• Title/Summary/Keyword: silica coating

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Effect of Hydrophobic Surface Coating on Flowability of Ceramic Tile Granule Powders (표면 소수화 처리를 통한 도자타일 과립 분말의 유동 특성)

  • Kim, Jin-Ho;Kim, Ung-Soo;Han, Kyu-Sung;Hwang, Kwang-Take
    • Korean Journal of Materials Research
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    • v.29 no.7
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    • pp.425-431
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    • 2019
  • Generally, ceramic tiles for building construction are manufactured by dry forming process using granular powders prepared by spray drying process after mixing and grinding of mineral raw materials. In recent years, as the demand for large ceramic tiles with natural texture has increased, the development of granule powders with high packing ratio and excellent flowability has become more important. In this study, ceramic tile granule powders are coated with hydrophobically treated silica nanoparticles. The effects of hydrophobic silica coating on the flowability of granule powders and the strength of the green body are investigated in detail. Silica nanoparticles are hydrophobically treated with GPTMS(3-glycidoxypropyl trimethoxy silane), which is an epoxy-based silane coupling agent. As the coating concentration increases, the angle of repose and the compressibility decrease. The tap density and flowability index increase after silica coating treatment. These results indicate that hydrophobic treatment can improve the flowability of the granular powder, and prevent cracking of green body at high pressure molding.

Tailoring of the Chemical Resistance of Chrome Yellow Particles by Silica Coating (안료의 내약품성 향상을 위한 황연입자의 실리카 피복에 관한 연구)

  • Lee, Seewoo;Kim, Seongsoo;Kim, Dong-Uk;Wang, Lin;Choi, Heekyu
    • Applied Chemistry for Engineering
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    • v.19 no.3
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    • pp.310-315
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    • 2008
  • Herein, we synthesized silica-coated chrome yellow particles having improved chemical resistance. The intermediate with a good dispersion stability was prepared and the chemical resistance of the final product was investigated. The effects of pH and temperature, as the main parameters influencing the formation of particles, the reduced particle size by homogenizer on the silica coating were investigated. The change in the particle morphology by temperature and pH was also studied. As the results, small and monodisperse particles were achieved at low pH and high temperature. Good silica coating was obtained when used reduced size of the particles by homogenizer. Furthermore, the sufficient silica coating by microencapsulation was obtained at 9~10 pH and the temperature above $90^{\circ}C$.

Ce:YAG remote phosphor coating for white LED with silica sol binder (Silica sol 바인더를 적용한 백색 LED용 Ce:YAG remote 형광체 코팅)

  • Gim, Su Jin;Park, Ha Na;Choi, Jae Ho;Jung, Yoon Sung;Kim, Hyeong-Jun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.5
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    • pp.212-217
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    • 2021
  • The applicability of the white LED from the blue LED of the coating film as a binder for surface and curved coatings were confirmed. The particle size of YAG is D50: 9~10 ㎛, and the crystal structure is garnet (Y3Al5O12), cubic. The coating film had no cracks, at the same time, the silica sol was uniformly coated with YAG phosphor, and the YAG content and thickness in the coating film showed a tendency to increase up to 40 ㎛ in proportion to the increase in the amount added. Furthermore, as the YAG content increased, the PL emission intensity increased and the color coordinate shift toward the end of the chromatic locus curve was confirmed.

The Control of Electrostatic Characteristics in Toner Type Paper-like Display

  • Lee, Sung-Guk;Kwon, Soon-Hyung;Cho, Won-Ki;Song, Moon-Bong;Kim, Young-Woon
    • Journal of Information Display
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    • v.8 no.1
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    • pp.14-17
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    • 2007
  • The toner type paper-like display (PLD) has been developed with two polymer particles having opposite polarity composed of polymer, colorant and external additives (nano-sized silica). Nano-sized silica with triboelectric charge was used for the charge control agent (CCA) and influenced on the electrostatic properties of the silica-coated polymer particles. The surface morphology and the cohesiveness of silica-coated polymer particles were changed with the silica coating time. From these results, it was verified that the PLD cell using silica-coated particles (200 seconds) shows a good white appearance and low driving voltage.

Development of Ceramic Composite Membranes for Gas Separation: V. Synthesis of Nanoparticulate Silica Membranes by the Pressurized Sol-Gel Coating Technique (기체분리용 세라믹 복합분리막의 개발 : V. 가압 졸-겔 코팅법에 의한 rrmaltp입자 실리카 막의 합성)

  • 현상훈;윤성필;김준학
    • Journal of the Korean Ceramic Society
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    • v.30 no.3
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    • pp.189-198
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    • 1993
  • A new pressurized sol-gel coating technique forming membrane layers inside pores of the porous support by the simple operation has been developed. Crack-free and reproducible nanoparticulate silica membranes supported on the porous $\alpha$-alumina tube are synthesized by pressurized coating at 600kPa for 2hr. The pore radius and N2 gas permiability at the room temperature of silica membrane layers are 8$\AA$ and 7.0$\times$10-7mol/$m^2$.s.Pa, respectively. The mechanism of N2 gas transfer through synthesized membrane layers is the perfect Knudeen flow, and the thermal stability of the silica composite membranes is excellent upto 40$0^{\circ}C$.

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Ambient Pressure Dried Silica Aerogel Thin Film from Water Glass

  • Cha, Young-Chul;Yoon, Jong-Seol;Lee, Jun;Hwang, Hae-Jin;Moon, Ji-Woong
    • Journal of the Korean Ceramic Society
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    • v.45 no.2
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    • pp.87-89
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    • 2008
  • A nano structured silica aerogel thin film was manufactured from inexpensive sodium silicate (water glass) using an ambient pressure drying method. High purity silicic sol was prepared by passing a water glass solution through an ion exchange resin, and the gel films were prepared on a modified glass substrate via dip coating. The dip coating conditions, such as coating time and solvent, were optimized. The optical and physical properties of the obtained silica aerogel thin film were characterized using a UV-visable spectrometer and a scanning electron microscope.

Convective Deposition of Silica Nano-Colloidal Particles and Preparation of Anti-Reflective Film by Controlling Refractive Index (콜로이드 실리카 나노입자의 부착에 의한 반사방지막 제조 및 굴절율 조절)

  • Hwang Yeon;Prevo Brian;Velev Orlin
    • Korean Journal of Materials Research
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    • v.15 no.5
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    • pp.285-292
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    • 2005
  • Anti-reflection film was coated by using spherical silica nano colloids. Silica colloid sol was reserved between two inclined slide glasses by capillary force, and particles were convectively stacked to form a film onto the substrate as the water evaporates. As the sliding speed increased, the thickness of the film decreased and the wavelength at the maximum transmittance decreased. The microstructure observed by SEM showed that silica particles were nearly close packed, which enabled the calculation of the effective refractive index of the film. The film thickness was measured by proffer and calculated from the wavelength of maximum transmittance and the effective refractive index. The effective refractive index of the film could be controlled by a subtle controlling of the coating speed and by mixing two different sized silica particles. When the 100 nm and 50 m particles were mixed at 4:1-5:1 volume ratio, the maximum transmittance of $95.2\%$ for one-sided coating was obtained. This is the one that has increased by $3.8\%$ compared to bare glass substrate, and shows that $99.0\%$ of transmittance or $1.0\%$ of reflectance can be achieved by the simple process if both sides of the substrate are coated.

Numerical Study of Secondary Coating Die Geometry Effects on High Speed Optical Glass Fiber Coating Process (광섬유 2차 코팅다이 형상 변화에 따른 유리섬유 고속 코팅공정 영향성 해석연구)

  • Kim, Kyoungjin;Park, Joong-Youn
    • Journal of the Semiconductor & Display Technology
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    • v.18 no.3
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    • pp.12-18
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    • 2019
  • The protective double layer polymer coatings on silica optical fibers are realized by wet-on-wet liquid coating process and they play an important role in final quality of mass produced optical fibers. This numerical study aims to analyze the effects of secondary coating die design parameters by employing two dimensional axisymmetric model of coating cup and coating die geometry and computational fluid dynamics simulations which include temperature dependent viscosity of polymer coating liquids and viscous dissipation heating. Under high speed fiber drawing conditions and pressurized coating liquid supply, the effects of converging die angle are investigated in order to appreciate the change of coating liquid flow patterns such as flow recirculation zone near coating die as well as primary and secondary coating layer thicknesses. The auxiliary coating die to converging coating die is also tested and the results find that this concept is advantageous in achieving stable double layer coatings on silica glass fiber.

Flame Synthesis of Silica-Coated Iron Oxide Nanoparticles and Their Characterization

  • Jun, Kimin;Yang, Sangsun;Lee, Jeonghoon;Pikhitsa, Peter V.;Choi, Mansoo
    • Particle and aerosol research
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    • v.9 no.4
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    • pp.209-219
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    • 2013
  • We have used the modified diffusion flame burner to synthesize silica coated iron oxide nanoparticles having enhanced superparamagnetic property. Silica-encapsulated iron oxide particles were directly observed using a high resolution transmission electron microscope. From the energy dispersive X-ray spectroscopy (EDS) and zeta potential measurements, the iron oxide particles were found to be completely covered by a silica coating layer. X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) measurements revealed that the iron oxide core consists of ${\gamma}-Fe_2O_3$ rather than ${\alpha}-Fe_2O_3$. Our magnetization measurements support this conclusion. Biocompatibility test of the silica-coated iron oxide nanoparticles is also conducted using the protein adsorption onto the coated particle.