• Title/Summary/Keyword: soda pulping

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Chemical and Mechanical Properties of Yellow Poplar Pulp Produced by Formic Acid- Hydrogen Peroxide Pulping (개미산-과산화수소 펄핑에 의하여 생산된 백합나무 펄프의 화학적 및 역학적 특성 분석)

  • Sim, Jaehoon;Kim, Jeong-Ho;Park, Jong-Moon;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.1
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    • pp.6-12
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    • 2013
  • TFormic acid-hydrogen peroxide (or performic acid) pulping process needs milder reaction condition than other chemical pulping process. Two-step formic acid-hydrogen peroxide pulping process can produce the chemical pulp with similar pulp yield and lignin content compared with soda-anthraquinone process. Formic acid-hydrogen peroxide pulp can be produced less xylan content than other alkaline pulps, which favor for dissolving pulp production. Formic acid-hydrogen peroxide pulp showed better response beating than soda-anthraquinone(AQ) pulps with reaching target freeness with less beating. Also, formic acid-hydrogen peroxide pulp had better tensile index at similar freeness level compared with soda-AQ pulps.

Ganoderma lucidum균 전처리를 이용한 볏짚의 상압.소다펄프화

  • 주용찬;강진하
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.4
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    • pp.51-60
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    • 2002
  • This study was carried out to develop the biochemical pulping method to enhance energy saving and decrease the capital cost through the soda pulping under atmospheric pressure (100%). Nonwood substrates, rice straw, were pretreated by white-rot fungi, Ganoderma Iucidum. It has acquired several basic data that can be applied in bio-soda pulping. The results of this study were as follow. Without any nutrients or with glucose, N and glucose+N the weight losses of rice straws inoculated by Canoderma Iucidum were 8.5~29.8%, 9.3~32% 11.8~30.1% and 11.8~24.4% respectively for 5, 10, 15, 20, 25 and 30 days incubation. The more extending incubation periods, the more increasing weight losses. The yield of untreated rice saw was 54.8% after pulping. When any nutrients was not added or glucose, N and glucose+N were added for the pretreatment, the total yields were ranged 50.6~38.5%, 48.6~34.4%, 47.2~38.4% and 49.5~42.6% respectively for 5, 10, 15, 20, 25 and 30 days incubation. The yields were gradually decreased based on extending of incubation. The physical properties of rice straw soda pulps without fungal treatment, the density, breaking length, burst index, tear index and folding endurance were 0.24 g/$\textrm{cm}^3$, 2.32 km, 0.91 kPa $m^2$/g, 56.7 mN.$m^2$/g and 35 times, respectively. After pretreatment without any nutrients or with glucose, N and glucose+N as nutrients the density was 0.27~0.30 g/$\textrm{cm}^3$, the breaking length 3.14~5.25 km, burst index 1.42~2.78 kPa.$\textrm{m}^2$/g, tear index45.8~64.5 mN.$\textrm{m}^2$/g and folding endurance 47~288 times at all incubating periods when pulping was done. The physical properties were increased with the increasing incubation periods. However, when glucose+N was added, the physical properties were shown superior results each incubating duration.

Comparison of the soda-anthraquinone pulping properties between imported Eucalyptus mixture chips and domestic yellow poplar (Liriodendron tulipifera)chips (수입산 혼합 유칼립투스 칩과 국내산 백합 나무 (Liriodendron tulipifera) 칩의 소다-안트라퀴논 (soda-anthraquinone) 펄핑 특성 비교)

  • Sung, Yong-Joo;Lee, Joon-Woo;Kim, Se-Bin;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.3
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    • pp.22-27
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    • 2010
  • Pulping properties of the imported mixed eucalyptus chips and the domestic yellow poplar chips were investigated for comparing two chips as the raw materials for the hardwood chemical pulp. Soda-AQ (anthraquinone) pulping was applied for this study. The pulp from yellow poplar showed higher pulp yield than pulp from mixed eucalyptus, which comes from the lower hot-water soluble extractives and the higher polysaccharides in yellow poplar chips than those of the mixed eucalyptus chips. The yellow poplar pulp had higher average fiber length and fiber width than those of the mixed eucalyptus pulp, which led to the better respond to beating and the higher tear strength than those of the pulp from the mixed eucalyptus chips.

Sugar Extraction by Pretreatment and Soda Pulping From Cattail (Typha latifolia L.) (1) Extraction of Sugar (부들의 전처리를 통한 당의 추출과 소다펄프화에 관한 연구 (1) 당 추출)

  • Lee, Sung-Eun;Kim, Wan-Jung;Son, Mi-Kyung;Seo, Yung-Bum
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.2
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    • pp.88-94
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    • 2010
  • Cattail (Typha L.) was used as a raw material for producing both bio-ethanol and pulp for papermaking at the same time. Pretreatments of cattail stems and leaves with acid ($H_2SO_4$) and alkali (NaOH) in three different addition levels were studied before soda pulping. The acid pretreatment gave reducing sugar of 15.2% of initial weight, but alkali pretreatment close to 1%. Soda pulping of the pretreated cattail gave 3% reduction in pulp yield and less bonding properties in paper; however, refining of the pulp from the pretreated cattail with alkali restored their fiber bondings up to that of the pulp from no-pretreated cattail at equivalent freeness.

New 2-methyl Anthraquinone Synthesis Approach and Application in Soda-anthraquinone (AQ) Pulping

  • Shin Soo-Jeong;Francis Raymond C.;Omori Shigetoshi
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.37 no.5 s.113
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    • pp.35-40
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    • 2005
  • We tried to synthesize the 2-methyl anthraquinone (2-MAQ) with reaction between phthalic anhydride and toluene instead of using 2-methyl phthalic anhydride and benzene. This process didn't generate significant of amount of 1-methyl anthraquinone (l-MAQ) as byproduct. The other advantage of this pathway is using less toxic toluene instead of benzene known as carcinogen. 2-MAQ synthesized this pathway was as effective as reagent grade from commercial available based on soda-anthraquinone(AQ) pulping results.

Elucidating soda and soda-anthraquinone pulping characteristics of Korean bamboo species (국내산 주요 죽종의 소다 및 소다-안트라퀴논 펄핑 특성 비교)

  • Lee, Kyu-Seong;Song, Woo-Yong;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.3
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    • pp.44-50
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    • 2016
  • As a raw material for pulp and paper industry, Moso bamboo, Timber bamboo and Henon bamboo pulps were prepared by soda or soda-anthraquinone(Soda-AQ) pulping process. Soda-AQ pulp yields was higher in Henon bamboo (43.2%) than in Moso bamboo or Timber bamboo (32.7-39.2%), but quite lower than hardwood species. In Kappa number comparison, Henon bamboo pulp showed lower (16.6) with 50 min cooking to $170^{\circ}C$ than that of Moso bamboo (22.8) and Timber bamboo (18.9) with 90 min cooking to $170^{\circ}C$. Fiber length of Timber bamboo soda pulp had higher (1.46 mm) than that of Moso bamboo or Henon bamboo (1.18-1.36 mm). All three bamboo pulps showed longer average fiber length than commercial hardwood pulp. With higher pulp yield and lower Kappa number, Henon bamboo is better raw material for pulp than Moso bamboo and Timber bamboo.

Study of Preparation and Characterization of Microcrystalline cellulose from Miscanthus sinensis (미세결정셀룰로오스의 제조를 위한 억새 바이오매스의 처리 및 특성연구)

  • Sung, Yong-Joo;Lee, Young-Ju;Lee, Joon-Woo;Kim, Se-Bin;Park, Gwan-Soo;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.4
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    • pp.56-63
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    • 2010
  • Microcrystalline cellulose (MCC) was prepared from Miscanthus in this study. Two pulping methods, soda pulping and alkaline sulfite pulping were applied as a pretreatment process. After pulping, two different bleaching processes such as $ClO_2$ treatment followed by $H_2O_2$ treatment and $O_3$ treatment followed by $H_2O_2$ treatment were carried out. Two concentration of $H_2SO_4$, 47% and 57% were applied to the purified Miscanthus cellulose as a acid hydrolysis process to make MCC. The crystallinity index and morphological properties of the produced MCC were evaluated with X-ray diffractometer and scanning electron microscopy. The MCC originated from the soda pulping sample showed the higher crystallinity index than that originated from the alkaline sulfite pulping sample. The two stages of treatmen twith $O_3$ and $H_2O_2$ resulted in the higher purified cellulose products.

Bio-Soda Pulping of Rice Straw with Pleurotus cornucopiae under Atmospheric Pressure

  • Ju, Yong-Chan;Kang, Jin-Ha
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.35 no.5
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    • pp.62-71
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    • 2003
  • This study was carried out to develop the bio-chemical pulping method to enhance the energy saving and decrease the capital cost through the soda pulping under atmospheric pressure ($100^{\circ}C$). Nonwood substrates, rice straw, were pretreated by white-rot fungi, Pleurotus cornucopiae. Several basic pieces of data that can be applied in soda pulping were acquired. The results of this study were as follows. Under the conditions without any nutrients or with glucose, N and glucose + N, the weight losses of rice straws inoculated by Pleurotus cornucopiae were 12.1∼32.6 %, 12.0∼26.3 %, 13.0∼25.4 % and 15.3∼24.7 % for 5, 10, 15, 20, 25 and 30 days incubation periods respectively. The more the fungal incubation was extended, the more the weight losses were gained. The yield of untreated rice straw was 54.8 % after pulping. When any nutrients was not added or glucose, N and glucose + N were added for the pretreatment, the total yields were ranged to 57.3∼42.9 %, 51.0∼43.3 %, 51.7∼43.9 % and 52.1∼46.1 % for 5 different incubation periods respectively. The yields were gradually decreased based on the extending of the incubation periods. The physical properties of the rice straw soda pulp without fungal treatment, the density, breaking length, burst index, tear index and folding endurance were 0.24g/㎤, 2.32 Km, 0.91 kPaㆍ$m^2$/g, 46.7 mNㆍ$m^2$/g and 21 times, respectively. In the case of pretreatment without any nutrients or with glucose, N and glucose + N as nutrients, the density was 0.24g/㎤, the breaking length was 3.30∼6.46 Km, the burst index was 1.36∼3.01 kPaㆍ$m^2$/g, the tear index was 33.0∼57.0 mNㆍ$m^2$/g and the folding endurance was 14∼381 times at most incubating periods, when pulping was done. The physical properties were increased as the incubation duration was extended. Especially, when N and glucose + N were added, the physical properties showed superior results during each incubation period.

Evaluation of Defiberation by Organosolv Ethanolamine Pulping for Integral Utilization of Oil Palm EFB (오일팜 바이오매스 EFB 고도 활용을 위한 Organosolv 에탄올아민 펄핑에 따른 섬유화 특성평가)

  • Kim, Chul-Hwan;Kim, Dong-Seop;Sung, Yong Joo;Hong, Hae-Eun;Kim, Se-Bin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.1
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    • pp.67-74
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    • 2013
  • Organosolv ethanolamine pulping for oil palm empty fruit bunches(EFB) were evaluated in this study. The screen yield by the ethanolamine pulping were higher than that by the soda pulping at the same operation conditions. The higher concentration of ethanolamine solvent resulted in the higher yield and the lower contents of residual lignin. The EFB pulp fibers were the narrower in fiber width but the higher in coarseness than those of the hardwood pulp fiber, while the fiber length of the EFB pulp fiber were similar to that of the hardwood fiber. The intrinsic zero span tensile testing showed the EFB pulp fiber by the 80% ethanolamine pulping were the stronger than the fiber by the soda pulping. The results of this study supported that the ethanolamine pulping could be used as an alternative pulping method for the EFB.

Soda Pulp Properties from Corn Stalk as Raw Material (옥수수 줄기를 원료로 제조한 소다 펄프의 특성)

  • Song, Woo-Yong;Lee, Kyu-seong;Lee, Jai-Sung;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.6
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    • pp.73-80
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    • 2015
  • Corn stalk is the lignocellulosic biomass, which remain as leftover after harvesting. To use the corn stalk as raw material for paper industry, soda pulping was applied. In chemical compositional analysis, extractive contents of corn stalk (45.1%) was higher than hardwood. With corn stalk pith, soda pulp yield was 25.3% at 10.6 Kappa number, but 39.5% yield with 14.8 Kappa number for corn stalk rind. Higher extractives content in pith is one of the reason for lower pulp yield than rind. Pith pulp fibers had higher fines content than rind pulp. Pith parenchyma cell was removed as fines during pulping or washing process, which caused the lower yield. To use the corn stalks as a raw material for paper making, de-pith process is essential for higher pulp yield and longer pulp length.