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A Study on Enzymatic Degummings of Raw Silk and Silk Fabric (견의 효소 정련에 관한 연구)

  • Lee, Yong-U;Song, Gi-Won;Jeong, In-Mo
    • Journal of Sericultural and Entomological Science
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    • v.28 no.1
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    • pp.66-71
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    • 1986
  • The studies were carried out to screen the optimum conditions for enzymatic degumming of raw silk yarn and silk fabric by use of Alkalase, a protease produced by Bacteria, comparing with Papain and Trypsin representing natural proteolytic enzymes. 1. The optimum temperature and acidity of degumming solution were 70$^{\circ}C$, pH 5-6 for Papain degumming, 40$^{\circ}C$, pH 8 for Trypsin and 50-60$^{\circ}C$ pH 8-9 for Alkalase. 2. By increasing the Alkalase concentration in the range of 0.6 to 1.0 gram per liter, the time for enzymatic degumming of silk yarn could be reduced by 40 minutes. 3. In degumming of silk yarn by Alkalase, the pretreatment of 95$^{\circ}C$, 10 minutes at 0.1% sodium bicarbonate solution or posttreatent of 80$^{\circ}C$, 20 minutes at 2% (o.w.f.) sodium silicate solution improved the efficiency of enzymatic degumming, as compared to that of nontreatment. 4. The breaking strength, elongation and Lousiness results of enzymatically degummed silk yarn were apt to be improved more than those of soap-degummed one. 5. When the pretreatment of alkaline solution was done with over 20% of degumming ratio, the enzymatic degumming efficiency of both Havutae and Crepe de chine could be reached to the same level with those of soap-soda degummed. 6. As the pretreated silk fabric with 20% of degumming ratio was under action of three proteases, respectively, the deumming efficiency of Havutae and Crepe de chine were completed by Alkalase more than by Papain or Trpysin. 7. The stiffness of enzymatically degummed Crepe de chine was not only reduced by 17% more than that of soap-soda degummed one but also the Drape coefficient was decreased in enzymatically degummed fabrics, which was closely related with the soft touch of degummed fabrics.

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Georeferencing of GPR image data using HD map construction method (정밀 도로 지도 구축 방법을 이용한 GPR 영상 데이터 지오레퍼런싱)

  • Shin, Jinsoo;Won, Jonghyun;Lee, Seeyoung
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.39 no.6
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    • pp.507-513
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    • 2021
  • GPR (Ground Penetrating RADAR) is a sensor that inspects the pavement state of roads, sinkholes, and underground pipes. It is widely used in road management. MMS (Mobile Mapping System) creates a detailed and accurate road map of the road surface and its surroundings. If both types of data are built in the same area, it is efficient to construct both ground and underground spatial information at the same time. In addition, since it is possible to grasp the road and important facilities around the road, the location of underground pipelines, etc. without special technology, an intuitive understanding of the site is also possible, which is a useful tool in managing the road or facilities. However, overseas equipment to which this latest technology is applied is expensive and does not fit the domestic situation. LiDAR (Light Detection And Raging) and GNSS/INS (Global Navigation Satellite System / Inertial Navigation System) were synchronized in order to replace overseas developed equipment and to secure original technology to develop domestic equipment in the future, and GPR data was also synchronized to the same GNSS/INS. We developed software that performs georeferencing using the location and attitude information from GNSS/INS at the time of acquiring synchronized GPR data. The experiments were conducted on the road site by dividing the open sky and the non-open sky. The road and surrounding facilities on the ground could be easily checked through the 3D point cloud data acquired through LiDAR. Georeferenced GPR data could also be viewed with a 3D viewer along with point cloud data, and the location of underground facilities could be easily and quickly confirmed through GPR data.

Composition Classification of Korea Ancient Glasses by Using Raman Spectroscopy (라만분광분석법을 이용한 한국 고대 유리의 조성 분류)

  • Sim, Woo Seok;Kim, Eun A;Lim, Soo Yeong;Kim, Hyung Min;Kim, Gyu Ho
    • Journal of Conservation Science
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    • v.38 no.2
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    • pp.117-123
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    • 2022
  • In this study, investigated the possibility of quantitatively and qualitatively analyzing Korean ancient glasses via Raman Spectroscopy. We subjected four categories of Korean traditional glasses, namely, lead-BaO, lead, potash, and soda glasses (3, 3, 10, and 10 pieces, respectively), to this analytical technique. The results showed significant differences between the stretching and bending Raman vibration regions corresponding to these different Korean ancient glass types. Specifically, the stretching vibration regions corresponding to lead-BaO and lead glasses showed peaks at 1040 and 1000 cm-1, respectively; the stretching vibration region of normal glass appears at 1100 cm-1. The bending vibration regions corresponding to potash and soda glass showed Raman peaks at 490 and 560 cm-1, respectively. Furthermore, the Raman spectra of the lead and lead-BaO glasses showed red shifts, which depended on the amount of PbO present. Thus, our findings highlighted the possibility of quantitatively determining the amount of PbO, a major component of lead glasses, via Raman Spectroscopy.

Diet Related Factors Influencing BMI Changes for Korean-Americans Residing in Eastern Area of America

  • Son, Sook-Mee;Ardy Gillespie;Lee, Hong-Sup
    • Journal of Community Nutrition
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    • v.4 no.2
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    • pp.90-98
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    • 2002
  • This study was performed to examine the dietary and BMI change of Koreans after moving to America and to identify the factors influencing changes of BMI. The subjects were 192 Korean-Americans (men : 86, women : 106) residing in the eastern area of the U.S.A. 1) subjects reported significantly increased consumption frequency in American foods like, low fat milk(p<0.001), cold cereals (p<0.001), whole wheat bread(p<0.001), hamburger(only in males p<0.01) and pizza(only in males p<0.01). Whereas significantly decreased consumption frequency in fish (p<0.05), cooked vegetables(p<0.001), kimchi(p< 0.001) and cooked rice (p<0.001) were reported. 2) It was reported that weight, accordingly BMI were significantly increased (p<0.01). The smoking habit score was significantly decreased for males (p<0.05). 3) Multiple linear regression analysis for BMI change showed that education years in Korea was the most prominent negative factor(p<0.001) in predicting BMI change in America. Elevated frequencies of alcohol, chicken and soft drink in America were also associated with greater increase of BMI. When the length of residence (increase of age) was included in regression model, the increase of age was the most significant factor (p<0.001). Changes of chicken and soda scores were other significant factors.

Codoped ZnO films by a co-spray deposition technique for photovoltaic applications

  • Zhou, Bin;Han, Xiaofei;Tao, Meng
    • Advances in Energy Research
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    • v.2 no.2
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    • pp.97-104
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    • 2014
  • A co-spray deposition technique has been developed to bypass a fundamental limitation in the conventional spray deposition technique, i.e., the deposition of metal oxides from incompatible precursors in the starting solution. With this technique, ZnO films codoped with F and Al have been successfully synthesized, in which F is incompatible with Al. Two starting solutions were prepared and co-sprayed through two separate spray heads. One solution contained only the F precursor, $NH_4F$. The second solution contained the Zn and Al precursors, $Zn(O_2CCH_3)_2$ and $AlCl_3$. The deposition was carried out at $500^{\circ}C$ on soda-lime glass in air. A minimum sheet resistance, $55.4{\Omega}/{\square}$, was obtained for Al and F codoped ZnO films after vacuum annealing at $400^{\circ}C$, which was lower than singly-doped ZnO with either Al or F. The transmittance for the codoped ZnO samples was above 90% in the visible range. This co-spray deposition technique provides a simple and cost-effective way to synthesize metal oxides from incompatible precursors with improved properties for photovoltaic applications.

Quality Characteristics of Yellow Layer Cake Added with Sourdough Starter Powder (사워종 분말을 첨가한 옐로우 레이어 케이크의 품질 특성)

  • An, Hye-Lyung;An, Hee-Jung;Lee, Kwang-Suck
    • Journal of the East Asian Society of Dietary Life
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    • v.23 no.3
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    • pp.349-356
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    • 2013
  • When making a yellow layer cake, an existing chemical leavening agent, sourdough starter powder, was used instead of using baking powder in order to produce batter where the acid agent in the baking powder was reduced using baking soda. The control group had the lowest share of the batter and therefore had the highest specific volume. In a test group, the share of SP4 was low and therefore, the specific volume was high. In terms of physiochemical characteristics, the volume, symmetry and uniform index was high in SP4 in the test group. The control group had the highest moisture content followed by SP4. In terms of texture, the control group had the lowest hardness and highest springiness. In the test group, SP4 had the lowest hardness and highest springiness. The result of the sensory evaluation indicates that SP4 had the best taste and flavor. In terms of overall preference, SP4 showed significantly higher preference overall. However, it did not show any significant difference compared to the control group.

Effect on Bleaching Efficiency by Chelating Treatment in Sugarcane Bagasse DEDP Bleaching Process (사탕수수 부산물 펄프의 DEDP 표백 시 킬레이트 전처리가 표백 효율에 미치는 영향)

  • Lee, Jai-Sung;Song, Woo-Yong;Park, Jong-Moon;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.4
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    • pp.81-87
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    • 2015
  • Soda-AQ pulp made from sugarcane bagasse (SCB) were bleached in element chlorine free (ECF) sequence. To reduce chlorine dioxide use, final peroxide bleaching was introduced. Prior to peroxide bleaching, different chelating chemicals were applied for comparative analysis in ISO brightness and viscosity. When using equal total chlorine dioxide usage (4.5%), bleached SCB pulp using chelate and hydrogen peroxide (DEDQP) was reached 86.8% (DTPA), 86.4% (EDTA) ISO brightness, whereas bleached pulp using only hydrogen peroxide (DEDP) reached at 81.2% ISO brightness. Viscosity of DEDQP bleached pulp was 25.6 cPs (DTPA), 25.2 cPs (EDTA), And DEDP bleached pulp was shown 18.0 cPs viscosity. Decreasing of transition metal by chelate process led to improvements in final brightness along with higher viscosity. Due to EDTA is 5-7 times cheaper than DTPA, EDTA is recommended as chelating chemical prior to peroxide bleaching.

Effects of Se flux on CIGS thin film solar cell (Se 증기압이 CIGS 박막 태양전지에 미치는 영향에 관한 연구)

  • Kim, Daesung;Kim, Chaewoong;Kim, Taesung
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.71.2-71.2
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    • 2010
  • CIS(CuInSe2)계 화합물 태양전지는 높은 광흡수계수와 열적 안정성으로 고효율의 태양전지 제조가 가능하여 화합물 태양전지용 광흡수층으로서 매우 이상적이다. 또한 In 일부를 Ga으로 치환하여 밴드갭을 조절할 수 있는 장점이 있다. 미국 NREL에서는 Co-evaporation 방법을 이용해 20%의 에너지 변환 효율을 달성하였다고 보고된바가 있다. 본 연구에서는 미국의 NREL과 같은 3 stage 방식을 이용하여 광흡수층을 제조하고자 한다. 본 실험에서는 Se 증기압을 각각 $200^{\circ}C$, $230^{\circ}C$, $240^{\circ}C$, $245^{\circ}C$로 달리 하며 실험을 실시하였다. 이때 1st stage의 시간은 15분으로 고정하였으며 기판온도는 약 $250^{\circ}C$로 고정 하였다. 2nd stage는 실시간 온도 감지 장치를 이용하여 Cu와 In+Ga의 조성비가 1:1이 되는 시간을 기준으로 Cu의 조성을 30%더 높게 조절하였으며 기판 온도는 약 $520^{\circ}C$로 고정 후 실험을 실시하였다. 3rd stage의 경우 Cu poor 조성으로 조절하기 위해 모든 조건을 10분으로 고정 후 실험을 실시하였다. 각각의 Se 증기압에 따른 물리적, 전기적 특성을 알아보기 위해 FE-SEM, EDS, XRD 분석을 실시하였다. 본 연구에서 기판은 Na이 첨가되어있는 soda-lime glass를 사용 하였으며 후면 전극으로 약60nm 두께의 Mo를 DC Sputtering 방법을 이용해 증착 하였다.

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Selenization methods for CIGS solar cell prepared by Cu-In-Ga metal precursors (CIGS 태양전지 제조를 위한 Cu-In-Ga 금속 전구체의 셀렌화 방법 연구)

  • Byun, Tae-Joon;Park, Nae-Man;Chung, Yong-Duck;Cho, Dae-Hyung;Lee, Kyu-Seok;Kim, Jeha;Han, Jeon-Geon
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.101.1-101.1
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    • 2010
  • $Cu(InGa)Se_2$ (CIGS) 태양전지는 박막형 태양전지 중 가장 높은 에너지 변환 효율이 보고 되고 있다. CIGS 태양전지를 제조하는 방법은 3 단계 동시 증착법, 금속 전구체의 셀렌화 공정법, 전기 증착법 등이 있다. 이 중 금속 전구체의 셀렌화 공정법은 다른 제조 방법에 비해 대면적 생산에 유리하고, 비교적 공정 과정이 간단하다는 장점이 있다. 하지만 금속 전구체의 미세구조 및 제조 방법, 셀렌화 공정의 최적화에 대한 연구가 부족하다. 본 실험에서는 후면전극으로 사용되는 Mo 층이 증착된 소다회 유리(soda-lime glass)를 기판으로 사용하였다. Cu-In(4:6), Cu-Ga(6:4) 타겟을 DC 스퍼터링 시스템을 이용하여 금속 전구체를 증착하였다. 이 후 미국 Delawere 대학교의 IEC 연구소와 한국전자통신연구원 (ETRI)에서 금속 전구체의 셀렌화 공정을 진행하였다. 셀렌화 공정 전후의 금속 전구체의 결정 크기와 미세구조의 변화를 관찰하기 위하여 주사전자현미경 (SEM)과 X선 회절 분석기 (XRD)를 사용하였다. 센렌화 공정이 진행된 금속 전구체 위에 버퍼층으로 사용되는 CdS와 전면전극으로 사영되는 ZnO, ITO 층을 합성한 후 에너지 변환 효율을 측정하였다. 최고 효율은 9.7%로 관찰되었다.

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Effects of Na on CIGS thin film solar cell (Na이 CIGS 박막 태양전지에 미치는 영향에 관한 연구)

  • Kim, Chaewoong;Kim, Daesung;Kim, Taesung;Kim, Jinhyok
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.62.1-62.1
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    • 2010
  • CIS(CuInSe2)계 화합물 태양전지는 높은 광흡수계수와 열적 안정성 및 조성 조절을 통한 밴드갭 조절이 용이해 고효율 박막 태양전지로 각광 받고 있다. 또한 CIGS 태양전지는 기존의 유리기판 대신 유연한 기판을 사용해 flexible 태양전지 제조가 가능하다. 이러한 유연기판은 보통 stainless steel과 같은 금속 기판이 많이 사용되는데 기존의 soda-lime glass 기판과는 달리 금속기판에는 Na이 첨가되어 있지 않아 별도의 Na첨가를 필요로 한다. Na은 CIGS 흡수층의 조성조절을 용이하게 하여 태양전지의 변환 효율을 향상시키는 역할을 한다. 본 연구에서 기판은 Na이 첨가되어있지 않은 corning glass를 사용 하였으며 NaF를 이용해 Mo가 증착된 기판에 NaF의 두께를 달리하며 증착해 CIGS 흡수층의 grain 사이즈를 비교 하였으며 그 후 태양전지 소자를 제조해 광전특성을 분석하였다. 후면 전극으로 약60nm 두께의 Mo를 DC Sputtering 방법을 이용해 증착 하였다. buffer층으로는 약 50nm의 CdS층을 CBD방법을 이용하여 제조 하였으며 TCO 층으로 약 50nm의 i-ZnO와 약 450nm의 Al-ZnO를 RF Sputtering방법으로 증착 하였다. 마지막으로 앞면 전극으로 약 $1{\mu}m$의 Al을 Thermal Evaporation방법으로 증착하였다. 태양전지 소자의 면적은 $0.49cm^2$로 효율을 비교 분석하였다.

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