• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.74.1-74.1
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• 2011

탄소나노튜브는 높은 전기 전도성과 열 전도성을 가지며, 이러한 특성 때문에 21세기를 주도해 나갈 수 있는 차세대 첨단 소재로서 각광을 받고 있다. 또한 최근에는 나노공학기술의 발달로 인하여 획기적으로 높은 열전도도를 나타내는 다중벽 탄소나노튜브(Multi-walled Carbon Nanotubes, MWCNTs)의 대량 생산이 가능하게 되면서 다중벽 탄소나노튜브의 높은 열전도도 특성을 이용하여 탄소나노튜브를 기본 유체 및 기능성 유체에 안정하게 분산 시킨 후 이를 이용하고자 하는 연구가 활발히 진행되고 있으며, 탄소나노튜브를 유체에 안정하게 분산시키기 위한 방법으로는 기계적 분산법, 물리적 흡착에 의한 분산법, 화학적 개질에 의한 분산법이 있다. 따라서 본 연구에서는 이들 분산 방법과 탄소나노튜브 입자의 물성치에 따른 나노유체의 특성을 알아보기 위하여 나노유체의 열전도도와 점도 특성을 비교 분석하였다. 모든 물성치는 같지만 탄소나노튜브의 길이만 다른 두 종류의 다중벽 탄소나노튜브에 각각 계면 활성제(Sodium Dodecyl Sulfate, SDS) 100 wt%와 고분자 화합물(Polyvinyl Pyrrolidone, PVP) 300 wt%를 첨가하여 나노유체를 제조하였으며, 산화처리 된 다중벽 탄소나노튜브(Oxidized Multi-Walled Carbon Nanotubes, OMWCNTs)를 증류수에 초음파 분산하여 산화나노유체를 제조하였다. 나노유체의 열전도도는 전기 전도성 유체의 비정상 열선법(Transient Hot-wire Method)을 이용하여 측정하였고, 나노유체의 점도는 회전형 디지털 점도계를 이용하여 측정하였다. 실험 결과, 상온에서 동일 혼합비의 나노유체를 비교했을 때, 산화나노유체가 SDS 100 wt%, PVP 300 wt%를 혼합한 다른 나노유체보다 높은 열전도도 특성을 보였으며 점도 특성 또한 가장 낮은 것으로 측정되었다. 특히 상온에서 0.1vol%의 산화 CM-100 나노유체는 증류수보다 열전도도가 8.34%가 증가하였고, $10^{\circ}C$의 저온에서는 상온에서 증류수와 비교하여 측정된 열전도도 값보다 0.36%가 감소한 7.98%가 증가함을 보였다. 본 연구를 통하여 얻어진 결과는 높은 열전도도를 필요로 하는 열교환기의 작동유체나 기타 활용 분야에 대한 기초 자료로써 유용한 정보를 제공할 것이라 판단된다.

• Analytical Science and Technology
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• v.9 no.2
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• pp.139-144
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• 1996

The spectrophotometric determination method of scandium with eriochrome cyanine R(ECR) and the composition ratio of the complex were investigated in the presence of surfactants. The absorbance increase and red shift of maximum adsorption wavelength of Sc(III)-ECR complex were observed in cetyltrimethylammonium bromide (CTMAB), but those changes were not observed in the sodium dodecyl sulfate(SDS) and Triton X-100. A volume of 5ml of $1{\times}10^{-3}M$ ECR and 10ml of $2{\times}10^{-4}M$ CTMAB are necessary for the determination of $1{\times}10^{-7}{\sim}3.0{\times}10^{-6}M$ Sc(III) at pH 6.5. The apparent molar absorption coefficient of the Sc(III)-ECR-CTMAB, temary complex at 610nm is $5.6{\times}10^5mol^{-1}cm^{-1}L$ and its detection limit is $1.0{\times}10^{-7}M$. The binary complex composition of Sc(III)-ECR is 1:2 and the ternary complex composition of Sc(III)-ECR-CTMAB is 1:3:1.

• Economic and Environmental Geology
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• v.35 no.5
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• pp.421-428
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• 2002

Lab-scale experiments were conducted to evaluate the effect of surface tension reduction on the extension of the influence zone and the VOC removal efficiency of ground water sparging. A glass column packed with coarse sand was used for VOC removal test at two different surface tensions. A glass column without porous media was also used fer control purpose prior to sand-packed column test. A quasi-two-dimensional glass box model, packed with a sand, was used fer sparging zone tests at different water surface tensions. Surface tension of the aquoues solution used in this study was controlled using sodium dodecyl sulfate (SDS). For the glass, sand column experiments, total amount of air filled in the media increased as surface tension decreased. Toluene (used as VOC in this study) removal rate increased slightly with decreased surface tension f3r both free water column and sand-packed column. Air sparging zone extended up to 500% as the surface tension decreased. Combining the results from two different experiments, VOC removal efficiency is expected to increase significantly with surface tension reduction.

• Journal of Animal Science and Technology
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• v.63 no.2
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• pp.417-425
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• 2021

The use of edible insects to replace meat protein is important to ensure future global food security. However, processed foods using edible insects require development to enhance consumer perception. Here, we examined the physicochemical characteristics and rheological properties of emulsions prepared from different edible insect larvae. Three edible insect species (Tenebrio molitor, Allomyrina dichotoma and Protaetia brevitarsis seulensis) were used to prepare larval emulsions that were formulated with 65% of insect larvae, 20% of pork back fat, and 15% ice. The A. dichotoma emulsion had the highest pH and lightness, redness, and yellowness values, while the T. molitor emulsion had the lowest pH and lightness, redness, and yellowness values. The T. molitor emulsion had the highest hardness, gumminess, chewiness, and apparent viscosity values but the lowest springiness and cohesiveness values. According to the sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE) analysis, T. molitor had the thickest bands, followed by P. brevitarsis seulensis. The differential scanning calorimetry distributions for the T. molitor and A. dichotoma emulsions showed one peak, while that of the P. brevitarsis seulensis emulsion had two peaks. The collective results suggest that T. molitor was the most suitable candidate (of the three tested species) for use as a meat replacement in terms of its physicochemical and rheological properties. It is important that such properties of insect-based emulsions are maintained using various technologies.

• Macromolecular Research
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• v.8 no.6
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• pp.253-260
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• 2000

Biodegradable wafers were prepared with poly (hydroxybutyrate-co-hydroxyvalerate) (PHBV;5, 10, and 15 mole% for 3-hydroxyvalerate) by simple heat pressing method for the sustained release of antibiotic agent, gentamicin sulfate (GS) to investigate the possibility of the treatment for osteomyelitis. The effects of hydroxyvalerate (HV) content, thickness of wafers, various types of additives such as sodium dodecyl sulfate (SDS), microcrystalline cellulose, polyvinylpyrrolidone, and hydroxypropylcellulose (HPC), and different initial drug loading ratio on the release profile have been investigated. In vitro release studies showed that different release patterns and rates could be achieved by simply modifying factors in the preparation conditions. PHBV wafers with 3 mm thickness, 10% of GS initial loading, 15% of HV content and addition of 5% of SDS and HPC were free from initial burst and a near-zero-order sustained release was observed for over 30 days. It might be suggested that the mechanisms of G5 release may be more predominant simple dissolution and diffusion of GS than erosion of PHBV in our system.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.10 no.1
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• pp.13-23
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• 1984

The fluorescence intensity rations (F2.F1) of excimer (F2) to monomer (F1) of pyrene were measured as a function of the concentration of sodium dodecyl sulfate (SDS). It was found that there were not gross changes in size and shape of sphere-shape micelles in the first micelle concentration, while at concentrations above the second critical micelle concentration (CMC) the micelles grew in size with increasing concentration. Fluorescence intensities of 8-anilinonaphthalene 1-sulfonate (ANS) were also monitored as a micellar probe with varying concentrations of SDS. Results suggested that a phase transition from sphere-shaped micelles to hemicapped rod-like micelles occurred at the second CMC (17). A general formula for the axial ratio of ellip-soil-shaped micelle in the first micelle concentration was suggested. According to this general formula, the axial ratio of SDS, sodium lauryl ether sulfate and sodium laurate were 1:1, 5:2, and 5:3, respectively. The electrolyte-induced phase transition from spherical to hemicapped rod-like micelles occurred and the size of hemicapped rod-like micelles grew with increasing electrolyte concentrations. The maximum concentrations of solubilzed benzene in sphere-shaped micelles and hemicapped rod-like micelles were measured by differential spectrohpotometry. The hemicapped rod-like micelles in the presence of electrolytes grew in size with increasing amount of benzene solubilized.

• Journal of the Korean Applied Science and Technology
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• v.18 no.4
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• pp.249-253
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• 2001

A proposed method of determining the composition of mixed micelles in equilibrium with monomer of known composition is described. The systems were sodium ${\alpha}-sulfonated$ dodecanoyl ethyl esther (${\alpha}-SR_{12}Et$) or sodium dodecyl sulfate(SDS)-polyoxyethylene 23 lauryl ether (Brij 35) un water and in 0.1M sodium chloride solution at $25^{\circ}C$. This technique applies the Gibbs-Duhem equation to the mixed micelles, which is treated as a pseudophase. This proposed methodology, which needs only critical micelle concentration data as a function of monomer composition, is applied to an anionic/nonionic surfactant pair. The calculated monomer-micelle equilibrium is found to be very similar to the much-used regular solution for nonideal systems.

• Journal of Chest Surgery
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• v.32 no.11
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• pp.998-1003
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• 1999

Background: Bovine pericardium treated with glutaraldehyde(GA) is one of the most popular prosthetic materials. However, its late calcific degeneration after implantation results in early failure of the prosthesis. Therefore, we investigated the effects of combined treatment with sodium dodecyl sulfate(SDS) and glutamate on calcific degeneration of GA treated bovine pericardium. Material and Method: Sixty square-shaped pieces of bovine pericardia were fixed in 0.625% GA solution with 4g/L MgCl2.6H2O as a control group (group 1). Sixty pieces pretreated with 1% SDS (group 2) and sixty pieces posttreated with 8% glutamate (group 3) were also fixed in the same GA solution. Sixty pieces pretreated with 1% SDS and posttrated with 8% glutamate were also fixed in the same GA solution (group 4). After 1 month of fixation, the pieces were implanted into the belly of sixty Sprague-Dawley rat subdermally and were extracted 1 month, 2 months and 3 months after the implantation. With an atomic absorption spectrophotometry, we measured the calcium amount deposited. Result: The calcium deposition in 1 month was 2.01$\pm$0.13 mg/g in group 1, 1.45$\pm$0.31 mg/g in group 2, 2.49$\pm$0.15 mg/g in group 3 and 0.75$\pm$0.27 mg/g in group 4. In 2 months, it was 3.57$\pm$0.15 mg/g in group 1, 0.98$\pm$0.30 mg/g in group 2, 3.46$\pm$0.12 mg/g in group 3, and 1.48$\pm$0.39 mg/g in group 4, and 5.45$\pm$0.42 mg/g in group 1, 2.43$\pm$0.53 mg/g in group 2, 4.20$\pm$0.55 mg/g in group 3, and 1.02$\pm$0.27 mg/g in group 4 in 3 months. The calcium depositions in group 2 and 4 were less than those of group 1 and 3 in 1 month 2, months, and 3 months(p<0.01). The calcium depositions in group 1, 2 and 3 increased with time. However, they remained unchanged in group 4, which was statistically significant(p<0.01). Conclusion: Pretreatment with SDS is effective in reducing calcification of GA treated bovine pericardium, and the combined method of pretreatment with SDS and posttreatment with glutamate was more effective than the other methods.

• Journal of the Korean Chemical Society
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• v.53 no.2
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• pp.125-132
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• 2009

The magnetized water is known to have a unique pattern of hydrogen bond between water molecules, thereby producing different physicochemical properties from the ordinary water. We have examined the effect of magnetized water on the change of critical micelle concentrations (CMC) of some surfactants. The CMC changes of SDS (sodium dodecyl sulfate) and CTAB (cetyltrimethylammonium bromide) dissolved in the magnetized water have been determined by the conductivity measurement at $25\;{^{\circ}C}$ and that of SDS, CTAB and Pluronic F-68 have also been examined by the surface tension method at $25\;{^{\circ}C}$. The CMC variation of SDS was examined by ITC (Isothermal Titration Calorimeter) at $25\;{^{\circ}C}$. The CMC of SDS, CTAB, and Pluronic F-68 are more decreased in the magnetized water, SDS is about $2.7{\sim}6.5$25 %, CTAB is about $2.3{\sim}3.0$%, and Pluronic F-68 is about 24.2 %, than in the control water.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.712-715
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• 2009

본 연구에서는 고밀도, 고촉진 가스하이드레이트 생성 촉진제 (promoter)의 개발을 위하여 음이온성 멀티체인형 게면활성제를 제조하였다. 또한 각 계면활성제의 알킬그룹의 길이에 따라 같은 조건에서의 계면활성제의 촉진 효과를 비교하였다. $1^{\circ}C$에서 35bar,40bar로 압력을 달리하여 비교 실험하여 메탄 하이드레이트 생성속도를 측정하고, 각 조건에서의 계면활성제의 촉진 효과를 비교하였다. 알킬그룹의 길이가 짧을수록, 압력이 높을수록 촉진 속도가 빠르다. 또한 기존의 상용화된 SDS(Sodium dodecyl sulfate)보다 본 연구에서 제조한 C10의 음이온성 멀티체인형 계면활성제가 SDS 대비하여 소량으로도 충분한 효과를 나타냄을 확인하였다.