• Title/Summary/Keyword: sodium leakage

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Effect of pH in Sodium Periodate based Slurry on Ru CMP (Sodium Periodate 기반 Slurry의 pH 변화가 Ru CMP에 미치는 영향)

  • Kim, In-Kwon;Cho, Byung-Gwun;Park, Jin-Goo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.117-117
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    • 2008
  • In MIM capacitor, poly-Si bottom electrode is replaced with metal bottom electrode. Noble metals can be used as bottom electrodes of capacitors because they have high work function and remain conductive in highly oxidizing conditions. In addition, they are chemically very stable. Among novel metals, Ru (ruthenium) has been suggested as an alternative bottom electrode due to its excellent electrical performance, including a low leakage of current and compatibility to high dielectric constant materials. Chemical mechanical planarization (CMP) process has been suggested to planarize and isolate the bottom electrode. Even though there is a great need for development of Ru CMP slurry, few studies have been carried out due to noble properties of Ru against chemicals. In the organic chemistry literature, periodate ion ($IO_4^-$) is a well-known oxidant. It has been reported that sodium periodate ($NaIO_4$) can form $RuO_4$ from hydrated ruthenic oxide ($RuO_2{\cdot}nH_2O$). $NaIO_4$ exist as various species in an aqueous solution as a function of pH. Also, the removal mechanism of Ru depends on solution of pH. In this research, the static etch rate, passivation film thickness and wettability were measured as a function of slurry pH. The electrochemical analysis was investigated as a function of pH. To evaluate the effect of pH on polishing behavior, removal rate was investigated as a function of pH by using patterned and unpatterned wafers.

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THE EFFECT OF INTRACANAL BASE TO PROTECT THE CERVICAL LEAKAGE OF BLEACHING AGENTS (표백제의 치경부 누출을 방지하기 위한 근관 내 이장재의 효과)

  • Kwon, Su-Mi;Hwang, Su-Jin;Lee, Se-Joon;Lee, Kwang-Won
    • Restorative Dentistry and Endodontics
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    • v.25 no.1
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    • pp.144-152
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    • 2000
  • Intracoronal bleaching is currently disregarded by many clinicians because of the potential consequence of cervical resorption. To prevent this complication it is recommended that intra coronal barrier materials be placed over the root canal obturation and sodium perborate be used with water rather than with hydrogen peroxide. The purpose of this study was to evaluate the amount of the hydrogen peroxide penetration according to the difference in intracanal base materials and sodium perborate preparation. Fifty extracted intact premolars were instrumented, and filled with gutta-percha. And then the outer surface of the teeth was sealed with wax exposing the CEJ. The prepared teeth were placed in plastic tubes containing 1.5ml distilled water with their entire root submerged into the solution, The teeth were divided into the following five groups. In the first two groups gutta-percha was removed without placement of barrier, and then water or superoxole(30% $H_2O_2$) with sodium perborate were used respectively for bleaching. In the other three groups, after removal of gutta-percha, an intracanal isolating barrier(ZPC, IRM, Fuji II LC) was placed and then bleached with sodium perborate and superoxole. The bleaching procedure was performed 4 times with 1 week interval. The results were as follows : 1. All the groups showed a tendency of increasing penetration amount with increasing treatment times(P<0.05). 2. After the 1st and 2nd treatments, there was no significant difference in microleakage among the groups. 3. After the 3rd bleaching with superoxole and sodium perborate, there was no significant difference in microleakage between gutta-percha alone group and gutta-percha with ZPC, Fuji II LC barrier group. But significant difference was found between IRM barrier group and other groups(P<0.01). 4. After the 4th bleaching with superoxole and sodium perborate, there was no significant difference between gutta-percha alone group and gutta-percha with barrier groups. 5. After the 4th treatment, the group bleached with sodium perborate and water without barrier showed lower hydrogen peroxide penetration than that of other groups(P<0.01).

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THE PROTEIN COMPOSITION OF GINGIVAL CREVICULAR FLUID SAMPLED FROM NORMAL SUBJECTS AND PATIENTS WITH PERIODONTAL DISEASE (정상치은열구액과 치주질환시 치은열구액의 단백질 조성비교에 관한 연구)

  • Kim, Soo-Ah;Lee, Jin-Young;Kim, Hyong-Seop
    • Journal of Periodontal and Implant Science
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    • v.23 no.3
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    • pp.391-398
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    • 1993
  • Gingival crevicular fluid (GCF) is a promising source for markers of destructive periodontal disease activity. This study was undertaken to evaluate the protein composition of GCF in varying stages of the gingival inflammatory response. GCF sampled from 26 people with clinically healthy gingiva and 18 people with periodontitis were examined via sodium dodecyl sulphate polyacrylamide gel electrophoresis(SDS/PAGE). The result were as follows. 1. Total amount of GCF protein of diseased group significantly different from that of normal group. But difference in protein concentration was not that significant. 2. In analyzing GCF with SDS/PAGE, it was suggested that albumin is used as indicator plasma protein leakage because of heavily staining bond of albumin in patients with periodontal disease. 3. In diseased group, overall bonds of protein and bands of high molecular weight protein were heavily stained. It was proved useful information on high molecular plasma protein leakage with increasing vascular permeability due to inflammation.

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Production of Acrylic Acid from Acrylonitrile by Immobilization of Arthrobacter nitroguajacolicus ZJUTB06-99

  • Shen, Mei;Zheng, Yu-Guo;Liu, Zhi-Qiang;Shen, Yin-Chu
    • Journal of Microbiology and Biotechnology
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    • v.19 no.6
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    • pp.582-587
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    • 2009
  • Immobilized cells of Arthrohacter nitroguajacolicus ZJUTB06-99 capable of producing nitrilase were used for biotransformation of acrylonitrile to acrylic acid. Six different entrapment matrixes were chosen to search for a suitable support in terms of nitrilase activity. Ca-alginate proved to be more advantageous over other counterparts in improvement of the biocatalyst activity and bead mechanical strength. The effects of sodium alginate concentration, $CaCl_2$ concentration, bead diameter, and ratio by weight of cells to alginate, on biosynthesis of acrylic acid by immobilized cells were investigated. Maximum activity was obtained under the conditions of 1.5% sodium alginate concentration, 3.0% $CaCl_2$ concentration, and 2-mm bead size. The beads coated with 0.10% polyethylenimine (PEI) and 0.75% glutaraldehyde (GA) could tolerate more phosphate and decrease leakage amounts of cells from the gel. The beads treated with PEI/GA could be reused up to 20 batches without obvious decrease in activities, which increased about 100% compared with the untreated beads with a longevity of 11 batches.

Sorting of Aged Seeds Using Leakage Substances of Crop Seeds (종자 누출물질을 이용한 노화종자의 선별)

  • Lee, Dong-Jin;Lim, Moo-Sang;Chu, Young-Ha;Chung, Kil-Woong;Kim, Bong-Ku
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.42 no.6
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    • pp.783-789
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    • 1997
  • This study was conducted to identify leakage of fluorescent substances out of 56 crops and to develop sorting methods of nonviable seeds of Chinese cabbage. Fluorescent substances were detected from 36 species, Chinese cabbage, radish, broccoli, cauliflower, egg plant and rape seed etc. In Chinese cabbage, the germination rate of non-sorted seeds decreased rapidly with ageing of seeds at 45$^{\circ}C$ and 100%. After Chinese cabbage seeds soaked for 4hrs and coated with cellulose, the sorting ratio of non fluorescent seeds were decreased 91.3% to 1.7% by increasing ageing periods from control to 8 days, while fluorescent seeds were increased drastically from 8.7% to 98.3%. Also, incubation of water soaked dead seeds of Chinese cabbage treated with 0.5-1.0% ninhydrin and 0.01N sodium thiosulfate for 30~60 minutes at 35$^{\circ}C$ developed purple color.

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Evaluation of Microbial Analysis and Application of Reduction Technology in a Dairy Factory (목장형 유가공장의 미생물 분석 및 저감기술 적용 평가)

  • Jong-Hui Kim;Eun-Seon Lee;Bu-Min Kim;Jun-Sang Ham;Mi-Hwa Oh
    • Journal of Dairy Science and Biotechnology
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    • v.41 no.4
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    • pp.203-210
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    • 2023
  • Bacterial contamination negatively affects the quality, functionality, and safety of dairy products. Adherent populations of bacteria, referred to as biofilms, grow on the surfaces of dairy processing equipment and are the primary cause of dairy contamination. In addition, microorganisms present in the farm environment and dairy factory can contaminate the Clear-In-Place (CIP) line through raw milk transport pipes; therefore, exhaustive management is required. In dairy manufacturing facilities, biofilm formation is controlled using CIP systems that primarily require sodium hydroxide and nitric acid. However, the leakage or incomplete removal of these potently active compounds can be harmful to humans. In the present study, we compared the eradication of Escherichia coli and other bacteria using commercially available combinations of sodium hypochlorite (NaClO) and citric acid, which are recognized by the Korean Ministry of Food and Drug Safety (MFDS) as food disinfectants. When considered in the CIP system of the field manufacturing process, E. coli was not detected (compared to detection before treatment), and other bacteria were detected at 0-32 culture-forming units (CFU)/cm2. The residual amount of chlorine ions after CIP treatment was similar to that in tap water, and there was no significant difference in the overall components of the fermented dairy products. Therefore, the NaClO/citric acid CIP system can be safely applied in dairy manufacturing processes.

Production of SCC Flaws and Evaluation Leak Behavior of Steam Generator Tubes (누설 및 파열실험용 SCC 결함 전열관 제작 및 누설거동 평가)

  • Hwang, Seong-Sik;Jung, Man-Kyo;Park, Jang-Yul;Kim, Hong-Pyo
    • Corrosion Science and Technology
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    • v.8 no.5
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    • pp.188-192
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    • 2009
  • A forced outage due to a steam generator tube leak in a Korean nuclear power plant was reported.1) Primary water stress corrosion cracking has occurred in many tubes in the plant, and they were repaired using sleeves or plugs. In order to develop proper repair criteria, it is necessary to understand the leak behavior of the tubes containing stress corrosion cracks. Stress corrosion cracks were developed in 0.1 M sodium tetrathionate solution at room temperature. Steam generator(SG) tubes with short cracks were successfully fabricated with a restricted solution contact method. The leak rates of the degraded tubes were measured at room temperature. Some tubes with 100 % through wall cracks showed an increase of leak rate with time at a constant pressure.

A Study On the Corrosion Tendency of Bottom Plates and Corrosion Prevention Measures in Hazmat Tanks (위험물저장탱코밑판의 부식 성향분석 및 부식예방 방안에 관한 연구)

  • Choi, Jeong Soo;Ro, Kyung Jin
    • Journal of the Society of Disaster Information
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    • v.4 no.1
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    • pp.138-152
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    • 2008
  • The most important factor in the maintenance of chemical industry facilities is related with deterioration and corrosion. Leakage of hazardous materials is likely to occur because the confirmation and maintenance of bottom plates are very difficult while the bottom corrosion of the massive hazmat-storage facilities is most dangerous especially. As a result of the analysis of the corrosion locations, areas, usage condition of 287 hazmat-storage tanks on this syudy, it is concluded that the main external corrosion factors are the inflow of moisture and the materials inducing corrosion in the air such as sodium chloride and the main internal corrosion factors are corrosion react caused by stay of seawater, sulfur and moisture in hazmat for a long time without appropriate discharges. It is anticipated that the corrosion of bottom plates can be restrained effectively by establishing the proper measures for the each corrosion cause.

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Comparison of apical seal with or without the use of dentin adhesive system

  • Lee, Min-Jo;Choi, Kyoung-Kyu;Choi, Gi-Woon
    • Proceedings of the KACD Conference
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    • 2003.11a
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    • pp.600-600
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    • 2003
  • I. Objectives Effective endodontic obturation must provide a complete, three-dimensional filling of the root canal system, preventing the communication of fluids between root canal and surrounding periapical tissues. The objective of this study was to compare the apical leakage with or without the use of dentin adhesive system. II. Materials and Methods Forth extracted human teeth with single canals were decoronated. Root canals were instrumented using GT rotary files and Profile .04 file up to #40, 1mm short of the apex. After each instrumentation, copious irrigation with 5.25% sodium hypochlorite solution and confirmation of apical patency were performed.(omitted)

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Evaluation of Chemical Resistance Performance of Synthetic Rubber and Cement Based Injection Repair Materials Used in Underground Concrete Structures (지하 콘크리트 구조물에 적용되는 합성고무계 및 시멘트계 주입형 보수재료의 화학 저항성능평가)

  • Kim, Soo-Yeon;Lee, Yeon-Sil;Song, Je-Young;Kim, Byoungil;Oh, Sang-Keun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.5
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    • pp.148-155
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    • 2017
  • In this study, by using the international standards ISO TS 16774, Part 2 Test method for chemical resistance as a quality control method of injection type repair material used for leakage crack of underground concrete structure, the performance requirement against of chemical environment of underground concrete structures for repair materials was tested. For this testing 3 types for each of the 2 classes of repair materials(synthetic rubber, cement), with a total of 9 types repair materials, were selected and examined. As a result, the test results showed that the smallest performance deterioration by the change in the mass was with the synthetic rubber(RG) type as opposed to the cement type system, showing that the synthetic rubber type had the strongest relative resistance to chemical exposure. Furthermore, it is necessary to investigate the material with high resistance to chemical substances and to examine the material which can increase resistance to sodium hydroxide and sodium chloride in cement system. These results can be used as a basic index for the selection of repair materials with the strongest resistance to chemical environment found in concrete structures. In addition, it is expected that the test results derived in this study can be used as reference data that can be reflected in the quality improvement of the maintenance material to be developed later.