• Journal of Soil and Groundwater Environment
• /
• v.28 no.1
• /
• pp.15-24
• /
• 2023

A persulfate(PS)/sulfidated microscale zero-valent iron(S-mZVI) system was tested for treating a soil contaminated with phenol. Sulfidation of bare mZVI was conducted using a mechanochemical process utilizing a ball mill in order to improve persulfate activation capacity and stability of unmodified mZVI. The synthesized S-mZVI performed markedly better than the bare mZVI in activating PS. The optimum molar ratio of sulfur to mZVI was around 0.12. In the soil slurry experiments, a very rapid and complete removal of phenol was observed at the optimum molar ratios of PS to S-mZVI of 2:1 and PS to phenol of 16:1. The phenol removal efficiencies decreased as the water content of the slurries decreased. This was believed to be due to increased soil oxidant demand as the amount of soil was increased as relative to the water content. To evaluate the field applicability of the process, slurry experiments adopting high soil contents were carried out that simulated in-situ soil mixing conditions. These experiments resulted in substantially compromised degradation efficiencies of 54.3% and 43.8% within 4 hours. The current study generally shows that the PS/S-mZVI process has a potential to be developed into a remediation technology for soils contaminated with organics.

• Tribology and Lubricants
• /
• v.39 no.2
• /
• pp.72-75
• /
• 2023

Silicon carbide (SiC) is used as a substrate material for power semiconductors; however, SiC chemical mechanical polishing (CMP) requires considerable time owing to its chemical stability and high hardness. Therefore, researchers are attempting to increase the material removal rate (MRR) of SiC CMP using various methods. Mixed-abrasive CMP (MAS CMP) is one method of increasing the material removal efficiency of CMP by mixing two or more particles. The aim of this research is to study the mathematical modeling of the MRR of MAS CMP of SiC with SiO₂ and TiO₂ particles. With a total particle concentration of 32 wt, using 80-nm SiO₂ particles and 25-nm TiO₂ particles maximizes the MRR at 8 wt of the TiO₂ particle concentration. In the case of 5 nm TiO₂ particles, the MRR tends to increase with an increase in TiO₂ concentration. In the case of particle size 10-25 nm TiO₂, as the particle concentration increases, the MRR increases to a certain level and then decreases again. TiO₂ particles of 25 nm or more continuously decreased MRR as the particle concentration increased. In the model proposed in this study, the MRR of MAS CMP of SiC increases linearly with changes in pressure and relative speed, which shows the same result as the Preston's equation. These results can contribute to the future design of MAS; however, the model needs to be verified and improved in future experiments.

• Journal of the Korean Wood Science and Technology
• /
• v.36 no.1
• /
• pp.79-87
• /
• 2008

Many researchers have studied on rooftop greening that can be installed in abandoned spaces on a building roof. The most important issue in rooftop greening is the soil weight problem. The light greening materials are needed to solve this problem. Therefore, many alternative materials against the soil were investigated for rooftop greening. In this study, the waste wood chips and the waste paper slurry were evaluated as the lightweight vegetation foundation for rooftop greening. It also has a meaning for recycling of waste materials. The mixture ratio of waste wood chips to waste paper slurry for the board (the foundation of greening) was 60 to 40. The wet strength resin and the sizing agent were additionally added with different amount. After the forming of the board, physical and chemical properties were tested with the variation of wet strength resin and sizing agent. As the result of the test, the board with 15% of wet strength resin in the wet condition showed the highest strength. Futhermore, the moisture evaporation loss from the board surface with sizing agent was much lower than that from the board without sizing agent. Therefore, it was clear that the sizing agent was effective for water retention. The change of thickness in the wet condition was less than 1 mm, and it showed that the board is the predominant material on the dimensional stability. The average pH value of the board was ranged from 7.6 to 8.25.

• Journal of the Korean GEO-environmental Society
• /
• v.17 no.12
• /
• pp.45-54
• /
• 2016

In this study, the construction method of new underground continuos impervious wall that the bentonite slurry keeps the stability of excavated trench and the mixture of cement and bentonite plays a role as a constituent of impervious wall in the trench. The merit of homogeneity of the method so called as a cement-bentonite slurry wall enables to accurately make an estimation of hydraulic conductivity of the walls compared with that by other general grouting methods and to verify their waterproof efficiency without difficulty at the design stage. The use of cement-bentonite slurry walls for the containment of groundwater flow has also proven a cost-effective impervious wall technology by employing the simple combination of construction equipments and easy and fast construction procedures. The engineering characteristics of cement-bentonite impervious wall obtained by carrying out the laboratory experiments under various conditions. This study reveals the effect of variation of constituent materials and their mixing methods (Water-Cement-Bentonite) on the engineering characteristics of a composition. Also, this study makes some recommendations on the optimum mixing ratio and mixing sequence for the best quality at the site. That is the most important factors to estimate the construction cost and design of the technique. The comparison is lastly made to evaluate the effect of ordinary Portland and blast furnace slag cement as a bonding material on the behavior of impervious walls.

• Journal of the Korean Geotechnical Society
• /
• v.24 no.11
• /
• pp.121-131
• /
• 2008

In constructing a slurry trench cutoff wall, bentonite-water slurry is used to secure the stability of sidewalls during excavation before the wall is completed by backfilling. Unexpectedly, a thin but relatively impermeable layer called filter cake can be formed on the excavation surface, which significantly influences the result of slug test analysis in the cutoff wall if not considered. This study is to examine the effect of filter cake on evaluating hydraulic conductivity of the vertical cutoff wall through slug test analysis with the aid of the verified numerical program Slug_3D. The no-flux boundary conditions were adopted in Slug_3D to simulate the filter cake on the interface between the wall and the natural soil. A new set of type curves were built for applying the type curve method. New modification factors were obtained for using the modified line-fitting method. With consideration of filter cake, the type curve method and the modified line-fitting method were adopted to reanalyze the case study taken from EMCON (1995). The previous results achieved by Choi and Daniel (2006) without consideration of filter cake were compared with the present results obtained in this paper. The comparison emphasizes the necessity of considering filter cake when analyzing slug test results in vertical cutoff walls.

• Journal of the Korean Ceramic Society
• /
• v.37 no.7
• /
• pp.705-712
• /
• 2000

In this study, the dispersion stability of CeO2 based complex oxide was studied, and density, porosity, and microstructure of green body were investigated using colloid surface chemistry to manufacture the Gd2O3 doped CeO2 solid electrolyte in an aqueous system. To prepare the stable slurry for slip casting, the dispersion stability was examined as a function of pH using ESA(electrokinetic sonic anplitude) analysis. The dynamic mobility of particles was enhanced with anionic and cationic dispersant were added the amount of 0.5wt% respectively, but pH value in slurries didn't move to below 6.0 because of the influence of dopants. This phenomenon also appeared in the CeO2-Y2O3 and CeO2-Sm2O3 systems, so it could be inferred that rare earth dopants such as Gd2O3, Sm2O3 and Y2O3 not only have the similar motion with changing pH in an aqueous system but also can be dissolved in the range of pH 6.0∼6.5. In CeO2-Gd2O3 system, when the anionic dispersant was added the amount of 0.5wt% and pH value in slurries was fixed at 9.5, the green body density was 4.07g/㎤, and the relative density of sintered body was 95.2%. It could be inferred from XRD analysis that Gd3+ substituted into Ce4+ site because there was no free Gd2O3 peak.

• Ocean Systems Engineering
• /
• v.4 no.4
• /
• pp.309-325
• /
• 2014

Geotextile tubes are basically a huge sack filled with sand or dredged soil. Geotextile tubes are made of permeable woven or non-woven synthetic fibers (i.e., polyester or PET and polypropylene or PP). The geotextile tubes' performances in strength, dewatering, retaining solid particles and stacked stability have been studied extensively in the past. However, only little research has been done in the observation of the deformation behavior of geotextile tubes. In this paper, a large-scale apparatus for geotextile tube experiment is introduced. The apparatus is equipped with a slurry mixing station, pumping and delivery station, an observation station and a data station. For this study the large-scale apparatus was utilized in the studies regarding the stresses on the geotextile and the deformation behavior of the geotextile tube. Model tests were conducted using a custom-made woven geotextile tubes. Load cells placed at the inner belly of the geotextile tube to monitor the total soil pressure. Strain gauges were also placed on the outer skin of the tube to measure the geotextile strain. The pressure and strain sensors are attached to a data logger that sends the collected data to a desktop computer. The experiment results showed that the maximum geotextile strain occurs at the sides of the tube and the soil pressure distribution varies at each geotextile tube section.

• Journal of Animal Environmental Science
• /
• v.4 no.2
• /
• pp.149-160
• /
• 1998

Hog manure slurry amended with sawdust was composted in pilot-scale reactor vessels using continuous aeration nuder different C/N ratios and pH conditions during composting high rate (decomposition) process. For each material two replicated piles were built and monitored over a period of three weeks. The compost piles had an initial volume of 0.18 ㎥. In this study we evaluated the temperature in compost O2 and CO2 evolution, aeration rate, NH3 concentration etc. and investigated the stability of compost during composting high rate process. According to measured results, while the maximum NH3 concentration during composting high rate process. According to measured results, while the maximum NH3 concentration during composting high rate was in the range of 213 to 412 ppm on 5th day which was near the optimum C/N(22∼24) and pH(7.5∼7.9). And then, the NH3 concentration reduced to between 22∼26 ppm by 13th day. The maximum NH3 concentration for the lower C/N(18∼19) and pH value of 6 reached 574∼1,063 ppm by the 16th through 11th days and the NH3 concentration during continuous aerated composting high rate process, it was more important to manage NH3 gas so that compost odor is reduced.

• Proceedings of the Korean Geotechical Society Conference
• /
• 2008.10a
• /
• pp.498-507
• /
• 2008

The mixture of bentonite powder and water is generally used to maintain the stability of excavation surface during the construction of vertical cutoff walls. The filter cake on the sidewall surface is the result of filtration of slurry into the adjacent soil formation. The filter cake is believed to have a very low hydraulic conductivity compared to that of the cutoff wall. This paper evaluates hydraulic conductivities of bentonite filter cakes set up with three types of bentonites under various pressure levels. A modified fluid loss test was employed in this experiment. Theory of filtration process was reviewed to explain the procedure in the present experiment. Hydraulic conductivity of the filter cakes with consideration of the filter medium resistance was evaluated. The results of the experiment with two calculation methods and discussion are presented to show the efficiency of the modified fluid loss test.

• Proceedings of the Korean Geotechical Society Conference
• /
• 2008.10a
• /
• pp.1502-1511
• /
• 2008

The mixture of bentonite powder and water is generally used to maintain the stability of excavation surface during the construction of vertical cutoff walls. The filter cake on the sidewall surface is the result of filtration of slurry into the adjacent soil formation. The filter cake is believed to have a very low hydraulic conductivity compared to that of the cutoff wall. This paper evaluates hydraulic conductivities of bentonite filter cakes set up with three types of bentonites under various pressure levels. A modified fluid loss test was employed in this experiment. Theory of filtration process was reviewed to explain the procedure in the present experiment. Hydraulic conductivity of the filter cakes with consideration of the filter medium resistance was evaluated. The results of the experiment with two calculation methods and discussion are presented to show the efficiency of the modified fluid loss test.