• Korean Journal of Environmental Agriculture
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• v.40 no.2
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• pp.142-147
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• 2021

BACKGROUND: Agricultural use and pest control purposes of pesticides may lead to livestock products contamination. Thiodicarb and its degraded product, methomyl, are carbamate insecticides that protect soya bean, maize, fruit, and vegetables and control flies in animal and poultry farms. For maximum residue limit enforcement and monitoring, the JMPR residue definition of thiodicarb in animal products is the sum of thiodicarb and methomyl, expressed as methomyl. This residue definition was set to consider the fact that thiodicarb was readily degraded to methomyl in animal commodities. And therefore the simultaneous analytical method of thiodicarb and methomyl is required for monitoring in livestock products. METHODS AND RESULTS: The study was conducted using a quick, easy, cheap, effective, rugged, and safe (QuEChERS) method and HPLC-MS/MS to determine the thiodicarb and methomyl in livestock products. The limit of quantitation (LOQ) was 0.01 mg/kg for livestock products, including beef, pork, chicken, milk, and egg. The coefficient of determinations (r²) for the calibration curve were > 0.99, which was acceptable values for linearity. Average recoveries at spiked levels (LOQ, 10LOQ, and 50LOQ, n=5) in triplicate ranged from 73.2% to 102.1% and relative standard deviations (RSDs) were less than 10% in all matrices. CONCLUSION: The analytical method was validated for the performance parameters (specificity, linearity, accuracy, and precision) in livestock products to be acceptable by the CODEX guidelines.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 1993.12a
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• pp.1-31
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• 1993

General state of research in fundamentals and applied areas of tribology is analysed with taldng account of changes in structure of funding and other aspects of transfer from centmllzed state economy to market one under simultaneous effect of USSR disintegration to independent states. Belarus Tribology Society as a coordinating body is presented. Activities of the major centers of research in friction, wear and lubrication are shown. Recent advances in development of analytical and calculation methods, surface characterization, wear testing and standardization, condition monitoring and tribomaterials are considered.

• Smart Structures and Systems
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• v.21 no.4
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• pp.449-467
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• 2018

In this paper, a theoretical and numerical study on bridge simultaneous damage detection procedure for identifying both the system parameters and input excitation mass, are presented. This method is called 'Adjoint Variable Method' which is an iterative gradient-based model updating method based on the dynamic response sensitivity. The main advantage of proposed method is inclusion of an analytical method to augment the accuracy and speed of the solution. Moving mass is a model which takes into account the inertia effects of the vehicle. This interaction model is a time varying system and proposed method is capable of detecting damage in this variable system. Robustness of proposed method is illustrated by correctly detection of the location and extension of predetermined single, multiple and random damages in all ranges of speed and mass ratio of moving vehicle. A comparison study of common sensitivity and proposed method confirms its efficiency and performance improvement in sensitivity-based damage detection methods. Various sources of errors including the effects of measurement noise and initial assumption error in stability of method are also discussed.

• Journal of the Society of Naval Architects of Korea
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• v.29 no.1
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• pp.14-28
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• 1992

For a planar curve-sided paned with constant or linear density distributions of source or doublet in the singularity methods, Cantaloube and Rehbach(1986) show that the surface integral can be transformed into contour integral by using Stokes' formulas. As an extension of their formulations, this paper deals with a planar polygonal panel for which we derive the closed-forms of the potentials and the velocities induced by the singularity distributions. Test calculations show that the analytical evaluation of the closed-forms is superior to numerical integration(suggested by Cantaloube and Rehbach) of the contour integral. The compact and explicit expressions may produce accurate values of matrix elements of simultaneous linear equations in the singularity methods with much reduced computer tiome.

• Analytical Science and Technology
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• v.7 no.1
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• pp.125-132
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• 1994

Flavours in kimchee are the result of unique combination of various sugars, organic acids and amino acids as well as various volatile organic compounds including sulfur-containing compounds, terpenes, alcohols, and some volatile organic acids. In the experiment for the flavour extracting methods, dynamic headspace(DHS) is more effective for collection of volatile flavour than simultaneous distillation extraction(SDE). The best polarity available at the moment is 5% phenyl methyl poly-siloxane which will separate non-polar, intermediate and polar components with good resolution.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.350-353
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• 2004

This study was conducted for a rapid and simple method using GC/FID and SPME to dectermin gasonline and chlorinated solvents simultaneity. A sodium chloride concentration of 25%(vol/w) combined with such as magnetic stirried, an absorption time of 20min, an extraction temperature of 4$0^{\circ}C$, the volume of minimized 50mL of gaseous phase and a desorption time of 5min pleprovided the greatest sensitivity while maintaining analytical efficiency. Analytical parameter such as linearity was also evaluated. The linear range extend from 30 to 500ppb. The results of chlorinated solvents and gasoline mixed samples showed that solvents have been completely removed from the sample preparation step and more accurated than those obtained by the other methods.

• The Korean Journal of Pesticide Science
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• v.13 no.3
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• pp.133-147
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• 2009

In order to develop the simultaneous analytical method for pesticide residues which ones in soil are rapidly and inexpensively measured by, many analytical methods for individual pesticide residue and several methods for multi-pesticide residues in agricultural commodities and food were reviewed. Various gas chromatographic conditions and pre-treatment procedures were intensively investigated and modified. And then new optimum procedure was established and its proficiency was validated. The response on detectors of simultaneous determination of 180 pesticides out of pesticides used in Korea was tested. The number of pesticides that their limits of detection (LOD) equal or lower than $0.05\;mg\;kg^{-1}$ were 137 pesticides on ECD, 170 pesticides on NPD and 179 pesticides on ECD/NPD integrated. The retention times of most pesticides ranged appropriately between 10 minutes and 40 minutes in the proposed chromatographic conditions. But about 90 pesticides eluded between 20 minutes and 30 minutes and so they were not resolved enough. In partition with dichloromethane, ethyl acetate/hexane (1:1) and ethyl acetate, number of pesticides whose extraction efficiency ranged from 70% to 120%, were 163, 154 and 147, respectively.

• Structural Engineering and Mechanics
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• v.56 no.5
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• pp.871-897
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• 2015

This paper presents a novel method based on sensitivity of structural response for identifying both the system parameters and input excitation force of a bridge. This method, referred to as "Adjoint Variable Method", is a sensitivity-based finite element model updating method. The computational cost of sensitivity analyses is the main concern associated with damage detection by these methods. The main advantage of proposed method is inclusion of an analytical method to augment the accuracy and speed of the solution. The reliable performance of the method to precisely indentify the location and intensity of all types of predetermined single, multiple and random damages over the whole domain of moving vehicle speed is shown. A comparison study is also carried out to demonstrate the relative effectiveness and upgraded performance of the proposed method in comparison to the similar ordinary sensitivity analysis methods. Moreover, various sources of error including the effects of noise and primary errors on the numerical stability of the proposed method are discussed.

• Food Science and Industry
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• v.55 no.1
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• pp.23-32
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• 2022

Processed foods using food additives designated as the other countries but not yet in Korea can be mixed and distributed among imported foods in Korea. Accordingly, it is necessary to develop an analysis method of undesignated food additives in order to continuously monitor. This paper introduced a study on the development and validation of analytical methods conducted in academia. The development of analytical methods was conducted using the analytical methods presented in previous studies. We first exhibited that simultaneous analysis of 12 food dyes was easy to reproduce, but the second introduced analytical method of emulsifiers cannot be utilized analysis using expensive equipment not provided in general laboratories, and it is difficult to reproduce due to the old publications. Therefore related national institutions, research and industry-academia circles need to constantly conduct research on the development of analytical methods for undesignated food additives.

• Journal of Environmental Health Sciences
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• v.47 no.1
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• pp.64-77
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• 2021

Objective: Biological monitoring of trace elements in human blood samples has become an important indicator of the health environment. The purpose of this study was to detect and evaluate multiple metal items in blood samples based on ICP-MS, to perform comparative evaluation with the existing analysis method, and to develop and verify a new method. Methods: 100 μL of whole blood from 80 healthy subjects was used to analyze ten metals (Sb, tAs, Cd, Pb, Mn, Hg, Mo, Ni, Se, Tl) using ICP-MS. Verification of the analysis method included calculation of linearity, accuracy, precision and detection limits. In addition, a comparative test with the conventional graphite furnace atomic absorption spectroscopy (GF-AAS) method was performed. In the case of Pb, Cd, and Hg in whole blood, cross-analysis between Pb, Cd, and Hg analysis methods was performed to confirm the difference between the existing method and the new method (ICP-MS). Results: The coefficient of determination (R2) was 0.999 or higher in seven items and 0.995 or higher in three items. The Pb result showed that Pearson's correlation coefficient was very high at 0.983, and the intraclass correlation coefficient was 0.966. The Cd result showed that Pearson's correlation coefficient was 0.917 between the existing method and the new analysis concentration value. Its intraclass correlation coefficient was 0.960, and there was no significant difference between the two groups. Hg had a low correlation at 0.687, and the intraclass correlation coefficient was 0.761, which was lower than that of Pb and Cd. The intra-day and inter-day accuracy of Pd and Cd were satisfactory, but Hg did not meet the criteria for both accuracy and precision when compared with the conventional analysis method. Conclusion: This study can be meaningful in that it proposes a more efficient and feasible analysis method by verifying a blood heavy metal concentration experiment using multiple simultaneous analyses. All samples were processed and analyzed using the new ICP-MS. It was confirmed that the agreement between the two methods was very high, with the agreement between the current and new methods being 0.769 to 0.998. This study proposes an efficient simultaneous methodology capable of analyzing multiple elements with small samples. In the future, studies of various applications and the reliability of ICP-MS analysis methods are required, and research on the verification of accurate, precise, and continuous analysis methods is required.