• Title/Summary/Keyword: silver oxide

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Electrochemical Behaviors of Polycrystalline Silver Electrodes in 8M KOH Solutions Containing Bi2O3 (Bi2O3를 첨가한 8M KOH용액에서 다결정 Ag전극의 전기화학적 거동)

  • Hur, Tae-Uk;Kong, Yeong-Kyung;Chung, Won-Sub
    • Journal of the Korean Electrochemical Society
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    • v.8 no.1
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    • pp.17-23
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    • 2005
  • The electrochemical behaviors of polycrystalline silver electrodes in 8M KOH solutions containing $Bi_2O_3$ were studied under various conditions by cyclic voltammetry, potentiostatic and galvanostatic techniques as well as the morphology of the silver oxide structures by SEM. It was found that three new compounds comprising silver, bismuth, and oxygen as well as $Bi_2O_3$, $Ag_2O$ and AgO were formed during the electrochemical oxidation of silver. In addition, the potentiostatic current transients were characterized by the appearances of the first current peaks corresponding to the formation of silver oxides, and the second current peaks corresponding to the Ag-Bi-O compounds, indicating the presence of the nucleation and 3D growth mechanism, in the potential regions of $Ag_2O$ and AgO, respectively. Microscopic examinations showed that two types of silver (I) oxide morphologies are formed in the potential region of $Ag_2O$.

CAPACITY ANALYSIS OF THE SILVER OXIDE-ZINC CELL (PHASE 2)

  • 이완구
    • Journal of the Korean Professional Engineers Association
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    • v.15 no.1
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    • pp.36-40
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    • 1982
  • This study is to characterize Ago stability useful for manufacturing silver oxide button cell, and deter mined by test tube gassing evaluations and by cell expansion and further discuss en the effectiveness of pellet reduction treatments to obtain single plateau discharge Profile and relevent performance.

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Fabrications of Silver Nanowire/NiO Based High Thermal-Resistance Hybrid Transparent Electrode (은나노선/Ni 산화물 고내열성 하이브리드 투명전극의 형성)

  • Jung, Sunghoon;Lee, Seunghun;Kim, Do-Geun
    • Journal of the Korean institute of surface engineering
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    • v.50 no.6
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    • pp.486-491
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    • 2017
  • Silver nanowire (AgNW) transparent electrode is one of next generations of flexible and transparent electrode. The electrode shows high conductivity and high transparency comparable to ITO. However, the electrode is weak against heat. The wires are separated into nanodots at temperature above $200^{\circ}C$. It causes the electrical resistance increase. Moreover, it is vulnerable to oxygen and moisture in the atmosphere. The improvement of thermal and moisture resistance of silver nanowire transparent electrode is the most important for commercializing. We proposed silver nanowires transparent electrode which is capped with very thin nickel oxide layer. The nickel oxide layer is five nanometers of thickness, but the heat and moisture resistance of the transparent electrode is effectively improved. The AgNW/NiO electrode can endure at $300^{\circ}C$ of temperature for 30 minutes, and resistance is not increased for 180 hours at $85^{\circ}C$ of temperature and 85% of relative humidity. We showed an applications of transparent and flexible heater using the electrode, the heater is operated more than $180^{\circ}C$ of temperature.

Effect of the Oxide Glass on the Metal Sintering Behavior in Silver Thick-Film System

  • Chung Young Sir;Kim Ho-Gi
    • Proceedings of the Korean Ceranic Society Conference
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    • 1986.12a
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    • pp.259-267
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    • 1986
  • The sintering behavior of silver-oxide glass composite thick-film has been studied with varing glass content. It is shown that during heat treatment glass became liquid phase to deeply affect the microstructure development of the silver particles and to control the physical properties of the thick-films. As glass content increased, the initial repacking of silver particles took place rapidly but the homogeneities of the microstructure showed different features. When the glass content was over some range, the silver particles exuded glass to decrease net energy and glass formed liquid pools separated from the solid skeletons. Finally the relations between the microstructures and electrical properties of the thick-film were discussed.

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Effect of silver oxide additions on YBCO thick film properties

  • Soh, Dea-Wha;Li, Ying-Mei;Cho, Yong-Joon;Korobova, N.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.81-84
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    • 2001
  • The effect of silver oxide (14 wt.%) addition to YBCO compounds and electrophoretic deposition of composite particles prepared by solid phase reaction have been investigated. The results were compared with those for as-processed samples with YBCO films on Ag wire substrate. Our experiments show that the adhesion, microstructure changes, superconducting properties of these films is sensitive to the silver content and sintering conditions. Adding a small amount of PEG tends to remove cracks in the YBCO and (YBCO + Ag) films, which develop during the heating process. An attempt has been made to explain the experimental observations regarding variation of critical current density with the YBCO and (YBCO + Ag) films.

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Effect of silver oxide additions on YBCO thick film properties

  • Soh, Dea-Wha;Li, Ying-Mei;Cho,Yong-Joon;N., Korobova
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.81-84
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    • 2001
  • The effect of silver oxide (14 wt.%) addition to YBCO compounds and electrophoretic deposition of composite particles prepared by solid phase reaction have been investigated. The results were compared with those for as-processed samples with YBCO films on Ag wire substrate. Our experiments show that the adhesion, microstructure changes, superconducting properties of these films is sensitive to the silver content and sintering conditions. Adding a small amount of PEG tends to remove cracks in the YBCO and (YBCO + Ag) films, which develop during the heating process. An attempt has been made to explain the experimental observations regarding variation of critical current density with the YBCO and (YBCO + Ag) films.

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Simple Preparation of One-dimensional Metal Selenide Nanomaterials Using Anodic Aluminum Oxide Template

  • Piao, Yuanzhe
    • Journal of Electrochemical Science and Technology
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    • v.3 no.1
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    • pp.35-43
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    • 2012
  • Highly ordered and perforated anodic aluminum oxide membranes were prepared by anodic oxidation and subsequent removal of the barrier layer. By using these homemade anodic aluminum oxide membranes as templates, metal selenide nanowires and nanotubes were synthesized. The structure and composition of these one-dimensional nanomaterials were studied by field emission scanning electron microscopy as well as transmission electron microscopy and energy dispersive X-ray spectroscopy. The growth process of metal selenide inside anodic aluminum oxide channel was traced by investigating the series of samples using scanning electron microscopy after reacting for different times. Straight and dense copper selenide and silver selenide nanowires with a uniform diameter were successfully prepared. In case of nickel selenide, nanotubes were preferentially formed. Phase and crystallinity of the nanostructured materials were also investigated.

The Generation Mechanism of Radical in the Silver-ion-fluted Aqueous Solution from A-type Zeolite Supporting Silver tons and Its Applications (은 이온교환 A 형 제오라이트에 의한 라디칼 발생메카니츰과 그 응용에 관한 연구)

  • 임경천;구경완;황재효;오상묵;타가사키유케
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.142-145
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    • 1999
  • We confirm that when A-type zeolite supporting silver lone is placed in ion-exchanged distilled water, silver ions is eluted and eluted silver ions generates hydroxyl-radical (.OH) and hydro-radical (.H) continuously, the amount of those is proportion to the silver-ion concentration. Hydroxyl-radical is not generated by super-oxide anion-radical (.O2) but by directly dissolved water. To know such a above discussed mechanism, we prepare A-type zeolite supporting silver ions, and measure the amount of the eluted silver tons by atomic absorption spectroscopy and the generated radical by ESR The radical generated by A-type zeolite supporting silver ions is discussed in the application of elecrical and electronic materials.

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Synthesis of 1,2-Benzothiazine Derivatives as Oxicam Family (옥시캄 계열의 1,2-벤조티아진 유도체의 합성)

  • Park, Myung-Sook
    • YAKHAK HOEJI
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    • v.44 no.6
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    • pp.494-498
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    • 2000
  • Noble 7,7'-substituted (or unsubstituted) 4-oxo-1,1',2,2'-dibenzothiazine-3,3'-dicarboxylic acid methyl ester 1,1,1',1'-tetraoxide 3,4'-yl ethers 2a-h were synthesized through the dehydration of 7-substituted (or unsubstituted) 4-hydroxy-1,2-benzothiazine-3-carboxylic acid methyl ester 1,1-dioxides 1a-h using silver(I) oxide for the development of new nonsteroidal antiinflammatory drugs (NSAIDs). Optimal reaction was proceeded through stirring of distilled acetone using 100 mol% of silver(I) oxide at room temperature for 24-68 hrs.

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