reliable risk assessment in abandoned mine areas, and also suggest a necessity of further fundamental studies regarding risk factors and standards.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.04a
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• pp.18-21
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• 2002

Phytoremediation which uses plants to enhance the bioremediation through stimulation of microbial activity and root uptake, has been a topic of increasing interest. Mathematical model were developed that can be applied to various bioremediation methods in the unsaturated zone, especially phytoremediation, for simulating the fate and transport of contaminants under field conditions. A 2-year field study was conducted using 72 (1.5m long and 0.1 m diameter) column lysimeters with four treatments: Johnsongrass; wild rye grass; a rotation of Johnsongrass and wild rye grass; and unplanted fallow conditions. The developed model represented the fate and transport of contaminant both in vegetated and unplanted soils satisfactorily for field applications. Parameters related to the contaminant concentration in the water phase were the main parameters determining the contaminant fate in the vadose zone and indicated that the bioavailability can be the most important factor in the success of phytoremediation as well as bioremediation applications.

• Journal of Soil and Groundwater Environment
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• v.24 no.3
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• pp.13-23
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• 2019

The purpose of this study is to suggest conceptual models based on finite numerical method that can be used to assess contaminant transport through subsurface and estimate exposed concentration at contaminated site. This study tested various assumptions of the numerical models for contaminant transport in unsaturated and saturated zones to simulate the pathways to the human exposal point. For this purpose, models for seven possible scenarios of contaminant transport were simulated using the numerical code MODFLOW and MT3D. The simulation results that showed different peak concentrations and travel times were compared. In conclusion, the potential utility of the numerical models in the site specific risk analysis suggested as well as future research ramifications.

• Advances in environmental research
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• v.4 no.3
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• pp.183-196
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• 2015

Migration of leachate generated through embankment of construction waste soil (CWS) in low-lying areas was studied through physical and chemical analysis. A leachate solution containing soluble cations from CWS was found to have a pH above 9.0. To determine the distribution coefficients in the alkali solution, column and migration tests were conducted in the laboratory. The physical and chemical properties of CWS satisfied environmental soil criteria; however, the pH was high. The effective diffusion coefficients for CWS ions fell within the range of $0.725-3.3{\times}10^{-6}cm^2/s$. Properties of pore water and the amount of undissolved gas in pore water influenced advection-diffusion behavior. Contaminants migrating from CWS exhibited time-dependent concentration profiles and an advective component of transport. Thus, the transport equations for CWS contaminant concentrations satisfied the differential equations in accordance with Fick's 2nd law. Therefore, the migration of the contaminant plume when the landfilling CWS reaches water table can be predicted based on pH using the effective diffusion coefficient determined in a laboratory test.