Pesticide residues play several key roles as environmental and food pollutants and it is crucial to develop a method for the rapid determination of pesticide residues in environments. In this study, a simple, effective, and sensitive method has been developed for the quantitative analysis of methoxyfenozide in water and soil when kept under laboratory conditions. The content of methoxyfenozide in water and soil was analyzed by first purifying the compound through liquid-liquid extraction and partitioning followed by florisil gel filtration. Upon the completion of the purification step the residual levels were monitored through high performance liquid chromatography(HPLC) using a UV absorbance detector. The average recoveries of methoxyfenozide from three replicates spiked at two different concentrations and were ranged from 83.5% to 110.3% and from 98.1% to 102.8% in water and soil, respectively. The limits of detection(LODs) and limits of quantitation(LOQs) were 0.004 vs. 0.012 ppm and 0.008 vs. 0.024 ppm, respectively. The method was successfully applied to evaluate the behavioral fate of a 21% wettable powder(WP) methoxyfenozide throughout the course of 14 days. A first-order model was found to accurately fit the dissipation of methoxyfenozide in water with and a $DT_{50}$ value of 3.03 days was calculated from the fit. This result indicates that methoxyfenozide dissipates rapidly and does not accumulate in water.
Raheem, Shehata E. Abdel;Aal, Elsayed M. Abdel;AbdelShafy, Aly G.A.;Mansour, Mahmoud H.;Omar, Mohamed
Ocean Systems Engineering
/
v.10
no.3
/
pp.243-266
/
2020
In-place analysis for offshore platforms is required to make proper design for new structures and true assessment for existing structures. In addition, ensure the structural integrity of platforms components under the maximum and minimum operating loads and environmental conditions. In-place analysis was carried out to verify the robustness and capability of structural members with all appurtenances to support the applied loads in either operating condition or storm conditions. A nonlinear finite element analysis is adopted for the platform structure above the seabed and the pile-soil interaction to estimate the in-place behavior of a typical fixed offshore platform. The SACS software is utilized to calculate the natural frequencies of the model and to obtain the response of platform joints according to in-place analysis then the stresses at selected members, as well as their nodal displacements. The directions of environmental loads and water depth variations have an important effect on the results of the in-place analysis behavior. The influence of the soil-structure interaction on the response of the jacket foundation predicts is necessary to estimate the loads of the offshore platform well and real simulation of offshore foundation for the in-place analysis. The result of the study shows that the in-place response investigation is quite crucial for safe design and operation of offshore platform against the variation of environmental loads.
Factors affecting phytotoxicity of dithiopyr in rice such as transplanting depth, seedling age, soil texure were examined and mechanism of phytotoxicity in rice was also determined by absorption study of $^{14}C$-dithiopyr in rice seedlings under above conditions. Rice injury was occurred in shallow transplanting depth, young rice seedlings and sandy soil conditions. Higher amount of dithiopyr was absorbed in rice at shallow transplanting depth and sandy soil conditions which may related to phytotoxicity of dithiopyr.
Kim, Won Tae;Cho, Yong Hyeon;Lee, Jong Mun;Yoon, Yong Han;Kang, Hee Kyoung;Park, Bong Ju;Yoon, Taek Seong;Jang, Kwang Eun;Shin, Kyung Jun;Eo, Yang Joon;Kwak, Moo Young;Song, Hong Seon
Journal of the Korean Society of Environmental Restoration Technology
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v.17
no.1
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pp.13-25
/
2014
The study aims to investigate and analyze actual situations of managing topsoil at forest development sites based on their types, in pursuit of conservation and effective use of national land. To do this, I selected target areas by deducting the typical types of forest development and analyzed the condition of soil at the target areas before and after development. In addition to this, I interviewed associated construction staffs to conduct study on present situations of topsoil management and find out its problems. I also surveyed of relevant experts, with the intention of seeking solutions. The results of the study have been shown that firstly, experts preferred collecting and recycling of topsoil as methods of improvement of soil conditions for plant growth. Secondly, the importance of topsoil has been well noticed and there were few construction sites using the methods. However, working and economical problems have disturbed carrying out these solutions. Thirdly, after constructions, organic matter and total-nitrogen content decreased in general which were necessary for plant growth in terms of soil conditions.
A laboratory experiment was conducted to investigate nitrogen removal from plating wastewater by a soil reactor. A combination of soil, waste oyster shell and activated sludge were used as a loading media in a soil reactor. The addition of 20% waste oyster shell and activated sludge to the soil accelerated nitrification (88.6% ${NH_4}^{+}-N$ removal efficiency) and denitrification (84.3% ${NO_3}^{-}-N$ removal) in the soil reactor, respectively. In continuous removal, the influent ${NH_4}^{+}-N$ was mostly converted to nitrate nitrogen in the nitrification soil reactor and only a small amount of ${NH_4}^{+}-N$ was found in the effluent. When methanol was added as a carbon source to the denitrification soil reactor, the average removal efficiency of ${NO_3}^{-}-N$ significantly increased. The ${NO_3}^{-}-N$ removal by methanol addition in the denitrification soil reactor was mainly due to denitrification. The phosphorus was removed by the waste oyster shell media in the nitrification soil reactor. Moreover, the phosphorus removal in the denitrification soil reactor was achieved by synthesis of bacteria and the denitrification under anaerobic conditions. The approximate number of nitrifiers and denitrifiers was $3.3{\times}10^5\;MPN/g$ soil at a depth of $1{\sim}10\;cm$ and $3.3{\times}10^6\;MPN/g$ soil at a depth of $10{\sim}20\;cm$, respectively, in the soil reactor mixed with a waste oyster shell media and activated sludge.
Journal of The Korean Society of Agricultural Engineers
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v.59
no.5
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pp.31-40
/
2017
The aim of this study is to estimate net irrigation requirements for red pepper during growing period using soil moisture model. The soil moisture model based on water balance approach simulates soil moisture contents of 4 soil layers in crop root zone considering soil moisture extraction pattern. The LAMP (Land-Atmosphere Modeling Package) high resolution meteorological data provided from National Center for AgroMeteorology (NCAM) was used to simulate soil moisture as the input weather data. Study area for the LAMP data and soil moisture simulation covers $36.92^{\circ}{\sim}37.40^{\circ}$ in latitude and $127.36^{\circ}{\sim}127.94^{\circ}$ in longitude. Soil moisture was monitored using FDR (Frequency Domain Reflectometry) sensors and the data were used to validate the simulation model from May 24 to October 20 in 2016. The results showed spatially detailed soil moisture pattern under different weather conditions and soil texture. Net irrigation requirements were also different by location reflecting the spatially distributed weather condition. The average of the requirements was 470.7 mm and averages about soil texture were 466.8 mm, 482.4 mm, 456.0 mm, 481.7 mm, and 465.6 mm for clay loam, sandy loam, silty clay loam, clay, and sand respectively. This study showed spatial differences of soil moisture and the irrigation requirements of red pepper about spatially uneven weather condition and soil texture. From the results, it was demonstrated that high resolution meteorological data could provide an opportunity of spatially different crop water requirement estimation during the irrigation management.
Journal of the Korean Society of Environmental Restoration Technology
/
v.18
no.4
/
pp.1-14
/
2015
A manipulation of zoysiagrass's lateral stems and soil-media; used for slope revegetation, is expected to facilitate the production of high-quality grass. To study the influences on the growth of zoysiagrass depending upon various soil-media conditions, two different types of soil are used. The results obtained - through investigation of its cover rates, leaf color and number - are summarized as follows. In mountain regions soil, there are no significant differences in growth and development of grass in treatments: zoysiagrass's lateral stems treatments with 1cm, 2cm, and 3cm soil-media and treatment with only seeding. Zoysiagrass, in most of the treatments, show about the same growth rates, and at the end, fair visual quality. Zoysiagrass's lateral stems treatments with 2cm, 3cm show slightly better growth, however, thickness of soil-media need not be more than 1cm to obtain an expected quality of lawn. In decomposed granite soil, there appears statistical significance in growth of the grass in treatments: zoysiagrass's lateral stems treatments with 1cm, 2cm, and 3cm soil-media and treatment with only seeding. The thicker the soil-media, the better the growth of grass, and that in treatment with seeding-only shows poor quality in general. And therefore, it is efficacious to plant in 3cm soil-media when quick formation of lawn is necessary; however, using 2cm soil-media is ultimately the most cost-efficient way of formation. But, when time allows - that is, more than three months - 1cm soil-media in decomposed granite soil is reasonable to formate just as effective lawn. And so when performing seeding, additional covering, fertilization or increasing the quantity of seed must be considered.
Kim, Yihyun;Hong, Sukyoung;Lee, Kyoungdo;Na, Sangil;Jung, Gunho
Korean Journal of Soil Science and Fertilizer
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v.47
no.4
/
pp.235-241
/
2014
A ground-based microwave scatterometer has an advantage for monitoring soil moisture content using multi-polarization, multi-frequencies and various incidence angles. In this paper, ground-based multi-frequency (L-, C-, and X-band) polarimetric scatterometer system capable of making observations every 10 min was used to monitor the soil moisture conditions in a corn field over an entire growth cycle. Measurements of volumetric soil moisture were obtained and their relationships to the backscatter observations were examined. Time series of soil moisture content was not corresponding with backscattering coefficient pattern over the whole growth stage, although it increased until early July (Day Of Year, DOY 160). We examined the relationship between the backscattering coefficients from each band and soil moisture content of the field. Backscattering coefficients for all bands were not correlated with soil moisture content when considered over the entire stage ($r{\leq}0.48$). However, L-band Horizontal transmit and Horizontal receive polarization (HH) had a good correlation with soil moisture ($r=0.85^{**}$) when LAI was lower than 2. Prediction equations for soil moisture were developed using the L-HH data. Relation between L-HH and soil moisture shows linear pattern and related with soil moisture content ($R^2=0.77$). Results from this study show that backscattering coefficients of microwave scatterometer appear to be effective to estimate soil moisture content in the field level.
Sangyeong Park;Hyeontae Park;Hangseok Choi;YoungSeok Kim;Sewon Kim
Journal of the Korean Geosynthetics Society
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v.23
no.2
/
pp.53-62
/
2024
Recently, development of non-traditional energy such as oil sands has been actively conducted in the cold region such as Canada. Frozen soil has different thermal and mechanical characteristics from general soil due to its high organic contents. This study evaluated the impact of organic matter content on the thermal and mechanical behavior of frozen soil samples collected from Alberta, Canada, and Gangwon Province, South Korea. As the organic content increases, the maximum dry unit weight decreases and the optimum moisture content increases in compaction tests. In uniaxial compression tests under frozen conditions, the strength of the frozen specimens increased as the temperature decreased. The strength of Canada soil sample increased with higher organic matter content at low temperatures. However, the strength of frozen soil was not significantly affected by organic matter content due to the complex behavior and unfrozen water content. Thermal conductivity tests showed higher thermal conductivity in frozen conditions compared to unfrozen conditions, due to the higher thermal conductivity of ice compared to water. These findings provide essential data for geotechnical design and construction in large-scale projects such as oil sands development in cold regions. Further research is needed to explore the impact of organic matter content on different types of frozen soils.
The correlations between environmental influences on microorganisms in soil and its effects on disease development in ginseng field were studied to obtain some useful data for increasing ginseng production and effective preventive measures against the root rot caused by soil-borne pathogens. The diseased replanted ginseng fields were selected as the diseased field and the healthy plot in first planted field selected as control in three major Korean ginseng producing areas such as Kumsan, Goesan and Poonggi. The physicochemical characteristics of the soil were analyzed and microorganisms susceptible for root rot of ginseng, such as Fusarium spp. and general fungi were investigated for their population density in various soil conditions. Correlations between soil microbial populations and environmental factors were investigated. The numbers of Fusarium spp. propagules were abundant in fall in both soil conditions. The numbers of Fusarium spp. were 1.9 to 2.6 times higher in replanted field than first planted field except Goesan area. Relative ratio of Fusarium spp. to total fungi propagules in replanted field was 1.6 times higher in replanted field than first planted field indicating higher numbers of Fusarium spp. distributed in replanted field of soil. The numbers of propagules of total fungi were increased in June and July and there was no sensitive variation according to the temperature. There was no significant difference in vertical distributions of total fungi according to soil depth, while the total fungi were abundant in the surface layer and $10{\sim}15\;cm$ layer. The contents of organic matter and phosphate in healthy field were somewhat high, and phosphate/organic matter ratio and Mg contents were high in diseased field. All of the soils showed a weak acidic pH of 4.5 to 5.7. Soil moisture contents were increased during winter season, but did not show any significant changes during the growing periods, showing 24.6% in healthy field and 19.5% in diseased field respectively. Soil temperature was the highest in July and August and the lowest in January and February.
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