• Title/Summary/Keyword: slag content

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The influence of sulphates and chlorides on the properties of slag blended cement (슬래그 혼합 시멘트의 물서에 미치는 황산염과 염화물의 영향)

  • 성진욱;이승헌;김창은
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.127-130
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    • 1999
  • Physical properties and microstructure of slag blended cement were investigated to evaluate the influence of sulphates and chlorides. The compressive strength developed as high chloride content dust and gypsum added and accordingly the microstructure modification was showed. The deviation of pore size distribution and hydrates was also observed. From these results we discussed optimum condition of gypsum and high chloride content dust leading to physical properties in this study.

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Thermodynamic of Phosphorus in FeO-MnO-CaO-SiO2-MgOsatd. Slag Systems (FeO-MnO-CaO-SiO2-MgOsatd. 슬래그에서의 P의 열역학적 거동)

  • Cho, Moon Kyung;Park, Kyung Ho;Min, Dong Joon
    • Korean Journal of Metals and Materials
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    • v.47 no.3
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    • pp.188-194
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    • 2009
  • Recently, new extraction technology for manganese nodule has been developed as alternative noble metallic resources. It is important to understand thermodynamic behaviors of phosphorus in low basic slag system from the viewpoint of the refining processing optimization. Thermodynamic behaviors of phosphorus in the $FeO-MnO-CaO-SiO_2-MgO_{satd.}$ slag system were investigated at 1723 K with various oxygen potential and slag composition of low basicity. The experimental results for dependence of phosphorus on oxygen potential and slag basicity indicated that the dissolution mechanism of phosphorus into slag of low basicity could be derived as follows; $[P]+5/4O_2+(O^{2-})=({PO_{3.5}}^{2-})$ Present experimental results implied that stability of phosphorus in slag would be depended on both of $O^{2-}$ (basicity) and content of $Ca^{2+}$ in molten slag. The thermodynamic effect of FeO, MnO and $Na_2O$ on low basicity on phosphate capacity was discussed.

Evaluation of Basic Oxygen Furnace Slag as Soil Conditioner in the Rice Paddy Field (논토양 벼재배에서 제강슬래그의 토양개량제로서의 시용 효과)

  • Lim, June-Taeg;Lee, Yeen;Park, In-Jin;Lee, Choong-Il;Hyun, Kyu-Hawn;Kwon, Byung-Sun;Kim, Hak-Jin
    • Korean Journal of Soil Science and Fertilizer
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    • v.32 no.3
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    • pp.295-303
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    • 1999
  • An experiment was conducted to evaluate the possibility of using basic oxygen furnace (BOF) slag as a soil conditioner in rice paddy field. In 1997, rice (Oryza sativa B. cv. Dongjinbyeo) crop was cultivated under different application rates of BOF slag at three different places, Inandong Sunchon city, Youjunglee Bosung province, and Nampyung Najoo city. In each paddy field, five treatments, four application rate of BOF slag (0, 4, 8, $12Mg\;ha^{-1}$) and one application rate of lime ($2Mg\;ha^{-1}$) were tried with three replications. Plant height, number of tillers per hill, leaf area per hill, leaf dry weight, calm dry weight or shoot dry weight per hill were measured five times at the interval of seven days. Chemical contents of rice plants and soil were also measured at the same sampling date Yield were estimated by harvesting $6.6m^2$ per experimental unit and yield components were measured by sampling 10 plants per experimental unit at the harvest date. Application of BOF slag hardly affected contents of soil organic matter, available phosphate and potassium in soil. Soil pH and contents of Ca, Mg, Fe and $SiO_2$ enhanced as BOF slag rate increased. Enhancement of soil pH by ROF slag treatment appeared to be closely related with increase in soil Ca content. Application tate of $2Mg\;ha^{-1}$ of lime showed almost the same effect, in increase of soil Ca content as application rate of $4{\sim}8Mg\;ha^{-1}$ of BOF slag, Fe content in soil decreased sharply as time passed after slag treatment and stabilized more or less at the later sampling date. Contents of inorganic matter in plant such as total nitrogen, phosphate, potassium and Mg were not affected by BOF slag treatment. However, contents of Ca, Fe, and $SiO_2$ in plants increased as slag rate became higher. The growth of rice plants with BOF slag treatment was more or less slower but continued persistently up to the later growth stage, so that growth of plants with BOF slag treatment was almost the same nr even greater than that of control or lime treatment. However, BOF slag rate of $12Mg\;ha^{-1}$ seemed to be too high because all the measurements of plant, growth at this rate showed lower values than those of other treatments at all the sampling dates. Treatments of BOF slag $4Mg\;ha^{-1}$ or $8Mg\;ha^{-1}$ showed higher rough rice yield than other treatments, so that the optimum BOF slag ratein rice paddy field seemed to be in the rage of $4{\sim}8Mg\;ha^{-1}$.

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Utilization of Blast Furnace Slag Quenched with Water as a Source of Silicate Fertilizer -II. Effect of Particle Size Distribution of Quenched Slag on Rice Yields (급랭광재(急冷鑛滓)의 비료화(肥料化)에 관(關)한 연구(硏究) -II. 수도(水稻)에 대한 급랭광재(急冷鑛滓)의 입도별(粒度別) 비효(肥效))

  • Lim, Dong-Kyu;Shin, Jae-Sung;Kim, Heung-Bae
    • Korean Journal of Soil Science and Fertilizer
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    • v.18 no.1
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    • pp.67-71
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    • 1985
  • The objective of this study was to attest the feasibility of the utilization of the blast furnace slag, quenched with water as a source of silicate fertilizer. A pot experiment was conducted to evaluate the effect of quenched slag and its particle size distribution on rice plant growth over the corresponding air-cooled slag of milled commercial silicate fertilizer. The yields of rice were slightly higher in quenched slag than in the commericial air-cooled slag, however, no significant statistical difference was observed. The silica content of rice plants through the growing period was high in quenched slag in any tested particle sizes. This indicated that the quenched slag might release silica fastly in soil. On the other hand, the available silica content retained in soil was high in air cooled slag, which implied that the silica of air-cooled slag was low acting. The results suggested that the quenched slag may be potentially utilized as a source of silicate fertilizer.

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Desulfurization Reaction according to Ladle Slag Recycling Method in Shaft-Type EAF Operation (Shaft형 전기로 공정에서 ladle 슬래그 재활용 방법에 따른 탈황반응)

  • Jung-Min Yoo
    • Resources Recycling
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    • v.33 no.2
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    • pp.46-53
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    • 2024
  • The residual heat and high CaO content present in the slag remaining in the ladle after the completion of continuous casting in the electric arc furnace (EAF) steelmaking process have been utilized to reduce power consumption and lime usage in the ladle furnace (LF) process. However, if the timing of such processes does not align with the LF and continuous casting operations, the recycling rate will decrease. To increase the slag recycling rate, the effect of ladle slag recycling methods, specifically pouring ladle slag into the slag pot in advance for subsequent recycling, on LF operations was analyzed. The slag liquefaction rate was calculated using the thermodynamic program Factsage 8.3 for ladle molten slag recycling methods. By applying each of the 10 heats operations for the ladle slag recycling methods, the desulfurization ability and LF operation performance were compared. It was found that when slag was immediately recycled into the ladle after continuous casting was completed, power consumption decreased by 0.3 MWh, LF operation time was shortened by 1.2 minutes, and the desulfurization rate increased by 5.8%.

A study on Utilization for Agriculture Using converter slag (제강전로슬래그의 농자원화 방안에 관한 연구)

  • 박정희;윤춘경;함종화
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 1998.10a
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    • pp.541-546
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    • 1998
  • To study the possibility of agricultural utilization of the sewage sludge and the converter slag, the chemical properties of soil, the growth response of corn plant and uptake of inorganic nutrients in plant tissues were investigated by application of the composts made of the sewage sludge and converter slag. Uptake of inorganic nutrients in stem and leaf of corn plant were decreased by applications of the composts. The content of heavy metals in soil and corn plant were investigated, but the results of show that the concentrations of heavy metals are much low.

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Hydration Products, Morphology and Microstructure of Activated Slag Cement

  • Murmu, Meena;Singh, Suresh Prasad
    • International Journal of Concrete Structures and Materials
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    • v.8 no.1
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    • pp.61-68
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    • 2014
  • This paper reports the physical properties and hydration products of slag cement that was prepared by activating ground granulated blast furnace slag with commercial lime and plaster of Paris (POP) as activators. The consistency, setting times and soundness of various mixes of slag-lime-POP is reported. The hydration products and formation of bonds in the paste during setting were studied with the help of SEM, FTIR and XRD tests and the same are correlated to the hydration process. The setting times of the mixes are found to be lower than that of the value prescribed for ordinary Portland cement (OPC). Borax is used as a setting retarder and a borax content of 0.4 % by mass gives setting times that are normally prescribed for OPC. In the early stages of setting C-A-S-H gels are found in this cementing material instead of C-S-H gel, as generally observed in the OPC.

A Study on the EMP Shielding Properties of Concrete Using Steel Slag (제강슬래그를 사용한 콘크리트의 EMP차폐 특성에 관한 연구)

  • Min, Tae-Beom;Choi, Hyun-Kuk;Kim, Hyeong-Cheol;Kim, Jae-Young;An, Dong-Hee
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.05a
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    • pp.170-171
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    • 2019
  • The EMP slip rate was compared with the general concrete using the electric arc furnace slag as an aggregate. Experimental results show that the shielding rate of concrete specimens using electric arc furnace slag increases. It is considered that the shielding rate is increased due to the high Fe content in the components of the electric arc furnace slag aggregate.

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Experimental Study on the Development of High-Performance Concrete (고성능 콘크리트 개발에 관한 실험적 연구 제 1보 : 고미분말 슬래그 혼합시멘트의 물성)

  • 구자술;이영진;김남호;정재동
    • Proceedings of the Korea Concrete Institute Conference
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    • 1993.10a
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    • pp.45-50
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    • 1993
  • This paper describes some results of various tests which were carried out with varying the fineness of salg from 6000 to 10000$\textrm{cm}^2$/g and the slag content in cement from 30 to 50wt% for the perpose of utilizing finely ground blast-furnace slag as an ingredient for high-performance concrete. Test for heat of hydration, microstructural and hydration characteristics in paste, and fluidity and compressive strength in mortar were carried out. From these test results, it was found that, by properly determining the content and fineness of the slag, it is possible to manufacture high-performance concrete that has low heat of hydration, high early strength development, fine pore size and a highly densified microstructure.

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Physical and Mechanical Properties of Low Carbon Green Concrete (저탄소 그린콘크리트의 물리·역학적 특성)

  • Cho, Il Ho;Sung, Chan Yong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.55 no.3
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    • pp.123-128
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    • 2013
  • This study was performed to evaluate the slump flow, air content, setting time, compressive strength, adiabatic temperature rise and diffusion coefficient of chloride used ordinary portland cement, crushed coarse aggregate, crushed sand, river sand, fly ash, limestone powder, blast furnace slag powder and superplasticizer to find optimum mix design of low carbon green concrete for structures. The performances of low carbon green concrete used fly ash, limestone powder and blast furnace slag powder were remarkably improved. This fact is expected to have economical effects in the manufacture of low carbon green concrete for structures. Accordingly, the fly ash, limestone powder and blast furnace slag powder can be used for low carbon green concrete material.