• 한국환경농학회지
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• 제40권2호
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• pp.142-147
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• 2021

BACKGROUND: Agricultural use and pest control purposes of pesticides may lead to livestock products contamination. Thiodicarb and its degraded product, methomyl, are carbamate insecticides that protect soya bean, maize, fruit, and vegetables and control flies in animal and poultry farms. For maximum residue limit enforcement and monitoring, the JMPR residue definition of thiodicarb in animal products is the sum of thiodicarb and methomyl, expressed as methomyl. This residue definition was set to consider the fact that thiodicarb was readily degraded to methomyl in animal commodities. And therefore the simultaneous analytical method of thiodicarb and methomyl is required for monitoring in livestock products. METHODS AND RESULTS: The study was conducted using a quick, easy, cheap, effective, rugged, and safe (QuEChERS) method and HPLC-MS/MS to determine the thiodicarb and methomyl in livestock products. The limit of quantitation (LOQ) was 0.01 mg/kg for livestock products, including beef, pork, chicken, milk, and egg. The coefficient of determinations (r²) for the calibration curve were > 0.99, which was acceptable values for linearity. Average recoveries at spiked levels (LOQ, 10LOQ, and 50LOQ, n=5) in triplicate ranged from 73.2% to 102.1% and relative standard deviations (RSDs) were less than 10% in all matrices. CONCLUSION: The analytical method was validated for the performance parameters (specificity, linearity, accuracy, and precision) in livestock products to be acceptable by the CODEX guidelines.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 1993년도 제18회 학술대회 초록집
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• pp.1-31
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• 1993

General state of research in fundamentals and applied areas of tribology is analysed with taldng account of changes in structure of funding and other aspects of transfer from centmllzed state economy to market one under simultaneous effect of USSR disintegration to independent states. Belarus Tribology Society as a coordinating body is presented. Activities of the major centers of research in friction, wear and lubrication are shown. Recent advances in development of analytical and calculation methods, surface characterization, wear testing and standardization, condition monitoring and tribomaterials are considered.

• Smart Structures and Systems
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• 제21권4호
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• pp.449-467
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• 2018

In this paper, a theoretical and numerical study on bridge simultaneous damage detection procedure for identifying both the system parameters and input excitation mass, are presented. This method is called 'Adjoint Variable Method' which is an iterative gradient-based model updating method based on the dynamic response sensitivity. The main advantage of proposed method is inclusion of an analytical method to augment the accuracy and speed of the solution. Moving mass is a model which takes into account the inertia effects of the vehicle. This interaction model is a time varying system and proposed method is capable of detecting damage in this variable system. Robustness of proposed method is illustrated by correctly detection of the location and extension of predetermined single, multiple and random damages in all ranges of speed and mass ratio of moving vehicle. A comparison study of common sensitivity and proposed method confirms its efficiency and performance improvement in sensitivity-based damage detection methods. Various sources of errors including the effects of measurement noise and initial assumption error in stability of method are also discussed.

• 대한조선학회논문집
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• 제29권1호
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• pp.14-28
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• 1992

평면판 요소에 균일한 혹은 선형적인 세기를 갖는 쏘오스 또는 다이폴이 분포된 경우, Stokes 정리를 이용하여, 표면 특이점 분포방법에서 나타나는 표면 적분식을 선적분 형태로 변환할 수 있다. 더우기 판요소가 다각형인 경우, 유기 포텐시얼과 유기속도를 구하기 위한 이 선적분의 closed-forms을 유도하였다. 이들 적분식의 해석적 계산을 통해 계산시간을 단축하고 수치해의 정도를 향상시킬 수 있을 것이다. 몇개의 계산예를 통해 해석적 적분 계산이 수치적 적분보다 우수함을 알 수 있다.

• 분석과학
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• 제7권1호
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• pp.125-132
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• 1994

김치의 향미는 당, 유기산, 유리아미노산 및 휘발성 향기성분들의 독특한 조합에 의한 것이며, 휘발성 향기성분은 함황화합물, 알코올류, 휘발성 유기산 및 터핀유 등 여러 가지 극성 및 비극성 성분들이 매우 복잡하게 혼합되어 있다. 김치 휘발성 향기성분의 분석조건을 검토한 결과 추출 분리에는 연속식 추출장치보다 dynamic headspace concentration법이 효율적이었고 GC에 의한 분석에는 5% phenyl methyl polysiloxane 컬럼에 의한 분리가 우수하였다.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
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• pp.350-353
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• 2004

This study was conducted for a rapid and simple method using GC/FID and SPME to dectermin gasonline and chlorinated solvents simultaneity. A sodium chloride concentration of 25%(vol/w) combined with such as magnetic stirried, an absorption time of 20min, an extraction temperature of 4$0^{\circ}C$, the volume of minimized 50mL of gaseous phase and a desorption time of 5min pleprovided the greatest sensitivity while maintaining analytical efficiency. Analytical parameter such as linearity was also evaluated. The linear range extend from 30 to 500ppb. The results of chlorinated solvents and gasoline mixed samples showed that solvents have been completely removed from the sample preparation step and more accurated than those obtained by the other methods.

• 농약과학회지
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• 제13권3호
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• pp.133-147
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• 2009

토양 중 농약잔류량을 신속하고 저렴하게 분석할 수 있는 다성분 동시분석법을 개발하기 위하여 작물체 중 잔류농약분석법 및 개별성분 분석법을 조사하고 확인하여 기기분석 조건을 확립하였고 분배과정의 용매별 효율성을 조사한 결과는 다음과 같았다. 국내사용농약 중 GC로 분석 가능한 성분 180 성분에 대하여 검출기별 감응성 검토결과 ECD의 경우 84 성분 및 NPD의 경우 113 성분이 예상검출한계 $0.01\;mg\;kg^{-1}$ 이하이었으며 ECD와 NPD를 종합하면 148 성분이었다. 검출한계 $0.05\;mg\;kg^{-1}$ 이하인 농약성분은 ECD 137 성분 및 NPD 170 성분이었고, 두 검출기의 결과를 종합하면 179 성분이 예상 검출한계 $0.05\;mg\;kg^{-1}$ 이하이었다. 농약성분 peak의 분리도와 분석소요시간을 고려하여 선정한 기기분석 조건에서의 머무름 시간 분포를 살펴보면 대부분의 성분이 시료주입 후 10 분에서 40 분 사이에 검출되어 적절하게 분포되었으나, 20 분과 30 분사이의 머무름 시간대에는 90 여 성분이 분포하여 많은 성분이 충분히 분리가 되지 않을 것으로 판단되었다. 분배과정의 회수율은 dichlorornethane이 가장 우수하였으며, 그 다음은 ethyl acetate/hexane 혼합용매, ethyl acetate 순으로 각각 시험대상 성분의 90%, 85% 및 81%가 70-120% 범위의 회수율을 나타내었다. 따라서 dichlorornethane을 두 분배용매체계로 대체하는 것이 가능할 것으로 사료된다.

• Structural Engineering and Mechanics
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• 제56권5호
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• pp.871-897
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• 2015

This paper presents a novel method based on sensitivity of structural response for identifying both the system parameters and input excitation force of a bridge. This method, referred to as "Adjoint Variable Method", is a sensitivity-based finite element model updating method. The computational cost of sensitivity analyses is the main concern associated with damage detection by these methods. The main advantage of proposed method is inclusion of an analytical method to augment the accuracy and speed of the solution. The reliable performance of the method to precisely indentify the location and intensity of all types of predetermined single, multiple and random damages over the whole domain of moving vehicle speed is shown. A comparison study is also carried out to demonstrate the relative effectiveness and upgraded performance of the proposed method in comparison to the similar ordinary sensitivity analysis methods. Moreover, various sources of error including the effects of noise and primary errors on the numerical stability of the proposed method are discussed.

• 식품과학과 산업
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• 제55권1호
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• pp.23-32
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• 2022

제외국에는 지정되었지만 국내에는 아직 미지정된 식품첨가물의 종류가 많다. 전세계적으로 가공식품이 꾸준히 개발됨에 따라 새로운 유형의 가공식품의 등장이 증가하고 있으며, 국가별로 수출입에 관한 법률 규정이 상이하여 우리나라에서는 안전성 검정 및 사용량 제한이 되어있지 않은 식품첨가물을 이용한 새로운 가공식품이 국내 수입식품 중 혼입되어 유통될 수 있다. 이에 따라 국민의 안전한 먹거리를 보장하기 위한 지속적인 모니터링을 하기 위하여 미지정 식품첨가물의 분석법 개발이 필요하다. 본 고에서는 학계에서 진행된 분석법 개발과 검증에 대한 연구를 소개하였으며, 선행연구에서 제시된 분석법을 활용하여 분석법 개발을 진행하였다. 첫 번째 소개된 12가지 식품 착색료에 대한 동시분석법은 선행연구 분석법의 재현이 용이하였지만, 두 번째 소개된 유화제의 분석법은 일반적인 연구실에는 구비되지 않은 고가의 장비를 이용한 분석법에 대해 활용이 불가하고, 선행 연구된 간행물이 오래되어 재현이 어려운 문제점이 있었다. 가공식품 시장이 커지면서 식품첨가물이 신생되기도 하고, 까다로운 분석물질이 등장함에 따라 미지정 식품첨가물의 분석법 개발 연구는 중요하다. 따라서 이에 관련된 국가기관(식약처 등)과 산업계, 연구계, 학계에서는 미지정 식품첨가물의 분석법 개발에 대한 끊임없는 연구 진행이 필요하며, 본 연구 분야의 발전 가능성은 무궁무진할 것으로 사료된다.

• 한국환경보건학회지
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• 제47권1호
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• pp.64-77
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• 2021

Objective: Biological monitoring of trace elements in human blood samples has become an important indicator of the health environment. The purpose of this study was to detect and evaluate multiple metal items in blood samples based on ICP-MS, to perform comparative evaluation with the existing analysis method, and to develop and verify a new method. Methods: 100 μL of whole blood from 80 healthy subjects was used to analyze ten metals (Sb, tAs, Cd, Pb, Mn, Hg, Mo, Ni, Se, Tl) using ICP-MS. Verification of the analysis method included calculation of linearity, accuracy, precision and detection limits. In addition, a comparative test with the conventional graphite furnace atomic absorption spectroscopy (GF-AAS) method was performed. In the case of Pb, Cd, and Hg in whole blood, cross-analysis between Pb, Cd, and Hg analysis methods was performed to confirm the difference between the existing method and the new method (ICP-MS). Results: The coefficient of determination (R2) was 0.999 or higher in seven items and 0.995 or higher in three items. The Pb result showed that Pearson's correlation coefficient was very high at 0.983, and the intraclass correlation coefficient was 0.966. The Cd result showed that Pearson's correlation coefficient was 0.917 between the existing method and the new analysis concentration value. Its intraclass correlation coefficient was 0.960, and there was no significant difference between the two groups. Hg had a low correlation at 0.687, and the intraclass correlation coefficient was 0.761, which was lower than that of Pb and Cd. The intra-day and inter-day accuracy of Pd and Cd were satisfactory, but Hg did not meet the criteria for both accuracy and precision when compared with the conventional analysis method. Conclusion: This study can be meaningful in that it proposes a more efficient and feasible analysis method by verifying a blood heavy metal concentration experiment using multiple simultaneous analyses. All samples were processed and analyzed using the new ICP-MS. It was confirmed that the agreement between the two methods was very high, with the agreement between the current and new methods being 0.769 to 0.998. This study proposes an efficient simultaneous methodology capable of analyzing multiple elements with small samples. In the future, studies of various applications and the reliability of ICP-MS analysis methods are required, and research on the verification of accurate, precise, and continuous analysis methods is required.