• Bulletin of the Korean Chemical Society
• /
• v.27 no.8
• /
• pp.1199-1202
• /
• 2006

A simple, sensitive and rapid spectrofluorimetric method was developed for determination of mefenamic acid in pharmaceutical preparation and human urine. The procedure is based on the oxidation of mefenamic acid with cerium (IV) to produce cerium (III), and its fluorescence was monitored at 354 nm after excitation at 255 nm. The variables affecting oxidation of drug were studied and optimized. Under the experimental conditions used, the calibration graphs were linear over the range 0.03-1.5 mg $L^{-1}$. The limit of detection was 0.009 mg $L^{-1}$ and the relative standard deviation for 5 replicate determinations of mefenamic acid at 1.0 mg $L^{-1}$ concentration level was 1.72%. Good recoveries in the range of 102-107 and 102-109% were obtained for pharmaceutical preparation and human urine, respectively. The proposed method was applied to the determination of MF in one pharmaceutical preparation and human urine. The amounts of mefenamic acid found are very similar to those obtained by a standard method.

• Bulletin of the Korean Chemical Society
• /
• v.32 no.2
• /
• pp.687-692
• /
• 2011

$^1H$ and $^{13}C$ NMR spectra of series of (E)-1-aryl-(2- and 3-thienyl)-2-propenones, that are aldol condensation products between 2- and 3-thiophenecarbaldehydes and m- and p-substituted acetophenones, were examined to make complete assignments of the chemical shifts. Long range couplings, $^4J$ and $^5J$, are observed in the $^1H-^1H$ COSY of both 2- and 3-thienyl compounds, which makes the elucidation of the conformation in solution possible. In contrast, the 2-furyl analogue shows the long range coupling phenomena, but the 3-furyl and phenyl analogues do not show similar phenomena.

• Proceedings of the KSR Conference
• /
• 2003.10a
• /
• pp.210-215
• /
• 2003

Korean High Speed Train (KHST) has been tested on high speed line in JungBu site since it was developed in 2002. The KHST figured 7 cars was modeled for dynamic simulation with Vampire program. and the data acquisition system was used to test successfully the on-line test for proving the dynamic performance of KHST. The comparison between test and simulation results for dynamic behavior of KHST was tried in this paper and it was very difficult because the environmental conditions and running conditions have an effect on the test results and these conditions are unable to be modeled for dynamic analysis. Also the parameters for data acquisition system for test are usually not same to simulation conditions. Therefor, in this paper the acceleration data after filtering with low pass filter below 1Hz were used to compare between test and simulation results because the low frequency range is useful to evaluate the dynamic performance for railway vehicle system, so as steady state curving acceleration. The results show that both are similar in low frequency range.

• Transactions of Materials Processing
• /
• v.14 no.2 s.74
• /
• pp.121-125
• /
• 2005

Electroforming is a process that employs technology similar to that used for electroplating but which is used for manufacturing metallic articles, rather than as a means of producing surface coatings. Electroforming provides a cost-effective means of producing alloys and fully dense nanocrystalline metals as foils, sheets and complex shapes. Fe-Ni nanocrystalline alloy foils with composition in the $36\~80wt\%$ Ni range were fabricated by electroforming. The thickness of electroformed foils was in the range of $5\~30{\mu}m$. TEM and XRD analysis was applied for measuring the grain size. Very fine grain size$(\~10nm)$ was obtained in alloy foils. The yield and tensile strength of electroformed Fe-Ni alloy were 2000-2800 MPa and 2500-3300 MPa respectively. The magnetic permeability at high frequency of electroformed Fe-Ni foil was higher than that of thicker foils.

• Proceedings of the Korea Electromagnetic Engineering Society Conference
• /
• 2003.11a
• /
• pp.604-608
• /
• 2003

In this paper, we studied the radiated electric field of power-line with DMT signal source in the frequency range of $1.7{\sim}30 MHz$. First, we made the midium voltage power-line communication model for PLC and calculated the current through the power-line using the impedance of the power-line model. Second, we calculated the radiated electric field in power range $-50{\sim}-30 dBm$ using the calculated current. Consequently, the calculated emissive electromagnetic field from the DMT signal is similar to the measured result. So this study is applicable to the standard regulation of electromagnetic interference for PLC.

• Journal of electromagnetic engineering and science
• /
• v.7 no.4
• /
• pp.154-160
• /
• 2007

A reconfigurable multi-band mixer for the SDR system is proposed. The proposed reconfigurable mixer is operated between $850\;MHz{\sim}2\;GHz$, which includes all commercial mobile communication service. Because the varactor diodes are used to select a specific frequency and to adjust the impedance characteristic of the selected frequency band, the proposed reconfigurable mixer can be achieved to similar performance across all of the tuning range. In addition, the designed reconfigurable mixer is applicable for the SDR system since it has a single signal path for the multi-band signals and wide band tuning range.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
• /
• 2000.04a
• /
• pp.102-108
• /
• 2000

Due to the rapid increase of long-distance transportation, particular attentions have been paid to truck tires, especially to their dynamic characteristics. In this research, experimental modal analysis on two kinds of light-truck tires, i.e., radial tire and bias tire, are performed by using GRFP(global rational fraction polynomial) method to investigate differences of the dynamic behavior of the two tires. The test results have shown that the modal frequencies of bias tire are much higher than their corresponding values of radial tire with a similar mode shape, which is in accordance with the fact that the radial rigidity of bias tire is higher than that of radial tire. And most of the modal decay rates of bias tire are larger than those of radial tire within the scope of this experiment. In the frequency domain range of test, the bias tire has extra modes, which do not occur in the radial tire. This difference is based on the fact that the circumferential rigidity of the bias tire is quite low whereas that of radial tire is so high that the frequencies of the corresponding modes are out of the frequency range of test.

• International Journal of Precision Engineering and Manufacturing
• /
• v.9 no.2
• /
• pp.44-49
• /
• 2008

This paper describes the problem of ultraprecision positioning with a ball screw mechanism in the microdynamic range, along with its solution. We compared the characteristics of two ball screw mechanisms with different table masses. The experimental results showed that the vibration resulting from the low stiffness of the ball screw degraded the positioning performance in the microdynamic range for the heavyweight mechanism. The proposed nominal characteristic trajectory following (NCTF) controller was designed for ultra precision positioning of the ball screw mechanism. The basic NCTF control system achieved ultra precision positioning performance with the lightweight mechanism, but not with the heavyweight mechanism. A conditional notch filter was added to the NCTF controller to overcome this problem. Despite the differences in payload and friction, both mechanisms then showed similar positioning performance, demonstrating the high robustness and effectiveness of the improved NCTF controller with the conditional notch filter. The experimental results demonstrated that the improved NCTF control system with the conditional notch filter achieved ultra precision positioning with a positioning accuracy of better than 10 nm, independent of the reference step input height.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
• /
• 2003.11a
• /
• pp.248-258
• /
• 2003

Finite element computations were carried out to study the indentation by rigid cone with half-angle of $70.3^{\circ}$ for 72 different combinations of elasto-plastic properties that cover the wide range of mechanical parameters of common engineering solid materials. The dimensional analysis and representative strain concept were used in the analysis. It was shown that for the same representative strain value, the loading curvature C can be formulated under two different forms, which are based on two alternative dimensionless functions. The present study's one is simpler than the other previously found by other authors using the similar approach. For a wide range of material's parameters, the hardness-modulus ratio should be a parabolic function of ${\sigma}E$, rather than a power law function earlier proposed.

• Journal of Welding and Joining
• /
• v.3 no.2
• /
• pp.1-9
• /
• 1985

In this study, the influence of carbon equivalents on friction welds of similar steels was investigated. Four types of steels with 15mm diameter tested in the wide range of carbon equivalents from 0.3 to 1.1 Main experimental results are summarized as follows : (1) Under the constant burn-off length, the friction time becomes longer with the increasing carbon equivalent, but the upset length shows no consistent tendencies. (2) Due to the recrystallization in the contact area, the maximum hardness occurs some away from the contact surface. And it increases almost linearly with the increasing carbon equivalent. (3) Even a steel with 1.1 C.E. can be friction welded to make defect-free welds. (4) With the increasing carbon equivalent, the bend angle and charpy impact value decrease very rapidly in the range from 0.3 C. E., but remain nearly unchanged for C. E. higher than 0.6. (5) Heat treatment of the base metals before welding has very little influence on the mechanical properties of welds. On the other hand, normalizing of the welds improves the bend angle and charpy impact value, but its effect becomes almost negligible, when the carbon equivalents are higher than 0.6.