• 공업화학
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• 제29권6호
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• pp.782-788
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• 2018

서브 미크론 구리-은 코어-쉘 Cu@Ag 입자를 초음파화학과 결합된 금속교환 반응으로 합성하고 인쇄용 전자부품을 위한 저렴한 전도성 페이스트 적용을 평가하였다. 코어-쉘의 합성을 위한 반응에서 코어로 사용된 $Cu_2O/Cu$ 복합체의 $Cu_2O$는 초음파화학 반응으로 Cu로 환원되고 Cu 원자는 Ag의 금속교환 반응의 환원제로 작용하여 코어 표면에 Ag가 코팅된 코어-쉘 구조를 얻었다. TEM-EDS와 TG-DSC를 이용하여 서브 미크론 입자의 코어-쉘 구조를 확인하였다. 70 wt% Cu@Ag를 용매에 분산시킨 전도성 페이스트를 결합제와 습윤제를 사용하여 제조하고, 스크린 인쇄법을 사용하여 폴리아미드 필름상에 코팅하였다. Ag 함량이 8 at%와 16 at%인 Cu@Ag 입자를 함유하는 인쇄된 페이스트 필름은 공기 중의 $180^{\circ}C$에서 소결한 후 각각 96.2와 $38.4{\mu}{\Omega}cm$의 낮은 비저항 값을 나타내었다.

• 전기학회논문지
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• 제60권5호
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• pp.1055-1061
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• 2011

In this study, main parameters: aperture, first bend and second bend which express a structure of ear canal are extracted in order to modeling and manufacture the ready-made ear shells of hearing aids. The proposed parameter extraction method consists of 2 important algorithms, aperture detection and feature detection. In the aperture detection algorithm, aperture of 3-D scanned virtual ear impression and parameters relating to ear shell of hearing aid are determined. The feature detection algorithm detects first bend, second bend, and related parameters. Through these two algorithms, parameters for aperture, first bend, and second bend are extracted to model the ready-made ear shell of hearing aid. The values of these extracted parameters from 36 people's right ear impression are analyzed and measured statistically. As a result of the analysis, it has been found that it is possible to classify ready-made ear shell parameters by age and size. The ready-made ear shell parameters are classified 3-size for 20 years old and 2-size for 60 years olde. Using 3D rhino program, virtual ready-made ear shell is reconstructed by parameters of every type, and simulated to model it. A final product was produced by transferring simulation result with rapid prototyping system. The modeled ready-made ear shell is evaluated with the objective and subjective method. Objective method is the comparison volume ratio and overlapped volume ratio of ear impression from randomly chosen 18 people and ready-made ear shell. And subjective method is that the final product of ready-made ear shell is used by users and the satisfaction number drawn from well fitting and comfortable testing was evaluated. In the result of the evaluation, it has been found that volume ration is 70%, big and middle size ready-made ear shell products are possible, and the satisfaction number is high.

• 소성∙가공
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• 제9권3호
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• pp.274-283
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• 2000

A dynamic explicit finite element code for simulating sheet forming processes has been developed. The code utilizes the discrete Kirchhoff shell element and contact force is treated by a conventional penalty method. In order to reduce the computational cost, a new and robust contact searching algorithm has been developed and implemented into the code. In the method, a hierarchical structure of tool segments is built for each tool at the initial stage of the analysis. hierarchical structure is built in a way to divide a box to 8 sub-boxes, 2 in each direction, until the lowest level of the hierarchical structure contains exactly one segment of the tool or empty. Then at each time step, contact is checked from the box to sub-boxes hierarchically for each node. Comparisons of computational results of various examples with the existing ones show the validity of the method.

• Steel and Composite Structures
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• 제28권3호
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• pp.381-388
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• 2018

In this paper, forced vibration of micro cylindrical shell reinforced by functionally graded carbon nanotubes (FG-CNTs) is presented. The structure is subjected to transverse harmonic load and modeled by beam model. The size effects are considered based on strain gradient theory containing three small scale parameters. The mixture rule is used for obtaining the effective material properties of the structure. Based on sinusoidal shear deformation theory of beam, energy method and Hamilton's principle, the motion equations are derived. Applying differential quadrature method (DQM) and Newmark method, the frequency curves of the structure are plotted. The effect of different parameters including, CNTs volume percent and distribution type, boundary conditions, size effect and length to thickness ratio on the frequency curves of the structure is studied. Numerical results indicate that the dynamic deflection of the FGX-CNT-reinforced cylindrical is lower with respect to other type of CNT distribution.

• Structural Engineering and Mechanics
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• 제91권3호
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• pp.325-334
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• 2024

This paper deals with the dynamic buckling behavior of truncated conical shells composed of carbon nanotube composites, an important area of study in view of their very wide engineering applications in aerospace industries. In this regard, the effective material properties of the nanocomposite have been computed using the Mori-Tanaka model, which has already been established for such analyses. The motion equations ruling the structure's behavior are derived using first order shear deformation theory, Hamilton's principle, and energy method. This will provide adequate background information on its dynamic response. In an effort to probe the dynamic instability region of the structure, differential quadrature method combined with Bolotin's method will be adopted to tackle the resulting motion equations, which enables efficient and accurate analysis. This work considers the effect of various parameters in the geometrical parameters and the volume fraction of CNTs on the structure's DIR. Specifically, it became clear that increasing the volume fraction of CNTs shifted the frequency range of the DIR to higher values, indicating the significant role of nanocomposite composition regarding structure stability.

• 전기학회논문지
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• 제61권1호
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• pp.85-88
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• 2012

DSCs are based on a dye-adsorbed porous $TiO_2$ layer as a photo electrode [1]. Under the illumination, dye molecules are excited and electrons are produced. The injected electrons in the conduction band of $TiO_2$ may recombine with the electrolyte. To obtain high performance DSCs, it is essential to retard the recombination. The charge recombination can be reduced by forming core-shell structure. In this work, we investigated the core-shell structure with $Al_2O_3$ and MgO coating layer on the porous $TiO_2$ layer. We confirmed the photovoltaic properties by I-V characteristics. The current and the efficiency was improved. In addition to, Through decrease in the width of EIS arc, which is the sum of the interfacial charge transfer resistances of both electrodes, we can be indicated that the block effect.

• Advances in aircraft and spacecraft science
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• 제10권2호
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• pp.127-140
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• 2023

The present article focuses on the thermoelastic deformation behavior of inhomogeneous functionally graded metal/ceramic cylindrical shell structure with multiple perforations using 2D finite element approximation. Here, cylindrical shell structure is considered with single (1×1) and multiple (2×2, 3×3 and 4×4) perforations. The temperature-dependent elastic and thermal properties of functionally graded material are evaluated using Voigt's micromechanical material scheme via power-law function. The kinematics of the proposed model is based on the equivalent single-layer first-order shear deformation mid-plane theory with five degrees-of-freedom. Here, 2D isoparametric finite element solutions are obtained using eight-node quadrilateral elements. The mesh refinement of present finite element model is performed to confirm the appropriate number of elements and nodes for the analysis purpose. Subsequently, a comparison test is conducted to demonstrate the accuracy of present results. In later section, numerous numerical illustrations are demonstrated at different set of conditions by varying structural, material and loading parameters and that confirms the significance of various parameters such as power-law index, aspect ratio, thickness ratio, curvature ratio, number of perforations and temperature on the deformation characteristics of functionally graded cylindrical shell structure.

• 산업경영시스템학회지
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• 제46권3호
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• pp.15-22
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• 2023

BNKT Ceramics, one of the representative Pb free based piezoelectric ceramics, constitutes a perovskite(ABO3) structure. At this time, the perovskite structure (ABO3) is in the form where the corners of the octahedrons are connected, and in the unit cell, two ions, A and B, are cations, A ion is located at the body center, B ion is located at each corner, and an anion O is located at the center of each side. Since Bi, Na, and K sources constituting the A site are highly volatile at a sintering temperature of 1100℃ or higher, it is difficult to maintain uniformity of the composition. In order to solve this problem, there should be suppression of volatilization of the A site material or additional compensation of the volatilized. In this study, the basic composition of BNKT Ceramics was set to Bi_0.5(Na_0.78K_0.22)_0.5TiO₃ (= BNKT), and volatile site (Bi, Na, and K sources) were coated in the form of a shell to compensate additionally for the A site ions. In addition, the physical and electrical properties of BNKT and its coated with shell additives(= @BNK) were compared and analyzed, respectively. As a result of analyzing the crystal structure through XRD, both BNKT(Core) and @BNK(Shell) had perovskite phases, and the crystallinity was almost similar. Although the Curie temperature of the two sintered bodies was almost the same (TC = 290 ~ 300 ℃), it was confirmed that the d33 (piezoelectric coefficient) and Pr (residual polarization) values were different. The experimental results indicated that the additional compensation for a shell additive causes the coarsening, resulting in a decrease in sintering density and Pr(remanent polarization). However, coating shell additives to compensate for A site ion is an effective way to suppress volatilization. Based on these experimental results, it would be the biggest advantage to develop an eco-friendly material (Lead-free) that replaced lead (Pb), which is harmful to the human body. This lead-free piezoelectric material can be applied to a biomedical device or products(ex. earphones (hearing aids), heart rate monitors, ultrasonic vibrators, etc.) and skin beauty improvement products (mask packs for whitening and wrinkle improvement).

• 한국진공학회:학술대회논문집
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• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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• pp.430.1-430.1
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• 2016

We present the concept of reducible fugitive material that conformally surrounds core Cu nanowire (NW) to fabricate transparent conducting electrode (TCE). Reducing atmosphere can corrodes/erodes the underlying/surrounding layers and might cause undesirable reactions such impurity doing and contamination, so that hydrogen-/forming gas based annealing is impractical to make device. In this regards, we introduce novel reducible shell conformally surrounding indivial CuNW to provide a protection against the oxidation when exposed to both air and solvent. Uniform copper lactate shell formation is readily achievable by injecting lactic acid to the CuNW dispersion as the acid reacts with the surface oxide/hydroxide or pure copper. Cu lactate shell prevents the core CuNW from the oxidation during the storage and/or film formation, so that the core-shell CuNW maintains without signficant oxidation for long time. Upon simple thermal annealing under vacuum or in nitrogen atmosphere, the Cu lactate shell is easily decomposed to pure Cu, providing an effective way to produce pure CuNW network TCE with typically sheet resistance of $19.8{\Omega}/sq$ and optical transmittance of 85.5% at 550 nm. Our reducible copper lactate core-shell Cu nanowires have the great advantage in fabrication of device such as composite transparent electrodes or solar cells.

• 한국자동차공학회논문집
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• 제18권2호
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• pp.31-38
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• 2010

Bus manufacturers have tested and studied the dynamic collapse behavior of a bus body structure in rollover since UN ECE established ECE Regulation 66 to provide the requirement for the strength of bus structure. In spite of the costly cycles of practical tests, however, it is still a hard task to meet the rollover regulation by means of local reinforcements in the bus structure. Therefore it is necessary to develop a well designed strategy for the rollover strength implemented in the early stage of vehicle development. In this study, the suitable development method for each design stage from a component to complete body structure was considered to make a well-established development process of a bus body structure for rollover safety. For the efficient approach of the concept design stage, a numerical model based on the plastic hinge theory was used instead of detailed shell models. After setting up the concept design for the component size and geometry, the shell model was used to confirm and optimize the whole structure composition. The process developed in this study was practically used as an effective method to predict the rollover behavior of a new bus body structure.