• Computers and Concrete
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• v.32 no.1
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• pp.45-60
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• 2023

Concrete in water environment is easily subjected to the attack of leaching, which causes its mechanical reduction and durability deterioration, and the key to improving the leaching resistance of concrete is to increase the compaction of its microstructure formed by the curing. This paper performs a numerical investigation on the intrinsic relationship between microstructures formed by the hydration of cement and slag and leaching resistance of concrete in water environment. Firstly, a shrinking-core hydration model of blended cement and slag is presented, in which the interaction of hydration process of cement and slag is considered and the microstructure composition is characterized by the hydration products, solution composition and pore structure. Secondly, based on Fick's law and mass conservation law, a leaching model of hardened paste is proposed, in which the multi-species ionic diffusion equation and modified Gérard model are established, and the model is numerically solved by applying the finite difference method. Finally, two models are combined by microstructure composition to form an integrated curing-leaching model, and it is used to investigate the relationship between microstructure composition and leaching resistance of slag-blended cement pastes.

• Journal of the Korea Concrete Institute
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• v.29 no.3
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• pp.315-322
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• 2017

The purpose of this study is to investigate experimentally the construction performances and economical evaluation of the self-compacting concrete in actual site work after selecting the optimum mix proportions according to cementitious materials. Slag cement type of 46.5% slag powder and belite cement of 51.4% $C_2S$ content, lime stone powder as binders are selected for site experiment including water cement ratio. Also, test items for optimum mix proportion are as followings ; (1) Slump flow, 500 mm reaching time, V-type flowing time and U-box height (2) Setting time, bleeding, shortening depth and adiabatic temperature rising (3) Mixing time in plant (4) Concrete quantity and cost, quality control in actual concrete work. As test results, (4) Optimum water-cement ratio ; Slag cement type 41.0% and belite cement 51.0% (2) Setting time and bleeding finishing time of slag cement are faster, bleeding content of slag cement is higher, shortening depth and adiabatic temperature rising of belite cement type are lower (3) Optimum mixing time in batcher plant is 75 seconds and concrete productive capacity is about $100{\sim}110m^3/hr$. (4) Belite cement type is lower than slag cement type in material cost 14.0%, and concrete quantity in actual concreting work save 3.3% in case of belite cement type. Therefore, self-compacting concrete of belite cement type is definitely superior to that of slag cement type in various test items without compressive strength development.

• Clean Technology
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• v.6 no.1
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• pp.61-69
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• 2000

In this study, generation process and properties of inorganic industrial waste which can be used in cement industry were investigated. The scheme of recycling to use the selected waste as raw materials, mineralizer and flux, admixture and raw materials for special cement was decided and then various experiments were carried out. The experimental results were as follows ; In the use of industrial waste as raw materials, ferrous materials could be substituted by Cu-slag, Zn-slag, electric arc furnace or convertor furnace slag etc., and a siliceous material could be substituted by sand from cast-iron industry. By-products from sugar or fertilizer industry, which has $CaF_2$ as the main component, and jarosite from Zn refinery enabled clinker phases to be formed at lower temperature by $100{\sim}150^{\circ}C$. Adding Cu slag and STS sludge in proper proportion to cement improved properties of cement. Fly ash and limestone powder as admixture had the same effect on cement. As a raw material for special cement, aluminium waste sludge could be used in making ultra early strength cement, which had the compressive strength of $300kg/cm^2$ within 2hours. And two different ashes from municipal incinerator could be raw materials of the cement which was mainly composed of $C_3S$ and $C_{11}A_7{\cdot}CaCl_2$ as clinker phases.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.10a
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• pp.191-194
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• 1999

Recently in Korea, may workers have reported the effects of the granulated blast furnace slag[BFS] of high fineness on the strength development of slag cement. We have studied the effect of slag fineness on the strength development of mortar with curing conditions, in order to get the basic data of high strength concrete using BFS. In this paper, we discussed the effects of slag fineness and porosity of mortar and the reaction of slag in hardened slag cement.

• Journal of the Korean GEO-environmental Society
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• v.23 no.5
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• pp.33-39
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• 2022

For a slag-cement-bentonite (slag-CB) cut-off wall, GGBS replaces a part of the cement mixed to build a CB cut-off wall, which is used to block the flow and leakage of pollutants or groundwater; prevent seawater infiltration; and repair or reinforcement an aged embankments. Slag-CB cut-off walls are used in various applications in different fields where groundwater control is required due to its excellent characteristics. Such properties include high strength, low permeability, high durability and chemical resistance. However, despite these advantages, slag-CB cut-off walls are not extensively studied in Korea and thus are not applied in many cases. Particularly, GGBS, which replaces cement in a mixture, has different properties depending on its country of production. Consequently, it is necessary to perform various studies on slag-CB cut-off walls that use GGBS produced in Korea in order to increase its usability. This study has evaluated the bleeding rate, setting time, strength, and permeability in relation to the cement replacement rate of GGBS produced in Korea for slag-CB cut-off walls, with the aim to increase its usability. The evaluation found that slag-CB cut-off walls, made of a mixture containing GGBS produced in Korea, have a lower bleeding rate and permeability, and higher strengththan CB cut-off walls. It was also analyzed that such improved performance is more effective with a higher cement replacement rate of GGBS.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.10c
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• pp.19-24
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• 1998

In this study, blended cement with low blaine(2000, 3000$\textrm{cm}^2$/g) blast-furnace slag power by 10-70wt.% was investigated through the measurement hydration heat, physical properties. The experiment results indicated compressive strength was decreased as low blaine slag blended, but hydration heat was reduced significantly and flow of the cement paste was increased.

• Journal of the Korean Ceramic Society
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• v.19 no.1
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• pp.19-23
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• 1982

The technique to determine the components in the supersulphated slag cement is discussed by several selective extraction analyses. Accordingly, the rate of hydration reaction of supersulphated slag cement could be quantitatively measured by the following 3 kinds of the selective extraction analyses. (1) Determination of unreacted slag - a salicylic acid, acetone.methanol solution (2) Determination of free $CaSO_4$ - a half saturated lime water (3) Determination of free $Ca(OH)_2$ - glycerine.alcohol solution

• Proceedings of the Korea Concrete Institute Conference
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• 1995.10a
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• pp.113-118
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• 1995

The purpose of this study is to suggest concrete mix proportioning design using Blast-furnace slag cement. The mix conditions are specified by concrete strength(180~400kg/$\textrm{cm}^2$), slump$(15\pm2cm)$m and air volume$(4.5\pm1%)$. From the result of concrete mix proportioning design using Blast-furnace slag cement, unit water content can be reduced by 3~8% comparing with OPC. The relationship between strength at 28days and cement water ratio is as follow. when blast-furnace slag cement is used: $\sigma_{28}$=304.OC/W-296.8. Super-plasticizer have to be used to get a slump of 15cm when water/cement ratio is less than 45%.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2011.11a
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• pp.31-32
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• 2011

Granulated slag from metal industries and fly ash from the combustion of coal are industrial by-products that have been widely used as mineral admixtures in normal and high strength concrete. Due to the reaction between calcium hydroxide and fly ash or slag, the hydration of concrete containing fly ash or slag is much more complex compared with that of Portland cement. In this paper, the production of calcium hydroxide in cement hydration and its consumption in the reaction of mineral admixtures is considered in order to develop a numerical model that simulates the hydration of concrete containing fly ash or slag. The heat evolution rates of fly ash- or slag-blended concrete is determined by the contribution of both cement hydration and the reaction of the mineral admixtures. Furthermore, the temperature distribution and temperature history in hardening blended concrete are evaluated based on the degree of hydration of the cement and the mineral admixtures. The proposed model is verified through experimental data on concrete with different water-to-cement ratios and mineral admixture substitution ratios.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.05a
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• pp.584-587
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• 2004

This research investigates the rheological behavior and the confined water ratio of the cement paste and binder condition in order to predict mix design proportion of the high flowing concrete. The purpose of this study is to determine the optimum replacement ratio of binders including fly ash, and lime stone powder by the cement weight. For this purpose, belite cement, blast furnace slag cement and ordinary portland cement are selected. As test results, the confined water ratio shows the following range ; OPC>blast furnace slag cement>belite cement. Therefore, belite cement is proved very excellent cementitious materials in a view point of the flowability. The optimum replacement ratio of lime stone powder is shown over $30\%$ in case of belite cement and about $10\%$ in case of slag cement type. Also, the optimum replacement ratio of fly ash is shown $30\%$ by the cement weight considering the confined water ratio and deformable coefficient of the paste condition.