• 공업화학
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• 제20권4호
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• pp.437-442
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• 2009

$TiO_2$, $Al_2O_3$를 담체로 한 Pt계 촉매에서 NOx, soot의 동시 제거 반응과 촉매의 열충격에 대한 연구를 수행하였다. 실험은 NOx와 soot의 반응을 독립 또는 동시에 반응시킨 조건으로 수행하였으며 그 결과 담체의 종류 및 상에 따라서 서로 상이한 NOx 제거능력과 soot 산화력을 나타내었고, soot의 산화시작온도의 결정은 NOx 제거능력과 상관관계가 있었다. NOx, soot의 동시 반응 시에는 생성된 $NO_2$에 의하여 soot 산화시작온도가 저온으로 이동하였다. 또한 열충격에 대한 NOx 제거율은 Pt/$Al_2O_3$ 촉매가 Pt/$TiO_2$ 촉매에 비하여 효율저하가 적게 일어났으며 soot 산화력은 활성점인 Pt의 소결현상에 의하여 촉매에 관계없이 모두 감소하였다.

• Bulletin of the Korean Chemical Society
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• 제22권3호
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• pp.303-307
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• 2001

The ignition of propane was investigated behind reflected shock waves in the temperature range of 1350-1800 K and the pressure range of 0.75-1.57 bar. The ignition delay time was measured from the increase of pressure and OH emission in the C3H8-O2-Ar system. The relationship between the ignition delay time and the concentrations of propane and oxygen was determined in the form of mass-action expression with an Arrhenius temperature dependence. The numerical calculations were also performed to elucidate the important steps in the reaction scheme of propane ignition using various reaction mechanisms. The ignition delay times calculated from the mechanism of Sung et al.1 were in good agreement with the observed ones.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 1999년도 춘계 학술대회논문집
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• pp.29-34
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• 1999

A two-dimensional Navier-Stokes code based on AUSMPW+ scheme has been developed to simulate the hypersonic flowfield of hypersonic shock-shock interaction. AUSMPW+ scheme is a new hybrid flux splitting scheme, which is improved by introducing pressure-based weight functions to eliminate the typical drawbacks of AUSM-type schemes, such as non-monotone pressure solutions. To study the real gas effects, three different gas models are taken into account in this paper: perfect gas, equilibrium flow and nonequilibrium flow. It has been investigated how each gas model influences on the peak surface loading, such as wall pressure and wall heat transfer, and unsteady flowfield structure in the region of shock-shock interaction. With the results, the value of peak pressure is not sensitive to the real gas effects nor to the wall catalyticity. However, the value of peak heat transfer rates is affected by the real gas effects and the wall catalyticity. The structure of the flowfield also changes drastically in the presence of real gas effects.

• Journal of applied mathematics & informatics
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• 제9권1호
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• pp.1-13
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• 2002

In this paper we present numerical methods fur computations of nonequilibrium hypersonic flow of air around bodies including chemical reaction effects and present numerical result of the flow over concave corners. We developed implicit finite difference method to overcome numerical difficulties with the lack of resolution behind the shock and near the body. Using our method we were able to find details of the flow properties near the shock and body and were able to continue the computation of the flow for a long distance from the corner of the body.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2003년도 제20회 춘계학술대회 논문집
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• pp.32-33
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• 2003

Mechanism of a periodic oscillation of shock-induced combustion over a two- dimensional wedges and axi-symmetric cones were investigated through a series of numerical simulations at off-attaching condition of oblique detonation waves(ODW). A same computational domain over 40 degree half-angle was considered for two-dimensional and axi-symmetric shock-induced combustion phenomena. For two-dimensional shock-induced combustion, a 2H2+02+17N2 mixture was considered at Mach number was 5.85with initial temperature 292 K and initial pressureof 12 KPa. The Rankine-Hugoniot relation has solution of attached waves at this condition. For axi-symmetric shock-induced combustion, a H2+2O2+2Ar mixture was considered at Mach number was 5.0 with initial temperature 288 K and initial pressure of 200 mmHg. The flow conditions were based on the conditions of similar experiments and numerical studies.[1, 3]Numerical simulation was carried out with a compressible fluid dynamics code with a detailed hydrogen-oxygen combustion mechanism.[4, 5] A series of calculations were carried out by changing the fluid dynamic time scale. The length wedge is varied as a simplest way of changing the fluid dynamic time scale. Result reveals that there is a chemical kinetic limit of the detached overdriven detonation wave, in addition to the theoretical limit predicted by Rankine-Hugoniot theory with equilibrium chemistry. At the off-attaching condition of ODW the shock and reaction waves still attach at a wedge as a periodically oscillating oblique shock-induced combustion, if the Rankine-Hugoniot limit of detachment isbut the chemical kinetic limit is not.Mechanism of the periodic oscillation is considered as interactions between shock and reaction waves coupled with chemical kinetic effects. There were various regimes of the periodicmotion depending on the fluid dynamic time scales. The difference between the two-dimensional and axi-symmetric simulations were distinct because the flow path is parallel and uniform behind the oblique shock waves, but is not behind the conical shock waves. The shock-induced combustion behind the conical shockwaves showed much more violent and irregular characteristics.From the investigation of characteristic chemical time, condition of the periodic instability is identified as follows; at the detaching condition of Rankine-Hugoniot theory, (1) flow residence time is smaller than the chemical characteristic time, behind the detached shock wave with heat addition, (2) flow residence time should be greater than the chemical characteristic time, behind an oblique shock wave without heat addition.

• 한국자동차공학회논문집
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• 제14권2호
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• pp.1-8
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• 2006

In this paper, an optimum design technology is developed to find an optimal position of the shock absorber using ADAMS and VisualDOC. A vehicle with a torsion-beam rear suspension is modeled by using ADAMS. Design variables for the optimal positioning of the shock absorber are defined considering the hard points of the chassis structure and design positioning are specified through the sensitivity analysis using a bump-crossing simulation. The objective function is defined as the joint reaction forces of the shock absorber connecting joints of the chassis structure. Sequential Quadratic Programming and Genetic Algorithms are used for this study. To validate the optimized design variables, pothole simulations are performed. GA showed better results than SQP algorithms for this design purpose.

• 소성∙가공
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• 제26권4호
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• pp.216-221
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• 2017

Recently, interest in multifunctional energetic structural materials (MESMs) has grown due to their multifunctional potential, especially in military applications. However, there are few studies about extrinsic factors that govern the reactivity of MESMs. In this paper, a shock compaction process was performed on the nano Ni/Al-mixed powder to investigate the effect of particle size on the shock reaction condition. Additionally, heating the statically compacted specimen was also performed to compare the mechanical properties and microstructure between reacted and unreacted material. The results show that the agglomerated structure of nanopowders interrupts the reaction by reducing the elemental boundary. X-ray diffraction analysis shows that the NiAl and $Ni_3Al$ intermetallics are formed on the reacted specimen. The microhardness results show that the $Ni_3Al$ phase has a higher hardness than NiAl, but the portion of $Ni_3Al$ in the reacted specimen is minor. In conclusion, using Ni/Al composites as a reactive material should focus on energetic use.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1084-1085
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• 2006

We studied formation of nanostructured $TiB_2$-Cu composites under shock wave conditions. We investigated the influence of preliminary mechanical activation (MA) of Ti-B-Cu powder mixtures on the peculiarities of the reaction between Ti and B under shock wave. In the MA-ed mixture the reaction proceeded completely while in the non-activated mixture the reagents remained along with the product . titanium diboride. The size of titanium diboride particles in the central part of the compact was 100-300 nm.

• 한국안전학회지
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• 제17권3호
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• pp.61-65
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• 2002

A study on the characteristics of electric shock in fresh water due to the leakage of submerged electric facility is conducted by using a reduced scale model at a scale of 1:10 in laboratory. Electric potential as a function of distance from leakage source, type of the leakage source, magnitude of the source voltage, submerged depth and diameter of a copper rod electrode is measured. On the basis of safety standard, separation for guarantee of safety is determined by the measured potential. Also supposing that body resistance is 500［$\Omega$］, the human reaction was estimated by calculating body current for some shock duration. Thus, in this paper, the hazard of the electric shock is assessed by introducing representative safety factors, body voltage and body current due to leakage source.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 1998년도 춘계 학술대회논문집
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• pp.1-14
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• 1998

Underwater explosion properties for TNT, an ideal explosive, and DXD-04, a nonideal explosive, were numerically modeled with a one-dimensional Lagrangian hydrodynamic code. The equation of state parameters for detonation products for TNT and DXD-04 were obtained from the BKW code, assuming complete reaction. Burn of TNT was modeled by using the Chapman-Jouguet(CJ) volume burn technique, a programmed-burn technique, assuming instantaneous detonation reaction. Burn of DXD-04 was modeled by using the same technique and by using the reaction rate calibrated from two-dimensional steady-state detonation experiments. The calculations for TNT reproduced the experimental peak pressure of the shock wave propagating through water with an error of $3.0\%$ and the experimental oscillation period of the bubble formed of detonation products with an error of $2.3\%$. For DXD-04, the CJ volume burn technique could not reproduce the experimental observations. When the reaction rate calibrated from two-dimensional steady-state detonation experimental data, the calculated peak pressure was slightly higher by $7.3\%$ than the experimental data, but the calculated shock profile was in good agreement. The bubble period was reproduced with an error of $1.8\%$. These results demonstrated that underwater explosion properties for an ideal explosive can be predicted by using a programmed burn technique, and that, however, those for a nonideal explosive can be predicted only when a well-calibrated reaction rate is used.