• Title/Summary/Keyword: silica composite

검색결과 396건 처리시간 0.022초

SO3를 다량 함유한 폐석고보드 미분말을 첨가한 3성분계 무기결합재의 길이변화 특성 (The Length Change Characteristic of the Ternary System Inorganic Composites adding the Waste Gypsum Board Micro Powder containing SO3 the great quantity)

  • 김윤미;박종필;이상수;송하영
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2012년도 추계 학술논문 발표대회
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    • pp.65-66
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    • 2012
  • The cement used in the construction industry of the manufacturing process, large amounts of the greenhouse gas, CO2 and is currently being studied for cement substitutes that reduce greenhouse gas issue. Therefore, the this study as a replacement for cement industrial by-product of blast furnace slag, red mud, silica fume and alkali-activator, using only inorganic composites without high-temperature calcination process were manufactured. The waste gypsum board micro powder added to compensate for the shrinkage cracks, the compressive strength and flow, and length change characteristics were investigated. Consequently, The setting time was shortened as GB added And liquidity was reduced. GB 2%, 7 days curing the added strength of specimens was the highest. Came out, and change the length of the Plain least.

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ICP 장치를 이용한 초전도 자속 흐름 트랜지스터의 링크 제작 (Fabrication of the Superconducting Flux Flow Transistor Using the ICP Etching Method)

  • 강형곤;임연호;임성훈;최효상;한윤봉;한병성
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제50권10호
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    • pp.494-499
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    • 2001
  • The effects of accelerated Ultraviolet (UV) radiation on High temperature vulcanized (HTV), Room temperature vulcanized (RTV) silicone rubber and two types of ethylene propylene diene terpolymer (EPDM) used for composite insulator were investigated by hydrophobicity class (HC), surface voltage decay after corona charging, SEM-ES, FTIR and XPS. The contact angle in two kinds of silicone rubber was scarcely change, but EPDM occurred to the loss of hydrophobicity followed by surface cracking and chalking. The surface voltage decay on UV-treated silicone rubber and EPDM showed a different decay trend with UV treatment. EDS and XPS analysis indicated that the oxygen content increased with UV treatment time in all samples. For silicone rubber, the oxidized groups of inorganic silica-like structure increased with UV treatment time. The oxidized carbon of C=O, O=C-O in EPDM increased. These oxidized surface for each material had different electrostatic characteristics, so deposited charges were expected to have different impacts on their surface hydrophobicity. The degradation mechanism based on our results was discussed.

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Light and Electron Microscopic Characterization of Husk from Korean Rice

  • Adya P. Singh;Park, Byung-Dae;Wi, Seung-Gon;Lee, Kwang-Ho;Yoon, Tae-Ho;Kim, Yoon-Soo
    • Plant Resources
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    • 제5권2호
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    • pp.95-103
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    • 2002
  • Microscopic techniques were used to observe the microstructure of rice husk. Microscopic examination showed that two main components of husk, lemma and palea consisted of outer epidermis, layers of fibers, vascular bundles, parenchyma cells, and inner epidermis, in sequence from the outer to the inner surface. The outer epidermal walls were extremely thick, highly convoluted and lignified. The underlying fibers were also thick-walled and lignified. Parenchyma cells were thin-walled and unlignified. Inner epidermal cells were also unlignified. The outer surface of both lemma and palea were conspicuously ridged, but the lower surface had a flat appearance. As part of a detailed study to characterize rice husk using microscopic and micro-analytical techniques, distribution of silica was also examined, and is presented elsewhere. Rice husk can potentially be used as a raw material for making composite products and the observations presented here form valuable background information for our future work related to product development.

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전바나듐계 레독스플로우전지용 집전체에 대한 연구 (Study on Current Collector for All Vanadium Redox Flow Battery)

  • 최호상;황갑진;김재철;유철휘
    • 한국수소및신에너지학회논문집
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    • 제22권2호
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    • pp.240-248
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    • 2011
  • All-vanadium redox flow battery (VRFB) has been studied actively as one of the most promising electrochemical energy storage systems for a wide range of applications such as electric vehicles, photovoltaic arrays, and excess power generated by electric power plants at night time. Among consisting elements of the VRFB, the ion exchange membrane and the electrode play important roles. In this study, carbon PVC coposite sheets for the VRFB have been developed and electrochemical characteristics investigated. Current collector for VRFB, carbon PVC composite sheets (CPCS), were prepared with G-1028 as a conducting particle, PVC as a polymer, Dibutyl phthalate (DBP) as a plasticizer and fumed Silica (FS) as a dispersion agent. CPCS has been shown to have the characteristics as an excellent current collector for VRFB and electrochemical properties of specific resistivity 0.31 ${\Omega}cm$, which were composed of G-1028 80 wt%, PVC 10 wt%, DBP 5 wt% and FS 5 wt%.

Repair bond strengths of non-aged and aged resin nanoceramics

  • Subasi, Meryem Gulce;Alp, Gulce
    • The Journal of Advanced Prosthodontics
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    • 제9권5호
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    • pp.364-370
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    • 2017
  • PURPOSE. To explore the influence of different surface conditionings on surface changes and the influence of surface treatments and aging on the bond strengths of composites to non-aged and aged resin nanoceramics. MATERIALS AND METHODS. Rectangular-shaped non-aged and aged (5000 thermocycles) resin nanoceramic specimens (Lava Ultimate) (n=63, each) were divided into 3 groups according to surface treatments (untreated, air abrasion, or silica coating) (n=21). The surface roughness was measured and scanning electron microscopy was used to examine one specimen from each group. Afterwards, the specimens were repaired with a composite resin (Filtek Z550) and half were sent for aging (5000 thermocycles, n=10, each). Shear bond strengths and failure types were evaluated. Roughness and bond strength were investigated by two- and three-way analysis of variance, respectively. The correlation between the roughness and bond strength was investigated by Pearson's correlation test. RESULTS. Surface-treated samples had higher roughness compared with the untreated specimens (P=.000). For the non-aged resin nanoceramic groups, aging was a significant factor for bond strength; for the aged resin nanoceramic groups, surface treatment and aging were significant factors. The failures were mostly adhesive after thermal cycling, except in the non-aged untreated group and the aged air-abraded group, which had mostly mixed failures. Roughness and bond strength were positively correlated (P=.003). CONCLUSION. Surface treatment is not required for the repair of non-aged resin nanoceramic; for the repair of aged resin nanoceramic restorations, air abrasion is recommended.

나노/마이크로 에폭시 복합체의 전기적, 열적특성 분석 (Analysis of electrical, thermal characteristic of Nano/Micro Epoxy composite)

  • 정의환;윤재훈;임기조;정수현
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.99-99
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    • 2010
  • Polymer nanocomposite has been attracting much attention as a new insulation material, since homogeneous dispersion of nm-sized inorganic fillers can improve various properties significantly. In this paper, various kinds of epoxy based nanocomposites were made and AC breakdown strength of Nano-TiO2 and micro-silica filler mixture of epoxy based composites were studied by sphere to sphere electrode. Moreover, nano- and micro-filler combinations were adopted as an approach toward practical application of nanocomposite insulation materials. Nano-TiO2 particle size is about 10nm and composites ratio was resin (100) : hardener (82) : accelerator (1.5). AC breakdown test was performed at room temperature (25 [$^{\circ}C$], 80 [$^{\circ}C$] and 100 [$^{\circ}C$] in the vicinity of Tg (90[$^{\circ}C$]). And thermal conductivity were measured by ASTM-D5470.

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Capacity and the moment-curvature relationship of high-strength concrete filled steel tube columns under eccentric loads

  • Lee, Seung-Jo
    • Steel and Composite Structures
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    • 제7권2호
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    • pp.135-160
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    • 2007
  • Recently, CFT column has been well-studied and reported on, because a CFT column has certain superior structural properties as well as good productivity, execution efficiency, and improved rigidity over existing columns. However, CFT column still has problems clearing the capacity evaluation between its steel tube member and high-strength concrete materials. Also, research on concrete has examined numerical values for high-strength concrete filled steel square tube columns (HCFT) to explain transformation performance (M-${\phi}$) when a short-column receives equal flexure-moment from axial stress. Moment-curvature formulas are proposed for HCFT columns based on analytic assumption described in this paper. This study investigated structural properties (capacity, curvature), through a series of experiments for HCFT with key parameters, such as strength of concrete mixed design (58.8 MPa), width-thickness ratio (D/t), buckling length to sectional width ratio (Lk/D) and concrete types (Zeolite, Fly-ash, Silica-fume) under eccentric loads. A comparative analysis executed for the AISC-LRFD, AIJ and Takanori Sato, etc. Design formulas to estimate the axial load (N)-moment (M)-curvature (${\phi}$) are proposed for HCFT columns based on tests results described in this paper.

A software-assisted comparative assessment of the effect of cement type on concrete carbonation and chloride ingress

  • Demis, S.;Papadakis, V.G.
    • Computers and Concrete
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    • 제10권4호
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    • pp.391-407
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    • 2012
  • Utilization of supplementary cementing materials (SCM) by the cement industry, as a highly promising solution of sustainable cement development aiming to reduce carbon dioxide emissions, necessitates a more thorough evaluation of these types of materials on concrete durability. In this study a comparative assessment of the effect of SCM on concrete durability, of every cement type as defined in the European Standard EN 197-1 is taking place, using a software tool, based on proven predictive models (according to performance-related methods for assessing durability) developed and wide-validated for the estimation of concrete service life when designing for durability under harsh environments. The effect of Type II additives (fly ash, silica fume) on CEM I type of cement, as well as the effect of every Portland-composite type of cement (and others) are evaluated in terms of their performance in carbonation and chloride exposure, for a service life of 50 years. The main aim is to portray a unified and comprehensive evaluation of the efficiency of SCM in order to create the basis for future consideration of more types of cement to enter the production line in industry.

해수담수화용 폴리아마이드 기반 나노복합막의 최신 연구동향 (Current Research Trends in Polyamide Based Nanocomposite Membranes for Desalination)

  • 이태훈;이희대;박호범
    • 멤브레인
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    • 제26권5호
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    • pp.351-364
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    • 2016
  • 최근 폴리아마이드 선택층에 나노물질을 혼합하여 해수담수화 성능을 높이고자 하는 연구가 활발히 이루어지고 있다. 본 총설은 역삼투 분리막 해수담수화 공정에서의 에너지 효율 향상을 위한 우수한 성능을 가진 폴리아마이드 기반 나노복합막을 소개하고자 한다. 그래핀 옥사이드 및 탄소나노튜브와 같은 탄소나노물질 및 제올라이트, 실리카 나노입자 등의 다양한 나노물질들이 기존 폴리아마이드의 투과분리성능을 높이기 위해 적용되고 있다. 본 총설에서는 최근 연구 중인 각 나노소재별 성능향상 특장점을 소개하고, 더 높은 성능을 갖는 나노복합막 제조를 위한 연구방향을 제시하고자 한다.

Evaluation of interaction between organic solutes and a membrane polymer by an inverse HPLC method

  • Kiso, Yoshiaki;Hosogi, Katsuya;Kamimoto, Yuki;Jung, Yong-Jun
    • Membrane and Water Treatment
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    • 제5권3호
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    • pp.171-182
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    • 2014
  • Organic compounds are adsorbed on RO/NF membranes, and the adsorption may influence the rejection of organic compounds by the membranes. Because almost RO/NF membranes are composite membranes, the results obtained by adsorption experiment with using membrane pieces are unable to avoid the influence by the support membrane. In this work, the interaction between membrane polymer and organic solutes was examined by an inverse HPLC methodology. Poly (m-phenylenetrimesoylate), the constituent of skin layer of RO/NF membranes, was coated on silica gel particles and used as a stationary phase for HPLC. When water was used as a mobile phase, almost hydrophilic aliphatic compounds were not effectively adsorbed on the stationary phase, although hydrophobic compounds were slightly adsorbed. The results indicated that the hydrophilic aliphatic compounds are useful probe solutes to examine the molecular sieving effect of a membrane. When water was used as a mobile phase, the aromatic compounds were strongly retained, and therefore $CH_3CN/H_2O$ (30/70) was used as a mobile phase. It was revealed that the adsorption of aromatic compounds was controlled by stacking between solute and polymer and was hindered by non-planar structure and substituents.