• Title/Summary/Keyword: silver salt

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Evaluation of Chloride Ion Binding Capacity of Hardened Portland Cement Paste Containing Hydrotalcite (경화된 하이드로탈사이트 혼입 포틀랜드 시멘트 페이스트의 염소이온 고정능력 평가)

  • Han, Jae-Do;Lee, Yun-Su;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.27-28
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    • 2018
  • Deterioration of reinforced concrete structures due to salt corrosion is a phenomenon that can be easily seen, and the main reason for deterioration is chloride ion. Therefore, researches are actively conducted to control chlorine ion penetration worldwide. The purpose of this study is to evaluate the chloride ion fixation capacity of Portland cement paste containing Hydrotalcite. For this purpose, cement paste containing 0%, 2.5%, and 5% of Hydrotalcite was sealed and cured for 28 days, and the cured cement paste was crushed. Chloride ion solution was prepared at a concentration of 0.5M using NaCl, and the powdered cement paste was reacted for a specific time in aqueous chloride ion solution. After the reaction, the concentration of the chloride ion aqueous solution was measured using a silver nitrate potentiometric titrator, and the reacted cement paste was analyzed using XRD and FT-IR.

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The Coloring Effect of Glasses by Ag+ Ion Exchange (Ag+ 이온교환에 따른 유리의 착색 효과)

  • 이용근;이동인;윤종석;이희수
    • Journal of the Korean Ceramic Society
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    • v.26 no.4
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    • pp.499-504
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    • 1989
  • Coloring effect, mechanical properties resulting from silver ions exchange of glasses immersed into the mixed molten salt of KNO3 and AgNO3 were investigated in this study. Ion exchange coloring of glasses made it possible to obtain glasses with a range from yellow to yellowish-brown, and spectral transmittance was investigated. The amount of ion exchange and peneration depth increased with treatment temperature and time. The activation energy decreased with mole fraction of AgNO3. It can be seem that the bending strength of ion exchanged glasses were 3~4 times higher than the parent glass and Ag+ colloids prevented from increasing surface microhardness.

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Direct route to high yield synthesis of metal nanoparticles for printable electronic devices

  • Kim, Dong-Hun;Lee, Gwi-Jong;Lee, Yeong-Il;Jeon, Byeong-Ho;Choe, Jun-Rak;Seo, Yeong-Gwan;Kim, Tae-Hun;Gang, Seong-Gu
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.14.1-14.1
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    • 2009
  • We found a high yield synthetic route to organic-soluble metal nanoparticles in the concentrated organic phase. The organic phase contains metal salt, amines, fatty acids, nonpolar solvent, and reducing agent. Even using only generic chemicals, organic-soluble silver and copper nanoparticles could be easily obtained by this simple and rapid reaction scheme at large scale. The hydrocarbon-protected metal nanoparticles showed excellent dispersion properties and were successfully printed onto polymer substrates. The printed pattern was heated at $200^{\circ}C$, which showed very low specific electrical resistance (< 10 uOhm$\cdot$cm), sufficient for conducting line of various printable devices.

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Polymer Electrolyte Membranes and their Applications to Membranes, Fuel Cells and Solar Cells

  • Kang, Yong-Soo
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.07a
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    • pp.29-32
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    • 2003
  • Polymer electrolyte membranes are developed for the applications to facilitated transport membranes, fuel cells and solar cells. The polymer electrolyte membranes containing silver salt show the remarkably high separation performance for olefin/paraffin mixture in the solid state; the propylene permeance is 45 GPU and the ideal selectivity of propylene/propane is 15,000. For fuel cell membranes, the effects of the presence and size of the proton transport channels on the proton conductivity and methanol permeability were investigated. The cell performance for dye-sensitized solar cells employing polymer electrolytes are measured under light illumination. The overall energy conversion efficiency reaches 5.44 % at 10 ㎽/$\textrm{cm}^2$, to our knowledge the highest value ever reported in the polymer electrolytes.

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The Noxiousness of Aldosterone Analogue-induced Senile Disease-related Hypertension and Inhibition of the Aldosterone by Silver Spike Point Electrical Stimulation in Elderly People -The Approach of Basic Physical Therapy for the Study of Cardiovascular Disease-related Specialized Physical Therapy- (알도스테론 동족체-유도 노인성질환-연관 고혈압의 유해와 노인에 적용한 은침점전기자극의 알도스테론 억제 -심혈관질환전문물리치료 연구를 위한 기초물리치료학적 접근을 중심으로-)

  • Lee, Sook-Hee;Kang, Joon-Hwan;Lee, Sang-Bin;An, Ho-Jung;Kim, Moo-Gi;Kim, Soon-Hee;Kim, Jung-Hwan
    • Journal of Korean Physical Therapy Science
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    • v.13 no.2
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    • pp.67-83
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    • 2006
  • The present study examined that in Vivo/Vitro test is investigated in normotensive sham-operated rats (NSR) and aldosterone-analogue deoxycorticosterone acetate (DOCA)-salt hypertensive rats (ADHR) and that the antihypertensive effect was induced by silver spike point (SSP) electrical stimulation at meridian points(CV-3, -4, Ki-12, SP-6, LR-3, BL-25, -28, -32, -52), specifically, such as aldosterone in 24 hour urine analysis from healthy volunteer. The gross examination and morphometric-histological changes, such as hypertrophy, production of necrotic tissues, and the changes of cell arrangement on the kidney, and adrenal gland were markedly observed in aldosterone-analogue DOCA-salt hypertensive rats compared with those from normotensive sham-operated rats. The systolic blood pressure, weight of kidney and adrenal gland were significantly increased in ADHR than that in NSR. The required time of PSS-induced resting tone was significantly increased in ADHR than that in NSR. However, the voltage-dependent K+ (Kv) currents were significantly decreased in ADHR than that in NSR. The urine analysis showed that the concentration of aldosterone was significantly decreased in resting state from the elderly people compared with those from the adolescent healthy volunteer. The current of 1 Hz continue type of SSP electrical stimulation significantly decreased in the concentration of aldosterone of 24 hour urine from the elderly people. These results suggest that the development of aldosterone analogue-induced hypertension is associated with changed the weight of kidney and adrenal gland, blood pressure, resting tone and Kv currents, which directly affects blood pressure. Therefore, the hypertension is a risk factor on cerebrovascular disease. Moreover, these results suggest that the diminished responsiveness to SSP electrical stimulation, especially current of 1Hz continue type, in elderly people may be, in part, related by the increased of antihypertensive effects.

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Preparation of melamine-formaldehyde microcapsule by surfactants (안정화제에 따른 멜라민-포름알데히드 마이크로캡슐의 제조)

  • Oh, Seong-Dae;Choi, Seong-Ho;Lee, Se-Hee;Lee, Kwang-Pill;Kim, Sang-Ho
    • Analytical Science and Technology
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    • v.18 no.2
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    • pp.97-103
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    • 2005
  • The various size and morphology microcapsules were prepared to produce smell sweet by heating condensation reaction of melamine and formaldehyde using 5-types of surfactants such as the laurylbenzenesulfonic acid sodium salt (SDS), polyvinylpyrrolidon (PVP), polyvinyl alcohol (PVA), Span-80 and 2-acrylamido-2-methyl-1-1 propanesulfonic acid (AMP). As result it was found that the size and morphology of microcapsule is intimately associated with a kind of surfactants. In order to prepare microcapsule with antibacterial, the silver nanoparticle was prepared by gamma-irradiation. microcapsule with silver nanoparticle was prepared.

Study on Determination of Seven Transition Metal Ions in Water and Food by Microcolumn High-Performance Liquid Chromatography

  • Hu, Qiufen;Yang, Guangyu;Li, Haitao;Tai, Xi;Yin, Jiayuan
    • Bulletin of the Korean Chemical Society
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    • v.25 no.5
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    • pp.694-698
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    • 2004
  • A new method for the simultaneous determination of seven transition metal ions in water and food by microcolumn high-performance liquid chromatography has been developed. The lead, cadmium, mercury, nickel, cobalt, silver and tin ions were pre-column derivatized with tetra-(4-aminophenyl)-porphyrin ($T_4$-APP) to form the colored chelates which were then enriched by solid phase extraction with $C_{18}$ cartridge. The enrichment factor of 50 was achieved by eluted the retained chelates from the cartridge with tetrahydrofuran (THF). The chelates were separated on a ZORBAX Stable Bound microcolumn ($2.0{\times}50\;mm,\;1.8\;{\mu}m$)with methanol-tetrahydrofuran (95 : 5, v/v, containing 0.05 mol/L pyrrolidine-acetic acid buffer salt, pH = 10.0) as mobile phase at a flow rate of 0.5 mL/min and detected with a photodiode array detector from 350-600 nm. The seven chelates were separated completely within 2.0 min. The detection limits of lead, cadmium, mercury, nickel, cobalt, silver and tin are 4 ng/L, 3 ng/L, 6 ng/L, 5 ng/L, 5 ng/L, 6 ng/L, 4 ng/L respectively in the original samples. This method was applied to the determination of the seven transition metal in water and food samples with good results.

Prevalence and Molecular Characterization of Methicillin-Resistant Staphylococcus aureus from Nasal Specimens: Overcoming MRSA with Silver Nanoparticles and Their Applications

  • Aly E. Abo-Amer;Sanaa M. F. Gad El-Rab;Eman M. Halawani;Ameen M. Niaz;Mohammed S. Bamaga
    • Journal of Microbiology and Biotechnology
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    • v.32 no.12
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    • pp.1537-1546
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    • 2022
  • Staphylococcus aureus is a cause of high mortality in humans and therefore it is necessary to prevent its transmission and reduce infections. Our goals in this research were to investigate the frequency of methicillin-resistant S. aureus (MRSA) in Taif, Saudi Arabia, and assess the relationship between the phenotypic antimicrobial sensitivity patterns and the genes responsible for resistance. In addition, we examined the antimicrobial efficiency and application of silver nanoparticles (AgNPs) against MRSA isolates. Seventy-two nasal swabs were taken from patients; MRSA was cultivated on Mannitol Salt Agar supplemented with methicillin, and 16S rRNA sequencing was conducted in addition to morphological and biochemical identification. Specific resistance genes such as ermAC, aacA-aphD, tetKM, vatABC and mecA were PCR-amplified and resistance plasmids were also investigated. The MRSA incidence was ~49 % among the 72 S. aureus isolates and all MRSA strains were resistant to oxacillin, penicillin, and cefoxitin. However, vancomycin, linezolid, teicoplanin, mupirocin, and rifampicin were effective against 100% of MRSA strains. About 61% of MRSA strains exhibited multidrug resistance and were resistant to 3-12 antimicrobial medications (MDR). Methicillin resistance gene mecA was presented in all MDR-MRSA strains. Most MDR-MRSA contained a plasmid of > 10 kb. To overcome bacterial resistance, AgNPs were applied and displayed high antimicrobial activity and synergistic effect with penicillin. Our findings may help establish programs to control bacterial spread in communities as AgNPs appeared to exert a synergistic effect with penicillin to control bacterial resistance.

Evaluation of the Corrosion Resistance of Steel Coated with Zinc Using a Cr-free Coating Solution as a Function of Heat Treatment Time (Cr-free 코팅액에 의한 아연도금강판의 건조시간에 따른 내식특성)

  • Seo, Hyun-Soo;Moon, Hee-Joon;Kim, Jong-Soon;Ahn, Seok-Hwan;Moon, Chang-Kwon;Nam, Ki-Woo
    • Journal of Ocean Engineering and Technology
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    • v.24 no.5
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    • pp.67-74
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    • 2010
  • Chromate conversion coating is a coating technique used to passivate aluminum, zinc, cadmium, copper, silver, magnesium, tin, and their alloys to slow corrosion. The process uses various toxic chromium compounds, which may include hexavalent chromium. The industry is developing less toxic alternatives in order to comply with substance restriction legislation, such as RoHS. One alternative is to develop a Cr-free coating solution. In this study, eco-friendly, Cr-free solutions (urethane solution S-700, organic/inorganic solution with Si LRO-317) were used. Test specimens were dried in a drying oven at $190^{\circ}C$ for 3, 5, 7, and 9 minutes. Corrosion resistance was evaluated using a salt spray test for 72 hours. The results show that the optimum corrosion resistance was achieved at $190^{\circ}C$ for five minutes for EGI and three or five minutes for HDGI, respectively. The adhesive properties of the two types of coating solutions were superior regardless of drying time.

Facilitated Transport Membrane for Ethylene/Ethane and Propylene/Propane Separation (SPEEK-Ag 촉진 수송 분리막을 이용한 $C_2,\;C_3$ 계 올레핀/파라핀 분리)

  • Kim, Ji-Yeon;Lee, Hyun-Joo;Kim, Hoon-Sik;Jung, Hyun-Wook;Choi, Dae-Ki
    • Clean Technology
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    • v.13 no.1 s.36
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    • pp.79-84
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    • 2007
  • Separation of ethylene from ethane and propylene from propane have been conducted using facilitated olefin transport membrane with SPEEK-Ag (Ag substituted sulfonated poly(ether ether ketone)). SPEEK was prepared by the sulfonation of PEEK using cone. $H_2SO_4$ and the reaction time affected the degree of sulfonation (DS) of the resulting SPEEK. SPEEK-Ag composite membrane was formed by soaking SPEEK in the polyester support into the Ag salt solution. With increasing the concentration of SPEEK in MeOH, the thickness of SPEEK on the polyester increased. The selectivity and the flux of SPEEK-Ag membrane for the separation of ethylene/ethane and propylene/propane were changed by the thickness of SPEEK layer on the top of polyester support. The anion of silver salt also affects the membrane performance.

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