• Title/Summary/Keyword: sludge

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Mercury Emission Characteristics from Co-Combustion of Coal and Sludge (석탄과 슬러지의 혼합연소에 따른 수은 배출 특성)

  • Kang, Sin-Wook;Shim, Sung-Hoon;Jeong, Sang-Hyun;Jung, Jong-Hyeon;Lee, Sang-Sup
    • Journal of Korean Society for Atmospheric Environment
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    • v.28 no.2
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    • pp.182-189
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    • 2012
  • Co-combustion of sludge with coal is proposed as an alternative option for sludge disposal instead of ocean dumping. Because the combustion of sludge can cause emissions of various air pollutants, it is important to understand the characteristics of sludge combustion flue gases. Especially, very few studies are found to investigate mercury emissions from the co-combustion of sludge with coal. In this study, coal and sludge samples were prepared with different mixing ratios. These samples were combusted in a bench-scale combustor, and their flue gases were analyzed. Due to higher mercury content in the sludge sample, higher mercury emissions were found with an increase in a ratio of sludge to coal. Compared to the combustion flue gas of the coal sample, higher levels of mercury oxidation were found in the combustion flue gas of the samples including sludge.

Adsorption Characteristics of Heavy Metals for Waste Sludge and Oyster Shell (폐슬러지와 폐굴껍질의 중금속 흡착특성)

  • Jeon, Dae-Young;Lee, Kyung-Sim;Shin, Hyun-Moo;Oh, Kwang-Joong
    • Journal of Environmental Science International
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    • v.15 no.11
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    • pp.1053-1059
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    • 2006
  • This study was performed to investigate the possible uses of waste sludge for the removal of heavy metal ions. The adsorption experiments were conducted with wastes such as sewage treatment sludge, water treatment sludge and oyster shell to evaluate their sorption characteristics. Heavy metals selected were cadmium, copper and lead. in the sorption experiments on the sewage treatment sludge, water treatment sludge, oyster shell and soil, sorption occurred in the beginning and it reached equilibrium after 40 minutes on the oyster shell and 4 hour on the sewage treatment sludge and water treatment sludge. Results of Freundlich isotherms indicated that sewage treatment sludge could be properly used as an adsorbent for heavy metals and sorption strength of heavy metals was in the order of Pb > Cu > Cd. In the influence of pH on the adsorbents, sorption rate was more than 80% in pH 4 and most of heavy metals were adsorbed in pH 9. Adsorption rate of Cd decreased with decreasing pH and then adsorption rate of Cu was lower in soil.

Change of Sludge-Recycle Ratio for the Bio-gas Production Improvement and Minimization with Two-Stage Anaerobic Digestion (2단 혐기성소화공정에서 반송변화를 통한 Bio-gas 생산량 증대 및 감량화)

  • Lee, Tae-Woo;Yang, Hae-Young;Do, Choong-Ho
    • Journal of the Korean Society of Industry Convergence
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    • v.15 no.3
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    • pp.83-86
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    • 2012
  • This study have cross checked the change of internal sludge-recycle in Full-scale Anaerobic-Digestion, and researched about not only the improvement of Bio-gas production from the digested sludge but also the efficient method of sludge minimization. Ultimate aim of the study is to reduce the amount of sludge by the improved efficiency of contact with the organic-matter and the microbes in Anaerobic-Digestion. The sludge-recycle fluidized sludge layer and raised the activity of the sludge, The sludge-recycle ratio of optimum was 500%, VS and COD removal ratio respectively appeared with 67.8% and 70.4%. Through these result of this study, it may be positive view to treat waste sludge by the sludge-recycle ratio in terms of minimization and circulation of resources.

Performances of a Sludge Reduction Process Using High Concentration Membrane Bioreactor with Sludge Pretreatment (슬러지 전처리와 고농도 MBR을 이용한 슬러지 감량화 공정연구)

  • Han, Kyu-Chul;Yeom, Ik-Tae;Jung, Woo-Jin;Kim, Hyung-Soo
    • Journal of Korean Society of Water and Wastewater
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    • v.17 no.4
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    • pp.559-566
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    • 2003
  • From this research, the performances of a sludge reduction in the sewage sludge aerobic digestion was experimented by using a sludge pretreatment and membrane bioreactor. The submerged plate membrane was used as the solid-liquid separation membrane. After drawing small amounts of sludge in a bioreactor and then doing the alkaline treatment and ozone treatment, the sludge was sent to back to the reactor. The HRT in the reactor was set as 5 days and the operation in the reactor was carried out at the DO of 1mg/L on average. After 100 days of operation in the reactor, it was shown that the reduction efficiency of total solids was more than 83%. Most of volatile solids were removed through mineralization, and the considerable portion of the non-volatile solids was dissolved and then flowed out with the effluent. Only about 16.3% of total solids in the sludge was accmulated in the reactor even without the loss of volatile fraction. Also, by deriving nitrification and denitrification in one reactor simultaneously, more than 90% of nitrogen removal effect was realized and the experiment was run smoothly without fouling of membrane, even in the high concentration of MLSS. Based on this experiment, sludge can be reduced considerably at a low HRT by these two newly suggested approach.

Effects of ECP (exocellular polymers) Changes to the Dewaterability and Settlability of Wastewater Sludge Pretreated by Acid and Ultrasonic (하수슬러지의 산과 초음파 처리에 따른 ECP(exocellular polymers)의 거동이 탈수성과 침강성에 미치는 영향)

  • Hwang, Sun-Jin;Jeong, Kyu-Ho;Whang, Gye-Dae
    • Journal of Korean Society of Water and Wastewater
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    • v.16 no.6
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    • pp.733-740
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    • 2002
  • The effects on dewaterability and settlability of wastewater sludge according to acid and ultrasonic pretreatment which was expected to change ECP (exocellular polymers) compounds in the sludge and bulk solution was investigated. Though ECP which attached to the sludge could stimulate coagulation of sludge particles by bridging effect, but ECP in the bulk solution deteriorated dewaterability and settlability of the sludge on the contrary. That is as the pH of the solution was decreased to 3 gradually by acid treatment, proportionally ECP in the bulk solution was attached to the sludge flocs and resulted in improvement of dewaterability and settlability of the sludge. In case of ultrasonic pretreatment, with proportional to the intensity and duration of ultrasonic application, ECP was detached and extracted from sludge flocs and these phenomena deteriorated dewaterability and settlability. Also because of the increasement of minute sludge particles according to ultrasonic, dewaterability became so much the worse.

Change of Sludge Consortium in Response to Sequential Adaptation to Benzene, Toluene, and o-Xylene

  • Park, Jae-Yeon;Sang, Byoung-In
    • Journal of Microbiology and Biotechnology
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    • v.17 no.11
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    • pp.1772-1781
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    • 2007
  • Activated sludge was sequentially adapted to benzene, toluene, and o-xylene (BTX) to study the effects on the change of microbial community. Sludge adapted to BTX separately degraded each by various rates in the following order; toluene>o-xylene>benzene. Degradation rates were increased after exposure to repeated spikes of substrates. Eleven different kinds of sludge were prepared by the combination of BTX sequential adaptations. Clustering analyses (Jaccard, Dice, Pearson, and cosine product coefficient and dimensional analysis of MDS and PCA for DGGE patterns) revealed that acclimated sludge had different features from nonacclimated sludge and could be grouped together according to their prior treatment. Benzene- and xylene-adapted sludge communities showed similar profiles. The sludge profile was affected from the point of the final adaptation substrate regardless of the adaptation sequence followed. In the sludge adapted to 50 ppm toluene, Nitrosomonas sp. and bacterium were dominant, but these bands were not dominant in benzene and benzene after toluene adaptations. Instead, Flexibacter sp. was dominant in these cultures. Dechloromonas sp. was dominant in the culture adapted to 50 ppm benzene. Thauera sp. was the main band in the sludge adapted to 50 ppm xylene, but became vaguer as the xylene concentration was increased. Rather, Flexibacter sp. dominated in the sludge adapted to 100 ppm xylene, although not in the culture adapted to 250 ppm xylene. Two bacterial species dominated in the sludge adapted to 250 ppm xylene, and they also existed in the sludge adapted to 250 ppm xylene after toluene and benzene.

Effect on Drying Efficiency of the Sewage Sludge (Digested, non digested) according to Polymer dose Ratio - Focus on the NIR and Microwave - (약품 주입비율에 따른 하수 슬러지 형태(소화·비소화)가 건조효율에 미치는 영향 - 근적외선 및 마이크로파를 중심으로 -)

  • Lee, Seung-Won
    • Journal of Environmental Science International
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    • v.30 no.3
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    • pp.245-255
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    • 2021
  • In this study, we evaluated the effect of the type of sewage sludge (digested, non digested) on drying efficiency according to the polymer injection rate. The drying characteristics were shown using a near-infrared ray (NIR) and a microwave. As a result of the drying characteristics with NIR at a polymer dose ratio of 8%, the heating up period is up to 6 minutes after the start of the drying experiment. Afterwards, the constant rate drying period of the digested sludge (A, C and G sites) was 6 minute → 18 minute, showing a rapid decrease in moisture. On the other hand, non digested sludge (B, D, E, F, H, I, J and K sites) showed gradual drying characteristics compared to digested sludge until complete drying (10%). As the polymer dose ratio of 10% and 12%, the heating up period for digested sludge is up to 6 minute after the start of the experiment. Afterwards, the constant rate drying period of the digested sludge was 6 minute → 20 minute, showing a rapid decrease in moisture. On the other hand, the heating up period of non digested sludge was up to 10 minute after the start of the experiment, and the constant rate drying period was 10 minute → 22 minute, which was shorter than digested sludge. As a result of the drying characteristics with microwave at a polymer dose ratio of 8%, 10% and 12%, the constant rate drying period the digested sludge was 4 minute → 20~22 minute, showing a rapid decrease in moisture. On the other hand, non digested sludge of the constant rate drying period was 4 minute → 22~30 minute, which was longer than digested sludge.

Sludge Solubilization by Pre-treatment and its Effect on Methane Production and Sludge Reduction in Anaerobic Digestion (전처리 방법에 따른 슬러지 가용화가 혐기소화에서 메탄 생산과 슬러지 감량에 미치는 영향)

  • Kim, Dong-Jin;Kim, Hye-Young
    • Korean Chemical Engineering Research
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    • v.48 no.1
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    • pp.103-109
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    • 2010
  • Anaerobic digestion has been widely used for the treatment of sludge, which is generated from the municipal and industrial wastewater treatment, for its volume reduction and methane production. Many researches on sludge pre-treatment have been carried out in order to enhance the performance of anaerobic digestion by increasing the hydrolysis of sludge which is the rate limiting step of anaerobic digestion. In this study, the effect of pre-treatment on sludge hydrolysis(solubilization), methane production and sludge reduction by anaerobic digestion after thermal, ultrasonic, and thermal-alkali sludge treatment were compared. Thermal-alkali treatment showed 67 and 70% solubilization with municipal and industrial wastewater sludge, respectively, while ultrasonic treatment and thermal treatment gave similar solubilization efficiency of 40% or more. Methane content of the anaerobic digestion gas reached 45~70% and pretreated sludge gave higher methane content than the control sludge. Methane production of thermal, ultrasonic, and thermal-alkali pre-treatment gave 2.6, 2.7, 3.5 times of municipal control sludge and 3.5, 4.1, 4.2 times of industrial control sludge, respectively. Sludge reduction of pre-treated sludge after anaerobic digestion gave 5~19% point higher than that of control sludge, and thermal-alkali treatment showed higher reduction efficiency than thermal and ultrasonic treatment. The results proved that pre-treatment contributed significantly not only for the methane production but also for the cost reduction of sludge treatment and disposal, and thermal-alkali treatment gave the best performance for the sludge treatment.

Effect of Sludge Digestion on Removal Efficiency of Heavy Metals from Sewage Sludge Using Thiobacillus thiooxidans MET (Thiobacillus thiooxidans MET를 이용한 중금속 제거 효율에 미치는 슬러지 성상의 영향)

  • 임설희;이소은;이인숙;조경숙;류희욱
    • KSBB Journal
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    • v.16 no.4
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    • pp.389-397
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    • 2001
  • The effect of sludge digestion on the leaching efficiency of heavy metals from sludge by bioleaching with Thiobacillus thiooxidans MET was investigated. The used sludges were a non- and anaerobically digested. The leaching efficiency of heavy metals was strongly dependent on the pH of the sludge solution rather than the sludge condition and stolid concentration. The lower the pH the more heavy metal was leached from 3.0 of pH. The sequent orders of leaching heavy metals were Zn, Cu, and Cr. Although the buffering capacity of non-digested sludge was similar to anaerobically digested sludge, the pH decrease rate of the anaerobically digested sludge solution was faster than that of the non-digested sludge solution due to the higher sulfur oxidation rate of T. thiooxidans MET in the anaerobically digested sludge. The amount of leached heavy metals from the anaerobically digested sludge showed higher than that of non-digested sludge at the same pH value. This result might be caused by the difference of the insoluble metal types, which were contained in the sludge. An increase in sludge solids concentration decreased the leaching efficiency of heavy metals in the range of solids concentration 10 g/L to 70 g/L. The optimum ratio of S° to sludge stolid was 0.1 in both the sludge. The bioleaching process of heavy metals with T. thiooxidans MET showed the disinfecting effect over 90% as well as the reduction effect in sludge weight of 20%.

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Study on Manufacture of Korean Paper(Hanji) Sludge-Wood Fiber Composite Boards II. Mechanical Properties of Korean Paper(Hanji) Sludge-Wood Fiber Composite Boards (한지슬러지-목재섬유 복합보드의 제조연구 II. 한지슬러지-목재섬유 복합보드의 기계적 성질)

  • Lee, Phil-Woo;Lee, Hak-Lae
    • Journal of the Korean Wood Science and Technology
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    • v.27 no.2
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    • pp.31-37
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    • 1999
  • This study was carried out to develop the Korean paper(Hanji) sludge-wood fiber composite boards utilizing the relinquished sludges occurring from the making process of Korean classic paper Hanji. The bark of paper mulberry(Broussonetia kazinoki Sieb.) has been used as a raw material since past hundreds and thousands years. Korean paper(Hanji) sludge was divided into two kinds, the one was the white sludge from the first stage and the other was the black sludge occurring from the final stage of Korean paper(Hanji) making. Four levels of the mixed ratio of each white or black sludge to wood fiber(10:90, 20:80, 30:70 and 40:60), three levels of the resin adhesives(PMDI, urea and phenol resin) and three levels of the density(0.60, 0.75 and 0.90) were designed to investigate the mechanical properties of Korean paper(Hanji) sludge-wood fiber composite boards. From the results and discussion, it could be concluded as follows : 1. In the white and black sludge-wood fiber composite boards, bending modulus of rupture showed the clear decreasing tendency according to the increase of sludge additive, but it was clearly increased with the increase of specific gravity. Modulus of elasticity showed the same tendency as in the modulus of rupture, and also tensile and internal bonding strength had the same tendencies as in these bending properties. 2. Among the resin adhesives, PMDI or urea resin showed great values in MOR of white sludge-wood fiber composite board, but urea resin was greater than PMDI in MOR and MOE of black sludge-wood fiber composite board. Tensile and internal bonding strength showed the same tendencies as in white sludge-wood fiber composite board. 3. It is suggested that the white sludge-wood fiber composite boards bonded with PMDI or black sludge-wood fiber composite boards bonded with urea resin were able to made similar boards to general fiberboard by the mixed ratio 20:80 of sludge to wood fiber.

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