• Title/Summary/Keyword: soil additives

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Efficiency Evaluation of Transition Metal-Based Additives for Efficient Thermochemical Conversion of Coffee Waste (커피찌꺼기의 효율적인 열화학 전환을 위한 전이 금속 기반 첨가제 효율 평가)

  • Cho, Dong-Wan;Jang, Jeong-Yun;Kim, Sunjoon;Yim, Gil-Jae
    • Journal of Soil and Groundwater Environment
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    • v.27 no.1
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    • pp.17-24
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    • 2022
  • This work examined the effect of mixing transition metal-based additives [FeCl3, Fe-containing paper mill sludge (PMS), CoCl2·H2O, ZrO2, and α-Fe2O3] on the thermochemical conversion of coffee waste (CW) in carbon dioxide-assisted pyrolysis process. Compared to the generation amounts of syngas (0.7 mole% H2 & 3.0 mole% CO) at 700℃ from single pyrolysis of CW, co-pyrolysis in the presence of Fe- or Zr-based additives resulted in the enhanced production of syngas, with the measured concentrations of H2 and CO ranging 1.1-3.4 mole% and 4.6-13.2 mole% at the same temperature, respectively. In addition, α-Fe2O3 biochar possessed the adsorption capacity of As(V) (19.3 mg g-1) comparable to that of ZrO2-biochar (21.2 mg g-1). In conclusion, solid-type Fe-based additive can be highly considered as an efficient catalyst to simultaneously produce syngas (H2 & CO) as fuel energy resource and metal-biochar as sorbent.

Treatment Cost Comparison and Development of Sustainability Indices for Microwave Soil Remediation of TPHs(Total Petroleum Hydrocarbons)

  • Kim, Dong Uk;Koo, Ja-Kong
    • Journal of Soil and Groundwater Environment
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    • v.20 no.5
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    • pp.11-15
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    • 2015
  • The three processes of 1) high- & low-temperature microwave heatings, 2) the soil washing, and 3) the thermal desorption processes in soil remediation are analysed on the treatment cost data for 2003-2012 years. The cost of microwave heating method with at temperature 500-700℃, for 30 minutes, and at 4-6 kW is approximately 10 $/ton (13,000 ₩) due to the deep through heating of micro-wave, the soil washing with chemicals is about 80 $/ton (85,000 ₩) due to the chemicals & duration, and the thermal desorption process is around 40 $/ton (41,000 ₩) from the less efficiency. Furthermore the sustainability has been assessed, and suggestions are made. 1) Green; the minimal environmental footprint, 2) Growth; the least cost, 3) Shared; the social & environmental justice, 4) Smart; the microwave characteristics of deep through irradiation & heating, and 5) Mutuality; the flexibility of the technology. More additives including water, the government support, and public relation are suggested realizing the microwave in this condition is not harmful to human beings.

A study on selection and size of Earth in application of Rammed Earth (흙다짐 적용을 위한 흙의 선정 및 입도조건에 관한 연구)

  • Hwang, Hey Zoo;Kim, Tae Hun;Yang, Jun Hyuk
    • KIEAE Journal
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    • v.9 no.2
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    • pp.65-71
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    • 2009
  • Results from tests for what mixing rate of soil and sand is proper for the rammed earth and for how much additives are optimum are as under. 1) In the test to evaluate what mixing rate of soil and sand is desirable, peptizing property and surface sticking rate are found similar in its degree, but compression strength is found most stable when the ratio of soil and sand mixing shows 30:70 which indicates the best mixing rate of soil and sand. 2) In a test to add hydrated lime, compression strength, peptizing property, and surface sticking rate are found best when the mixing rate of soil and sand shows 23:7. 3) In a test to add sea weeds, the peptizing property goes down at 75% of sea weeds input a little bit more than at 100%, but compression strength shows best at 75% which is thought to be the best rate. 4) In a drop test, more soil powder mixed, the sticking strength gets better and more sands are contained, the sticking strength gets far worse to be scattered in powder type. 5) As concluding all results mentioned in the above item, the most desirable mixing rate of soil, sand, and hydrated lime is found to be 23:7:70 for the rammed earth where compression strength, peptizing property, and surface sticking rate are best.

Geotechnical behaviour of nano-silica stabilized organic soil

  • Kannan, Govindarajan;Sujatha, Evangelin Ramani
    • Geomechanics and Engineering
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    • v.28 no.3
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    • pp.239-253
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    • 2022
  • Suitable techniques to stabilize organic soil and improve its engineering behaviour are in demand. Despite various alternatives, nano-additives proved to be an effective stabilizer owing to their strength enhancing properties. The study focuses on using nano-silica as a potential stabilizer to improve organic silt. Soil was treated with four dosages of nano-silica namely 0.2%, 0.4%, 0.6% and 0.8% of dry weight of the soil. Nano-silica treated soil showed a strength increase of nearly 25% at a dosage of 0.4% after curing for two hours. Strength of the treated soil improved with age. Strength improved by nearly 62.9% after 28 days of curing and 221.4% after 180 days of curing due to formation of Calcium - Silicate - Hydrate (CSH) gel in the soil matrix. Dosage of 0.6% nano-silica is observed to be the optimum dosage. Coefficient of permeability and compression index showed an increase by 13.32 and 5.5 times respectively owing to aggregation of particles and creation of void spaces as visualized from the scanning electron micrographs. Further model foundation study and numerical parametric studies using PLAXIS 2D indicate that optimized and economic results can be obtained by varying the additive dosage with depth.

The Effect of Hydration Retarder on Initial Compressive Strength of Sodium Silicate-Cement Grouted Soil (시멘트 수화지연제가 규산나트륨-시멘트 그라우트 초기강도에 미치는 영향에 관한 연구)

  • Chun, Byung-Sik;Yoo, Young-Nam
    • Proceedings of the Korean Geotechical Society Conference
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    • 2005.10a
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    • pp.453-460
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    • 2005
  • Sodium silicate - the usual portland cement which accomplishes a cement pouring reconsideration main stream and sodium silicate(No.3) after reacting sodium silicate(No.3) with the reaction sodium silicate where oxidation natrium which is included does not react with the cement receiving stiffening water it will burn together on underwater and to become the durability lacks pouring it is recognized. From the hazard which improves an advantage it used the additive which relates in congealing and stiffening of the portland cement and sodium tripolyphosphate(STPP) addition hour initial material age(72 hours at once) which does to be revealed the at high-in-tensity is discovered while accomplishing. The effect of additives on the reactions of sodium silicate solution and cement suspesion was investigated by various physical and chemical tests, such as Si-NMR, XRD, SEM uniaxial compression test. The additives were STPP(sodium tripolyphosphate), EDTA, SUGAR. The compressive strength of sodium silicate(No.3) - cement grout with additives was about $1.5{\sim}10$ times higher than that without additive in early age(72 hours).

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Strength Characteristics of Soil-Bentonite Mixture (Soil-Bentonite 혼합토의 강도 특성)

  • Jin, Guang-Ri;Shin, Dong-Hoon;Im, Eun-Sang;Kim, Ki-Young
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.03a
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    • pp.844-851
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    • 2009
  • A soil mixture with low permeability and bentonite as an additive has been highly utilized as a cutoff material in landfills, banks, and dams. Even though it is anticipated that the water can seep through shear failures in the filter layer due to external loads and embankment loads during construction, usually only the coefficient of permeability of the soil mixture is considered rather than the changes of strength from the different amounts of additives. Therefore, the amount of bentonite was changed between 0%~4% in the soil mixture of the bed material to conduct a series of unconfined compressive strength, tensile strength, and shear strength tests on a specimen in order to study the characteristics of the strength. In the result, the unconfined compressive and tensile strength were increased along with the increased amount of bentonite in the low water content; however, the tensile strength in the consolidated-drained shear test generally showed similar values without significant changes.

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Utilization of carrageenan as an alternative eco-biopolymer for improving the strength of liquefiable soil

  • Regina A. Zulfikar;Hideaki Yasuhara;Naoki Kinoshita;Heriansyah Putra
    • Geomechanics and Engineering
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    • v.33 no.2
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    • pp.221-230
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    • 2023
  • The liquefaction of soil occurs when a soil loses strength and stiffness because of applied stress, such as an earthquake or other changes in stress conditions that result in a loss of cohesion. Hence, a method for improving the strength of liquefiable soil needs to be developed. Many techniques have been presented for their possible applications to mitigate liquefiable soil. Recently, alternative methods using biopolymers (such as xanthan gum, guar gum, and gellan gum), nontraditional additives, have been introduced to stabilize fine-grained soils. However, no studies have been done on the use of carrageenan as a biopolymer for soil improvement. Due to of its rheological and chemical structure, carrageenan may have the potential for use as a biopolymer for soil improvement. This research aims to investigate the effect of adding carrageenan on the soil strength of treated liquefiable soil. The biopolymers used for comparison are carrageenan (as a novel biopolymer), xanthan gum, and guar gum. Then, sand samples were made in cylindrical molds (5 cm × 10 cm) by the dry mixing method. The amount of each biopolymer was 1%, 3%, and 5% of the total sample volume with a moisture content of 20%, and the samples were cured for seven days. In terms of observing the effect of temperature on the carrageenan-treated soil, several samples were prepared with dry sand that was heated in an oven at various temperatures (i.e., 20℃ to 75℃) before mixing. The samples were tested with the direct shear test, UCS test, and SEM test. It can increase the cohesion value of liquefiable soil by 22% to 60% compared to untreated soil. It also made the characteristics of the liquefiable increase by 60% to 92% from very loose sandy soil (i.e., ϕ=29°) to very dense sandy soil. Carrageenan was also shown to have a significant effect on the compressive strength and to exceed the liquefaction limit. Based on the results, carrageenan was found to have the potential for use as an alternative biopolymer.

Studies on the Consolidation Characteristics of Marine Clay Stabilized with Lime and Briquette Ash (석회 및 연탄회 안정처리토의 압밀특성에 관한 연구)

  • 김재영;유병옥;주재우
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.34 no.4
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    • pp.48-58
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    • 1992
  • This study was conducted to investigate the consolidation characteristics of the marine clay, treated with predetermined ratios of lime and briquette ash. The standard consolidation test was performed for the sample of mixture remoulded under the condition of optimum moisture content. The results obtained were as follows ; 1.The increase of the consolidation coefficient due to load increament was larger in the lime treated soil and briquette ash treated soil than in the untreated soil. The decrease of the compression index due to admixing ratio of additives was smaller in the former than in the latter. 2.The increase of the secondary consolidation coefficient of the untreated soil due to load increment was minimal, while that of lime treated soil and the lime-briquette ash treated soil was conspicuous and that of briquette ash treated soil was slight. 3.The $C\alpha$/Cc relationship of untreated soil was represented by colsely distributed points. That of briquette ash treated soil, lime treated soil and the lime-briquette ash treated soil was represented by linear distribution. The $C\alpha$/Cc values of untreated soil, briquette ash treated soil and lime treated soil were approximately 0.049, 0.044 and 0.031, respectively. 4.The maximum consolidation coefficient was obtained with lime and briquette ash (lime : briquette .h 2 :1) mixture ratio of 15%. And the minimum secondary consolidation coefficient, compression index was obtained with same mixture ratio. The required quantity of lime could be reduced and the consolidation was accelerated by applying the above mixture ratio.

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Application of Laboratory Pressurized Vane Shear Test and Discrete Element Method for Determination of Foam-conditioned Soil Properties (폼제에 의해 개선된 흙의 물성 도출을 위한 실내 가압 베인 전단시험 및 개별요소법의 적용)

  • Kang, Tae-Ho;Lee, Hyobum;Choi, Hangseok;Choi, Soon-Wook;Chang, Soo-Ho;Lee, Chulho
    • Journal of the Korean Geosynthetics Society
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    • v.19 no.4
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    • pp.65-74
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    • 2020
  • In earth pressure balance (EPB) shield TBM tunnelling, the application of soil conditioning which improves properties of the excavated muck by additives injection, is generally used for enhancing the performance of TBM. Therefore it is important to apply the soil conditioning in the numerical model which simulates excavation performance of TBM equipment, but related studies on a method that simulates soil conditioning are insufficient to date. Accordingly, in this study, an laboratory pressurized vane test apparatus was devised to evaluate the characteristics of conditioned soil. Using the apparatus, the vane shear tests were performed on foam-conditioned soil with different shear rates, and the test was numerically simulated with discrete element method (DEM). Finally, the contact properties of particles in DEM were determined by comparing the results of test and analysis, and it indicates that the applicability of pressurized vane test and DEM model for reproducing soil conditioning in TBM excavation model with DEM.

Soil Adsorption Characteristics of Heavy Metals and Antibiotics in Piggery Waste Fertilizer (양돈 퇴, 액비 내 중금속 및 항생제의 토양 흡착특성 연구)

  • Oa, Seong Wook
    • Journal of Wetlands Research
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    • v.14 no.3
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    • pp.365-374
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    • 2012
  • Due to the wide use of feed additives on pig farms, large content of heavy metals and antibiotics have been found in piggery wastes. More than 90 % of piggery wastes were applied to crop field in Korea. The metals and antibiotics originated from piggery waste in the soil may affect plant growth and human health. To examine the adsorption capacity and residual ratio of heavy metals and antibiotics to the soil, a couple of jar test and leaching tests were conducted. While 86.4 % of zinc and 68% of copper applied were adsorbed to soil particles, while over than 60% of antibiotics in pig manure liquid fertilizer were leaked out to effluent.