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http://dx.doi.org/10.12654/JCS.2022.38.2.05

Composition Classification of Korea Ancient Glasses by Using Raman Spectroscopy  

Sim, Woo Seok (Department of Chemistry, Kookmin University)
Kim, Eun A (Department of Cultural Heritage Conservation Science, Kongju National University)
Lim, Soo Yeong (Department of Chemistry, Kookmin University)
Kim, Hyung Min (Department of Chemistry, Kookmin University)
Kim, Gyu Ho (Department of Cultural Heritage Conservation Science, Kongju National University)
Publication Information
Journal of Conservation Science / v.38, no.2, 2022 , pp. 117-123 More about this Journal
Abstract
In this study, investigated the possibility of quantitatively and qualitatively analyzing Korean ancient glasses via Raman Spectroscopy. We subjected four categories of Korean traditional glasses, namely, lead-BaO, lead, potash, and soda glasses (3, 3, 10, and 10 pieces, respectively), to this analytical technique. The results showed significant differences between the stretching and bending Raman vibration regions corresponding to these different Korean ancient glass types. Specifically, the stretching vibration regions corresponding to lead-BaO and lead glasses showed peaks at 1040 and 1000 cm-1, respectively; the stretching vibration region of normal glass appears at 1100 cm-1. The bending vibration regions corresponding to potash and soda glass showed Raman peaks at 490 and 560 cm-1, respectively. Furthermore, the Raman spectra of the lead and lead-BaO glasses showed red shifts, which depended on the amount of PbO present. Thus, our findings highlighted the possibility of quantitatively determining the amount of PbO, a major component of lead glasses, via Raman Spectroscopy.
Keywords
Glass beads; Flux; Lead glass; Raman Spectroscopy; Red shift; PbO content;
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Times Cited By KSCI : 1  (Citation Analysis)
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