• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.04a
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• pp.183-186
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• 2002

The objective of this study is to predict behavior of a contaminant plume and concentration of contaminants in soil through tile relations between the concentrations of contaminants in groundwater and in soil on the shallow sandy aquifer contaminated with petroleum hydrocarbons. The current state of the plume and its fate in the study area was simulated by using the MODFLOW-RT3D model and geochemical parameters of grounwater had been monitored and measured during 3 years (1999~2001). The relations between the concentrations of contaminants in each medium were taken from the investigation of site characterization conducted in 1999. Simulation results showed the center of the plume would migrate 407m twenty years later. At that time, the concentration would be decreased down to about 26 mg/$\ell$(93%). In comparison TEX concentration in the groundwater with that in the soil, the value of correlation coefficient (r=0.876) was as high as it could be used. Based on the high r-value, the linear equation was obtained from regression analysis. The results of model simulation by RT3D engine showed that the highest TEX concentration in the groundwater would be 58.8 mg/$\ell$ 16 years later, and then the TEX concentration in soil would be below the alarming level (80 mg/kg) of regulation criteria.

• Journal of Soil and Groundwater Environment
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• v.22 no.6
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• pp.22-28
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• 2017

The accuracy of analytical results in response to the use of different additives ($NH_4Cl$, KCl, $LaCl_3$) and oxidant gases was evaluated and compared by using Atomic Absorption Spectrometry (AAS). Identification of spectroscopic interferences and possible improvements in Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) analysis were also discussed. The average accuracies of total chromium using Certified Reference Materials (CRMs) were found to be 72.1~94.2% in air/acetylene flame condition by AAS, and they were improved to 100.5~110.5% when the oxidants was changed to nitrous oxide rather than adding the additives. The field samples showed similar trends to CRMs, but chromium concentrations were highly variable depending on analytical conditions. The average accuracies using CRMs were estimated to be 89.3~166.1% by ICP-AES, and improved to below 121.7% after eliminating iron interference. Field samples with low chromium and high iron concentration were measured to be > 30% lower in total chromium concentrations by ICP-AES than AAS in nitrous oxide/acetylene flame. Total chromium concentrations in soil could be analyzed with better accuracy under nitrous oxide/acetylene flame by AAS because it was more effective to increase the temperature of the flame than to eliminate the chemical interference for maximizing atomization of chromium. When using ICP-AES, interference substances, total chromium levels, and analytical conditions should be also considered.

• Journal of Soil and Groundwater Environment
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• v.19 no.3
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• pp.15-24
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• 2014

Soil pollution has been recognized as a serious problem because it causes groundwater pollution through medium contacts. Although concentration of individual chemical could be more easily measured by physico-chemical analysis, it is not easy to consider the bioavailability of edaphic receptors living in soil or groundwater. To measure the toxicity of soil, the soil extracts (soil elutriates or soil suspensions in the other words) are often used due to the difficulties of extracting soil pore water. In this study, we reviewed 15 toxicity test methods found in literature to analyze the detail of each extraction method and to recommend the most frequently used extraction methods. The identified most commonly used extraction methods are as following: The 1 : 4 soil:water ratio, 24 hours shaking time, room temperature, dark, and separation of supernatant using a $0.45{\mu}m$ pore size filter.

• The Journal of Engineering Geology
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• v.25 no.4
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• pp.533-545
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• 2015

Spatial and seasonal variations in hydrogeochemical characteristics and the factors affecting the deterioration in quality of shallow portable groundwater in an agricultural area are examined. The aquifer consists of (from the surface to depth) agricultural soil, weathered soil, weathered rock, and bedrock. The geochemical signatures of the shallow groundwater are mostly affected by the NO₃⁻ and Cl⁻ contaminants that show a gradual downward increase in concentration from the upper area, due to the irregular distribution of contamination sources. The concentrations of the major cations do not varied with the elapsed time and the NO₃⁻ and Cl⁻ ions, when compared with concentrations in background groundwater, increase gradually with the distance from the upper area. This result suggests that the water quality in shallow groundwater deteriorates due to contaminant sources at the surface. The contaminations of the major contaminants in groundwater show a positive linear relationship with electrical conductivity, indicating the deterioration in water quality is related to the effects of the contaminants. The relationships between contaminant concentrations, as inferred from the ternary plots, show the contaminant concentrations in organic fertilizer are positively related to concentrations of NO₃⁻, Cl⁻, and SO₄²⁻ ions in the shallow portable groundwaters, which means the fertilizer is the main contaminant source. The results also show that the deterioration in shallow groundwater quality is caused mainly by NO₃⁻ and Cl⁻ derived from organic fertilizer with additional SO₄²⁻ contaminant from livestock wastes. Even though the concentrations of the contaminants within the shallow groundwaters and the contaminant sources are largely variable, it is useful to consider the ratio of contaminant concentrations and the relationship between contaminants in groundwater samples and in the contaminant source when analyzing deterioration in water quality.

• Journal of Soil and Groundwater Environment
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• v.18 no.6
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• pp.1-7
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• 2013

Groundwater development and use have been increasing in Korea causing frequent occurrences of related hazards such as groundwater level decline, land subsidence, and groundwater contamination. To tackle these groundwater problems, central and local governments have set-up and maintained many groundwater monitoring programs such as the National Groundwater Monitoring Network and the Groundwater Quality Monitoring Network, which collect very valuable data on the overall status of domestic groundwater to aid proper groundwater management. However, several problems mainly related to the remediation of contaminated groundwater remain unresolved. Recently, there have been some incidents related to the contamination of groundwater, and these have drawn the concern of the Korean people. Although groundwater contamination has been investigated in detail, actual groundwater remediation work has not yet been implemented. The remediation of the contaminated groundwater must begin immediately in order to sustain the eco-system service of clean groundwater and enhance the welfare of the Korean people.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.02a
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• pp.65-78
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• 2003

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.02a
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• pp.41-48
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• 2003

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1996.11a
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• pp.1-38
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• 1996

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1996.11a
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• pp.110-113
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• 1996

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2001.02a
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• pp.61-73
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• 2001