• Title/Summary/Keyword: sludge ash

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Strengths and Permeability Properties of Porous Polymer Concrete for Pavement with Different Fillers (충전재 종류에 따른 포장용 포러스 폴리머 콘크리트의 강도 및 투수 특성)

  • Kim, Young-Ik;Sung, Chan-Yong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.49 no.4
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    • pp.51-59
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    • 2007
  • Recently, concrete has been made porous and used for sound absorption, water permeation, vegetation and water purification according to void characteristics. Many studies are carried out on the utilization of sewage sludge, fly ash and waste concrete to reduce the environmental load. This study was performed to evaluate the void, strength, relationship between void and strength, permeability and chemical resistance properties of porous polymer concrete for pavement with different fillers. An unsaturated polyester resin was used as a binder, crushed stone and natural sand were used as an aggregate and bottom ash, fly ash and blast furnace slag were used as fillers. The mix proportions were determined to satisfy the requirement for the permeability coefficient, $1{\times}10^{-2}$ cm/s for general permeable cement concrete pavement in Korea. The void ratios of porous polymer concrete with fillers were in the range of $18{\sim}23%$. The compressive strength and flexural load of porous polymer concrete with fillers were in the range of $19{\sim}22$ MPa and $18{\sim}24$ KN, respectively. The permeability coefficients of porous polymer concrete with fillers were in the range of $5.5{\times}10^{-1}{\sim}9.7{\times}10^{-2}$ cm/s. At the sulfuric acid resistance, the weight reduction ratios of porous polymer concrete immersed during 8-week in 5% $H_{2}SO_{4}$ were in the range of $1.08{\sim}3.56%$.

Synthesis of Cement Raw Materials by Melting of Industrial Wastes (폐기물의 용융처리에 의한 시멘트원료의 합성)

  • Hwang, Yeon;Sohn, Yong-Un;Chung, Hun-Saeng;Lee, Hong-Ki;Park, Hyun-Suh
    • Resources Recycling
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    • v.5 no.1
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    • pp.3-8
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    • 1996
  • CZS(2Ca0 , SiO\ulcorner) phase of cement clinkcr was obtaincd by melting mixcd four indnstrial wasles of limestone sludge, waste Foundry sand, coal lly ash fiorn power plants and chernicas glasses. The effect ot mixing ratio of four rvastc mater~als ou the composnlg phascs in melled slag was investigated. Thc mixed wastes were meltcd to slag by heat under a constant basicity at 1370C. The shg consisted of p -CIS and C,AS(2CaO - A I P , . SiO,). The ratio of two phases was varied with mixing ~atioo f the waste materials. In order Lo increasc the amount ot j -C2S phase, the coal fly ash content should be reduced, while amount of the chemical glass be increased. The coal fly ash contcnt was the most imporlant factor in controlling phases of thc melted-slag.

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Valorization of bottom ash with geopolymer synthesis: Optimization of pastes and mortar

  • Froener, Muriel S.;Longhi, Marlon A.;de Souza, Fabiana;Rodriguez, Erich D.;Kirchheim, Ana Paula
    • Advances in concrete construction
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    • v.14 no.1
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    • pp.1-13
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    • 2022
  • Due to the physical-chemical characteristics of some bottom ash (BA), there are technical, economic and environmental limitations to find a destination that will add value to it. In Brazil, this residue is eventually used for filling coal extraction pits or remains in sedimentation ponds, creating a susceptible panorama to environmental issues. The geopolymers binders are one of the alternatives to the proper use high amounts of these materials. In this work, geopolymeric binder pastes were produced with BA mixed to activators with different alkali contents (expressed as %Na2O), as well as the incorporation of soluble silicates (Ms content). The production of binary geopolymeric pastes based on the use of two industrial wastes: fluid catalytic cracking (FCC) and aluminum anodizing sludge (AAS), was also assessed. The content in mass of BA/FCC and BA/AAS ranged from 100/0, 90/10; 80/20 and 70/30. Systems with soluble silicates as activator in a molar ratio SiO2/Na2O of 1.0 (Ms = 1.0) and Na2O content of 15%, showed the best results of mechanical strength (42 MPa at day 28th). The improvement is up to 5X when compared to NaOH based systems. For systems with partial replacement of BA of 10% of AAS and 20% of FCC (80/20), the presence of soluble silicates was also effective to increase compressive strength.

Synthesizing Behavior of Calcium Chloroaluminate with using MSWI Fly Ash in the Different Sintering Conditions (생활폐기물(生活廢棄物) 소각(燒却) 비산(飛散)재의 소성(燒成) 조건(條件)에 따른 Calcium Chloroaluminate 합성(合成) 거동(擧動)에 관한 연구(硏究))

  • Yoo, Kwang-Suk;Lee, Seong-Ho;Hwang, Sun-Ho;Ahn, Ji-Whan
    • Resources Recycling
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    • v.19 no.5
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    • pp.68-74
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    • 2010
  • The aim of this study is to investigate the behaviors of synthesis of Calcium Chloroaluminte($11CaO{\cdot}7Al_2O_3{\cdot}CaCl_2$) under the melting temperature of municipal solid waste incineration fly ash(MSWI fly ash); $900^{\circ}C-1300^{\circ}C$ of sintering temperature. A sludge generated from a water purification plant (SW) was also used to fill up $Al_2O_3$ source, which might be deficient in MSWI fly ash. MF and SW were mixed at mixing ratio of 10 to 7, which is the mole ratio of CaO to $Al_2O_3$ of calcium Chloroaluminte. Mixed samples were sintered in the opened sintering reactor and the closed sintering reactor, respectively. The results showed that calcium chloroaluminte was formed at $1,000^{\circ}C$ in both reactors, but the temperature of decomposition of calcium chloroaluminte depended upon sintering reactor type; an opened sintering reactor and a closed sintering reactor, owing to the vaporization velocity of Cl.

Fundamental Properties of Controlled Low Strength Materials Mixed Blast Furnace Slag and Sewage Sludge (고로슬래그미분말 및 하수슬러지를 혼입한 시멘트계 저강도 재료의 기초적 물성)

  • Kim, Dong-Hun;Park, Shin;Lim, Nam-Gi
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.11a
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    • pp.53-54
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    • 2015
  • As the result of uniaxial compression strength test on the CLMS mixing BFS and SS with BFS 4000, it required to determine the desired strength through increasing unit quantity of cement in mixing process because of dramatic strength deterioration of strength according to increasing replacing rate. In this study's result, regardless of differences in fine aggregates used, in order to get uniaxial compression strength in the scope exceeding criteria of minimum strength for applying to the field, the most reasonable combination was to mix replacing BFS with fineness of 6000 in 30%. For the CLMS mixing BFS and SS, in order to improve flow ability by securing quantity of minimum unit and to repress bleeding rate with securing uniaxial compress strength considering the field applicability, regardless of differences in fine aggregates used, to mix BFS over 6000 in 30% was most effective.

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Studies on the High Strength Cement Hardened Body Blended by Industrial By-Products (산업 폐부산물을 혼합재로한 고강도 시멘트 경화체의 제조 및 특성분석)

  • 연영훈;최상흘
    • Journal of the Korean Ceramic Society
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    • v.31 no.12
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    • pp.1507-1512
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    • 1994
  • High strength cement hardened body was prepared by ordinary portland cement, silica-fume, super-plasticizer and the industrial by-product powder such as tailing, paper sludge ash and granulated slag. These raw materials were mixed and formed with w/c=0.18. The cement hardened body is cured in the autoclave at 18$0^{\circ}C$, 10atm. These admixtures made the compressive strength of all specimens develope by 170~230%. The highest compressive strength could be obtained by 236 MPa when mix composition was 14 wt% of silica-fume and 26 wt% of granulated slag. The compressive strength increased with decreasing the average pore size and the amount of the poe over the size of 50 nm by which the appearance of high compressive strength of the cement hardened body were mainly influenced. In the result, the hydration products were C-S-H, tobermorite and ettringite and it was realized that the reason why the cement hardened body became dense and revealed the higher strength was that those hydrates were formed inside of the pore and filled in it and the unhydrated materials played the role of an inner-filler.

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Reclamation of Inorganic wastes to Artificial Lightweight Aggregates

  • Chang, Hui-Lan;Liaw, Chin-Tson
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.565-570
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    • 2001
  • Annually, Taiwan generates approximately 2 million tons of inorganic wastes in the form of sludge, fly ash and slug. To increase the added value of waste and maintain the increasingly insufficient supply of natural gravel, large public construction projects account for this large demand each year. future architectural trends are leading towards high-rise buildings. In light of the above, Center for Environmental, Safety and Health Technology Development, Industrial Technology Research Institute has developed the technology of manufacturing cold-bonding, sintering and bloating types of lightweight aggregates with a specific gravity ranging between 0.7~1.7, water absorption rate < 30%. The lightweight aggregate verified by physical property tests can be used as a substitute for the natural aggregate, which generally appears in replacing gravel in concrete, soundproofing and heat insulation materials. Doing so would not only moderate waste disposal problems, but also achieve the goal of resource recovery.

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Synthesis of Alinite-Calciumchloroaluminate System Cement Using Solid State Waste

  • Cho, Jin-Sang;Han, Gi-Chun;Kim, Hyung-Seok;Ahn, Ji-Whan;Kim, Hwan;Lee, Hyoung-Ho
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.581-585
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    • 2001
  • Alinite-Calciumchloroaluminate system clinker was synthesized from solid state waste. The raw materials were municipal incineration ash, sewage sludge, limestone and clay. ecocement was prepared by the mixing of synthesized clinker and optimum amount of gypsum and its hydrolysis characteristic was investigated. X-ray diffraction, conduction calorimeter and reflecting microscope were used to analyze structural and physical properties. The main phase of clinker were alinite, calcium chloroaluminate. $C_2$S, $C_3$S. From the results of hardening time, hydration reactivity of synthesized all samples was faster than that of ordinary portland cement.

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CLASSIFICATION OF LAKE SEDIMENTS BY USING HYDROCYCLONES

  • Jo, Young-Min;Jang, Hyun-Tae
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2001.11a
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    • pp.64-69
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    • 2001
  • The present work provides a result from the preliminary experiment for hydrocyclone technology. In this work, local lake sediments and waste coal fly ash were used as test samples, prior to the application of hydrocyclone technology to the waste sludge thickening. A few cyclones based on the Rietema standard geometry were prepared. Chemical analysis of the sediments showed that more organic contaminants were in smaller particles. The experimental tests further showed that physical characteristics of particles, configuration of the cyclone and operation condition would affect the separation efficiency. The current results showed that small size cyclones might improve the separation and concentration of the lake sediments, and higher inlet velocity would increase the concentration rate of under flow and absolute concentration of sediment particles.

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Effects of Soil Amendments on the Early Growth and Heavy Metal Accumulation of Brassica campestris ssp. Chinensis Jusl. in Heavy Metal-contaminated Soil (중금속 오염 토양에서 안정화제가 청경채의 초기 생육과 중금속 흡수량에 미치는 영향)

  • Kim, Min-Suk;Koo, Namin;Kim, Jeong-Gyu;Yang, Jae-E.;Lee, Jin-Su;Bak, Gwan-In
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.6
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    • pp.961-967
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    • 2012
  • There have been many studies about efficiency of amendments for heavy metal stabilization through chemical assessment. The objective of this study was to evaluate the efficiency of several soil amendments (lime, agric-lime, dolomite, steel slag, fly ash and acid mine drainage sludge) on heavy metals stabilization through not only chemical but also biological assessments (phytotoxicity test) in abandoned mining area soil. In order to achieve the goal, we conducted preliminary screening experiment targeting 12 types of crop plants such as radish, young radish, chinese cabbage, winter grown cabbage, cabbage, bok choy, chicory, crown daisy, carrot, chives, spinach, and spring onion. The results of inhibition rates of early plant growth in metal-contaminated soil against non-contaminated soil and the correlations between inhibitions items showed that the bok choy was appropriate specie with respect to confirm the effect of several amendments. Several amendment treatments on contaminated soil brought about the changes in the root and shoot elongation of bok choy after 1 week. Agric-lime, dolomite and steel slag treatments showed the great efficiency of reducing on mobility of heavy metals using chemical assessment. But in contrary, these treatments resulted in the reduction of root and shoot elongation and only AMD sludge increased that of elongation, significantly. When considering both chemical and biological assessments, AMD sludge could be recommended the compatible amendment for target contaminated soil. In conclusion, biological assessment was also important aspect of decision of successful soil remediation.