• Title/Summary/Keyword: shape and decay

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Optical Properties of InAs Quantum Dots Grown by Using Indium Interruption Growth Technique (Indium Interruption Growth법으로 성장한 InAs 양자점의 광학적 특성)

  • Lee, Hi-Jong;Ryu, Mee-Yi;Kim, Jin-Soo
    • Journal of the Korean Vacuum Society
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    • v.18 no.6
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    • pp.474-480
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    • 2009
  • We have investigated optical properties of InAs quantum dots (QDs) grown on GaAs (100) substrate by molecular beam epitaxy, by means of photoluminescence (PL) and time-resolved PL spectroscopy. InAs QDs were grown by using In interruption growth technique, in which the In flux was periodically interrupted by a closed In shutter during InAs QDs growth. The shutter of In source was opened for 1 s and then closed for 0, 9, 19, 29, or 39 s. This growth sequence was repeated 30 times during QDs growth. For each sample, the total amount of In contributing to the growth was the same (30 s) but total growth time was varied during the InAs growth. As the In interruption time is increased from 0 to 19 s, the PL peak position of the QDs is red-shifted from 1096 to 1198 nm, and the PL intensity is increased. However, the PL peak is unchanged and the intensity is decreased as the In interruption time is increased further to 39 s. The PL decay times measured at the PL peak position for all the InAs QDs are independent on the QD growth conditions and showed about 1 ns. The red-shift of PL peak and the increase of PL intensity can be explained due to increased QD size and the enhancement in the migration of In atoms using In interruption technique. These results indicated that the size and shape of InAs QDs can be controlled by using In interruption growth technique. Thus the emission wavelength of the InAs QDs on GaAs substrate can also be controlled.

Photoluminescence Characteristics of Spherical-Shaped LaPO4:Tb Phosphor Particles Prepared by Spray Pyrolysis (분무열분해법에 의해 제조된 구형의 녹색 LaPO4:Tb 형광체의 발광특성)

  • Lee, Kyo-Kwang;Kang, Yun-Chan;Zeon, Il-Woon;Jung, Kyeong-Youl;Park, Hee-Dong
    • Korean Journal of Materials Research
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    • v.12 no.9
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    • pp.761-766
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    • 2002
  • Fine $LaPO_4$:Tb phosphor particles with spherical shape were prepared by spray pyrolysis. The influence of the precursor type of phosphorous such as ($NH_4$)$_2$$HPO_4$, $NH_4$$H_2$$PO_4$, ($NH_4$)$_3$$PO_4$ and $H_3$$PO_4$ on the morphology and brightness of particles was investigated. As-prepared particles by spray pyrolysis had spherical shape when ($NH_4$)$_2$ $HPO_4$ and $NH_4$$H_2$$PO_4$ were used as the precursor of phosphorous. The precursor type of phosphorous affected the photoluminescence intensity of $LaPO_4$:Tb phosphor particles, but not significant. With changing the content of activator(Tb) and excess of phosphorous, the optimal composition giving the highest photoluminescence intensity was found. The spherical morphology of prepared $LaPO_4$:Tb particles was completely maintained even after the posttreatment up to $1050^{\circ}C$. When the posttreatment temperature was over $1100^{\circ}C$, the particles did not have the spherical shape anymore. However, the highest photoluminescence intensity of prepared $LaPO_4$:Tb particles was obtained at $1050^{\circ}C$. The photoluminescence characteristics of prepared $_LaPO4$:Tb under the vacuum ultraviolet(VUV) illumination was comparable with that of the commercial $Zn_2$$V_4$:Mn and (La,Ce)PO$_4$:Tb phosphor particles. At the optimal condition, the decay time of prepared spherical $LaPO_4$:Tb phosphor particles was about 6.8ms.

Characteristics of Channelbed and Woody Debris on Mountainous Stream (산지급류소하천(山地急流小河川)에 있어서 하상미지형(河床微地形)과 유목(流木) 특성(特性))

  • Chun, Kun-Woo;Kim, Min-Sik;Park, Wan-Geun;Ezaki, Tsugio
    • Journal of Korean Society of Forest Science
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    • v.86 no.1
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    • pp.69-79
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    • 1997
  • The purpose of this study is to acquire essential data to reduce the amount of woody debris resulted from the debris flow. This research examined topographic characteristics of the channelbed affecting generation, movement and storage of woody debris and woody characteristics related to number, sizes, shapes, decay, storage direction to mountainous stream. 1. The number of woody debris had a tendency to increase in proportion to stream width, but it was hardly affected by longitudinal gradient of stream. Especially, the greater amount of woody debris was stored at wide section of the stream with compound channel, and it was found in deposits of channelbed rather than in the present channel. 2. Total woody debris over 10cm in diameter and over 2m in length was 402 units and storage number was 35.3 units per 100m of stream. Average diameter of breast height and length were 14cm and 4m, respectively. The woody debris appeared shorter in length and greater in diameter at down-stream than up-stream. 3. Since woody debris met sediments and bed-materials of great roughness in moving, the greater amount of woody debris without root was found in up-stream and down-stream, but deformed woody debris was discovered in upper stream. Decay of woody debris was more severe in down-stream and woody debris on rotting process was found down-stream. 4. Storage direction of woody debris was mainly parallel to center line of stream, and rate of parallel and perpendicularity was 276 and 126 units, respectively. But, as woody debris storing to the perpendicular direction was unstable, the traveling debris could easily be stored. Therefore, some counterplan was required to prevent the traveling woody debris. 5. Tree species of woody debris was mainly larch, which occupied about two third of total woody debris(256 units). The woody debris of larch is easy to move due to hitting of channelbed materials or lower channelbed fluctuation because the lower part of larch is weaker than its upper part. Therefore, the section of the tree species planting in the riparian vegetation needs much more carefulness.

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The Effect of Packaging and Storage Temperature on Quality Changes of 'White Dadagi' Cucumber (포장과 저장온도가 '백다다기' 오이 선도에 미치는 영향)

  • Lee, Jung-Soo;Kim, Gibin;Kim, Hayeon;Jeong, DaHye;Chei, Da Kyoung;Chea, Ye Rim;Park, Me Hea;Jang, Min Sun;Hong, Yuun Pyo
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.27 no.2
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    • pp.115-121
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    • 2021
  • The evaluation of package temperature for fresh preservation of cucumber was investigated. The fresh cucumber is available in markets of Korea during whole seasons, for the help of farmer, distributor and consumer. Cucumbers were stored within cardboard boxes packaging covered with low density polyethylene (LDPE) at different temperatures (5, 10, 15 and 20℃). Changes in weight loss, hue angle, firmness, moisture content and general appearance (shape of cucumber) were investigated during storage of cucumbers. General appearance index with non-packaging decreased more than with LDPE film packaging at 5℃ and 10℃. During storage of cucumbers, general appearance index as freshness showed packaging effect at low temperature than room temperature. In the fresh weight loss, the packaged cucumbers were less reduced than that of the non-packaging ones. At color change, Hue angle of cucumber stored within low temperature with film packaging decreased gradually during storage. However remarkable change in hue angle were observed in cucumber within LDPE film packaging treatments of 15℃ and 20℃ storage. The effect of hue angle with packaging appears differently depending on the storage temperature conditions. The firmness and moisture content of cucumber flesh were not affected by packaging and storage temperature. In this experiment, cucumbers packaged with LDPE film at 5℃ and 10℃ were the most desirable for extending the quality. These results suggest that packaging of low temperature treatments in combination could be effective in prolonging the shelf life of cucumber.

Simulation of Transport and Transformation of Nonconservative Pollutants in Natural Streams: Storage-Transformation Model (자연하천에서 비보존성 오염물질의 이동 및 변환 모의: 저장-변환 모형)

  • Seo, Il Won;Yu, Dae Young
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.14 no.4
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    • pp.867-874
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    • 1994
  • The complex nature of low flow transport and transformation of nonconservative pollutants in natural streams has been investigated using a numerical solution of a proposed mathematical model that is based on a pair of mass balance equations describing the advection, dispersion, decay and mass exchange mechanisms in streams and in storage zones. In the present study, a mathematical model (named "Storage-Transformation Model") has been developed to predict adequately the non-Fickian nature of mixing and transformation mechanisms for decaying substances in natural streams under low flow conditions. Comparisons of the computed concentration-time curves with the measured data show that the Storage-Transformation Model yields better agreements in general shape, peak concentration and time to peak than the conventional 1-D dispersion model. The proposed model shows significant improvement over the 1-D dispersion model in predicting natural transport and transformation processes in streams through pools and riffles.

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Flow Characteristics of Two-Dimensional Turbulent Stepped Wall Jet (2次元 亂流 Stepped Wall Jet 의 流動特性)

  • 부정숙;김경천;박진호;강창수
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.9 no.6
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    • pp.732-742
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    • 1985
  • Measurements of mean velocity and turbulence characteristics are obtained with a linearized constant temperature hot-wire anemometer in a two-dimensional turbulent jet discharging parallel to a flate. Wall static pressure distribution is also measure. The Reynolds number based on the jet nozzle width (D) is about 42,000 and the step height is 2.5D. The reattachment length is found to be 7.5D by using both wool tuft and oil methods. Upstream of the reattachment point, there exist double coherent structures and mean velocity, Reynolds stresses and triple product profiles are asymmetric about jet center line due to the influence of streamline curvature and recirculating flow region. Near the reattachment point, wall static pressure and turbulence quantities change its shape rapidly because of the large eddies by the solid wall. Especially, turbulence intensity has a maximum value in the reattachment regin, then decreases slowly in the redeveloping wall jet ragion. Downstream of X/D=14, a single large scale eddy structure is formed. Far downstream affer the reattachment(X/D.geq.18) mean velocity profile, the decay of maximum velocity and the variation of jet half width are nearly similar to those of plane wall jet, but the Reynolds stresses are higher than those of the latter.

GaN Nanowire Growth on Si Substrate by Utilizing MOCVD Methods (MOCVD 방법에 의한 Si 기판위 GaN 나노선의 성장)

  • Woo, Shi-Gwan;Shin, Dae-Keun;O, Byung-Sung;Lee, Hyung-Gyoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.11
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    • pp.848-853
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    • 2010
  • We have grown GaN nanowires by the low pressure MOCVD method on Ni deposited oxidized Si surface and have established optimum conditions by observing surface microstructure and its photoluminescence. Optimum growth temperature of $880^{\circ}C$, growth time of 30 min, TMG source flow rate of 10 sccm have resulted in dense nanowires on the surface, however further increase of growth time or TMG flow rate has not increased the length of nanowire but has formed nanocrystals. On the contrary, the increase of ammonia flow has increased the length of nanowires and the coverage of nanowire over the surface. The shape of nanowire is needle-like with a Ni droplet at its tip; the length is tens of micron with more than 40 nm in diameter. Low temperature photoluminescence obtained from the sample at optimum growth condition has revealed several peaks related to exciton decay near band-edge, but does not show any characteristic originated from one dimensional quantum confinement. Strong and broad luminescence at 2.2 eV is observed from dense nanowire samples and this suggests that the broad band is related to e-h recombination at the surface state in a nanowire. The current result is implemented to the nanowire device fabrication by nanowire bridging between micro-patterned neighboring Ni catalysis islands.

Fabrication of $Gd_2O_3:Eu^{3+}$ Nano Phosphor and Optical Characteristics for High Resolution Radiation Imaging (고해상도 방사선 영상을 위한 $Gd_2O_3:Eu^{3+}$ 나노 형광체 제조 및 광학적 특성)

  • Kim, So-Yeong;Kang, Sang-Sik;Park, Ji-Koon;Cha, Byung-Youl;Choe, Chi-Won;Lee, Hyung-Won;Nam, Sang-Hee
    • Journal of Biomedical Engineering Research
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    • v.28 no.1
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    • pp.148-152
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    • 2007
  • In this paper, we have synthesized $Gd_2O_3:Eu^{3+}$ nano phosphor particle using a low temperature solution-combustion method. We have investigated the structure and the luminescent characteristic as the sintering temperature and europium concentration. From XRD(X-ray diffraction) and SEM(scanning electron microscope) results, we have verified that the phosphor particle was fabricated a spherical shape with $30{\sim}40nm$ particle size. From the photoluminescence results, the strong peak exhibits at 611 um and the luminescent intensity depends on europium concentration. $Gd_2O_3:Eu$ fine phosphor particle has shown excellent luminescent efficiency at 5 wt% of europium concentration. The phosphors calcinated at $500^{\circ}C$ have possessed the x-ray peaks corresponding to the cubic phase of $Gd_2O_3$. As calcinations temperature increased to $700^{\circ}C$, the new monoclinic phase has identified except cubic patterns. From the luminescent decay time measurements, mean lifetimes were $2.3{\sim}2.6ms$ relatively higher than conventional bulk phosphors. These results indicate that $Gd_2O_3:Eu$ nano phosphor is possible for the operation at the low x-ray dose, therefore, the application as medical imaging detector.

Effects of Operating Variables on CO Conversion of WGS Catalyst in a Fluidized Bed Reactor Equipped with Bed Insert (내부 삽입물을 적용한 유동층 반응기에서 WGS 촉매의 CO 전화율에 미치는 조업변수들의 영향)

  • Park, Jihye;Lee, Dongho;Park, Youngeheol;Moon, Jongho;Rhee, Youngwoo;Ryu, Hojung
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.2
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    • pp.209-217
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    • 2014
  • To enhance the performance of SEWGS system by holding the WGS catalyst in a SEWGS reactor, a spring type bed insert was developed. In this study, effects of operating variables such as steam/CO ratio, gas velocity, syngas concentration on CO conversion were investigated in a fluidized bed reactor using the spring type bed insert to hold the WGS catalyst as tablet shape. CO conversion increased initially as the steam/CO ratio increased. But further increment of the steam/CO ratio caused decreasing of CO conversion because of increment of gas velocity and decrement of syngas concentration. Moreover, CO conversion decreased as the gas velocity increased and the syngas concentration decreased at the same steam/CO ratio. Continuous operation up to 48 hours (2 days) was carried out to check reactivity decay of WGS catalyst supported by spring type bed insert. The average CO conversion was 99.04% and we could conclude that the WGS reactivity at those conditions was maintained up to 48 hours.

A numerical study of flow and heat transfer characteristics varied by impingement jet in turbine blade cooling (터빈블레이드의 냉각에서 충돌제트에 의해 변화되는 유동 및 열전달 특성에 관한 수치해석적 연구)

  • Lee, Jeong-Hui;Kim, Sin-Il;Yu, Hong-Seon;Choe, Yeong-Gi
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.12
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    • pp.4013-4026
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    • 1996
  • A numerical simulation has been carried out for the jet impinging on a flat plate and a semi-circular concave surface. In this computation finite volume method was employed to solve the full Navier-Stokes equation based on a non-orthogonal coordinate with non staggered variable arrangement. The standard k-.epsilon. turbulent model and low Reynolds number k-.epsilon. model(Launder-Sharmar model) with Yap's correction were adapted. The accuracy of the numerical calculations were compared with various experimental data reported in the literature and showed good predictions of centerline velocity decay, wall pressure distribution and skin friction. For the jet impingement on a semi-circular concave surface, potential core length was calculated for two different nozzle(round edged nozzle and rectangular edged nozzle) to consider effects of the nozzle shape. The result showed that round edged nozzle had longer potential core length than rectangular edged nozzle for the same condition. Heat transfer rate along the concave surface with constant heat flux was calculated for various nozzle exit to surface distance(H/B) in the condition of same jet velocity. The maximum local Nusselt number at the stagnation point occurred at H/B = 8 where the centerline turbulent intensity had maximum value. The predicted Nusselt number showed good agreement with the experimental data at the stagnation point. However heat transfer predictions along the downstream were underestimated. This results suggest that the improved turbulence modeling is required.