• Economic and Environmental Geology
• /
• v.49 no.1
• /
• pp.63-75
• /
• 2016

The ratio of fractured reservoir is very high in oil & gas fields around the world. The demand of drilling technology for fractured reservoir is expected to increase continuously if oil and gas prices are economical. The purpose of the review study is to help operator or driller in selecting of proper drilling technology for preventing a lost circulation in the fractured formation. In order to achieve this goal, fractured reservoir(formation) they are classified into partial lost circulation formation and total lost circulation formation. In case of partial lost circulation formation, the drilling problem can be solved by using LCM(lost circulation material) mud additive and squeezing cement. For shallow depth, total lost circulation formation can be drilled safely and economically with casing drilling method. Also, for deeper depth, problems of total lost circulation in formation can be solved by applying mud cap, which is one of the drilling methods. This was confirmed through field application such as Italy's Medusa-1 field and Qatar's North field.

• Economic and Environmental Geology
• /
• v.33 no.5
• /
• pp.425-434
• /
• 2000

The 3.5 KHz seismic survey was carried out for studying the distribution pattern of the unconsolidated sediments of the Yeosu Sound on the southern coast of the Korean Peninsula. Field data originally recorded in analog are converted and processed digitally to recover the high-resolution acoustic profiles. Across the north-south trending channel with the depth of 20~30 m, different seismic facies types are observed in the top section of sediments. The western part is characterized by the continuous high-amplitude subparallel reflectors within which the acoustic turbidity as a token of the presence of gas is commonly observed, whereas the counterpart largely shows poor reflectors and has shallow acoustic basement toward the north. The dissimilarity of the seismic expression across the channel can be interpreted as the result of the change of depositional environment caused by relative sea-level fluctuations of the late-Quaternary. During the last glacial period, the Yeosu Sound was exposed and eroded by the paleo-Seomjin River. By the following rapid rise of sea level, it was covered by the transgressive sand sheet. When the sea level reached near the present position, the muddy sediment has accumulated only in the western part of the Yeosu Sound as its depositional front has moved toward the north. It is partly caused by the asymmetrical tidal current in the Yeosu Sound where the flood near the bottom has stronger current flow and contains more suspended sediments.

• Economic and Environmental Geology
• /
• v.55 no.4
• /
• pp.407-419
• /
• 2022

Soil(vadose zone) gas compositions were measured for about 3 days to suggest a method for monitoring and interpreting soil gas data collected around wells from which methane(CH₄) is outflowing. The vadose zone gas samples were collected within 1 m around two test wells(TB2 and TB3) at Pohang and analyzed for CO₂, CH₄, N₂ and O₂ concentrations in situ. CO₂ flux was measured beside TB2. In addition, gas samples from well head in TB2 and atmospheric air samples were collected for comparison. Carbon isotopes of CO₂(δ¹³C_CO2) of samples collected on the last day of the study period were analyzed in the laboratory. The two test wells (TB2 and 3) were 12.7 m apart and only TB3 was cemented to the surface. According to the bio-geochemical process-based interpretation, the relationships between CO₂ and O₂, N₂, and N₂/O₂ of vadose zone gas were plotted between the lines of CH₄ oxidation and CO₂ dissolution. In addition, the CH₄ concentrations of gas samples from the wellhead of the uncemented well (TB2) were 5.2 times higher than the atmospheric CH₄ concentration. High CO₂ concentrations (average 1.148%) of vadose zone gas around TB2 seemed to be attributed to the oxidation of CH₄. On the other hand, the vadose zone CO₂ around the cemented well(TB3) showed a relatively low concentration(0.136%). This difference indicates that the vadose zone gas(including CO₂) around the CH₄ outflowing well were strongly affected by well completion(cementing). This study result can be used to establish strategies for environmental monitoring of soil around natural gas sites, and can be used to monitor leakage around injection and observation wells for CO₂ geological storage. In addition, the method of this study is useful for soil monitoring in natural gas storage and oil-contaminated sites.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2000.11a
• /
• pp.3-4
• /
• 2000

Many researchers are interested in the synthesis and characterization of carbon nitride and diamond-like carbon (DLq because they show excellent mechanical properties such as low friction and high wear resistance and excellent electrical properties such as controllable electical resistivity and good field electron emission. We have deposited amorphous carbon nitride (a-C:N) thin films and DLC thin films by shielded arc ion plating (SAIP) and evaluated the structural and tribological properties. The application of appropriate negative bias on substrates is effective to increase the film hardness and wear resistance. This paper reports on the deposition and tribological OLC films in relation to the substrate bias voltage (Vs). films are compared with those of the OLC films. A high purity sintered graphite target was mounted on a cathode as a carbon source. Nitrogen or argon was introduced into a deposition chamber through each mass flow controller. After the initiation of an arc plasma at 60 A and 1 Pa, the target surface was heated and evaporated by the plasma. Carbon atoms and clusters evaporated from the target were ionized partially and reacted with activated nitrogen species, and a carbon nitride film was deposited onto a Si (100) substrate when we used nitrogen as a reactant gas. The surface of the growing film also reacted with activated nitrogen species. Carbon macropartic1es (0.1 -100 maicro-m) evaporated from the target at the same time were not ionized and did not react fully with nitrogen species. These macroparticles interfered with the formation of the carbon nitride film. Therefore we set a shielding plate made of stainless steel between the target and the substrate to trap the macropartic1es. This shielding method is very effective to prepare smooth a-CN films. We, therefore, call this method "shielded arc ion plating (SAIP)". For the deposition of DLC films we used argon instead of nitrogen. Films of about 150 nm in thickness were deposited onto Si substrates. Their structures, chemical compositions and chemical bonding states were analyzed by using X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy and infrared spectroscopy. Hardness of the films was measured with a nanointender interfaced with an atomic force microscope (AFM). A Berkovich-type diamond tip whose radius was less than 100 nm was used for the measurement. A force-displacement curve of each film was measured at a peak load force of 250 maicro-N. Load, hold and unload times for each indentation were 2.5, 0 and 2.5 s, respectively. Hardness of each film was determined from five force-displacement curves. Wear resistance of the films was analyzed as follows. First, each film surface was scanned with the diamond tip at a constant load force of 20 maicro-N. The tip scanning was repeated 30 times in a 1 urn-square region with 512 lines at a scanning rate of 2 um/ s. After this tip-scanning, the film surface was observed in the AFM mode at a constant force of 5 maicro-N with the same Berkovich-type tip. The hardness of a-CN films was less dependent on Vs. The hardness of the film deposited at Vs=O V in a nitrogen plasma was about 10 GPa and almost similar to that of Si. It slightly increased to 12 - 15 GPa when a bias voltage of -100 - -500 V was applied to the substrate with showing its maximum at Vs=-300 V. The film deposited at Vs=O V was least wear resistant which was consistent with its lowest hardness. The biased films became more wear resistant. Particularly the film deposited at Vs=-300 V showed remarkable wear resistance. Its wear depth was too shallow to be measured with AFM. On the other hand, the DLC film, deposited at Vs=-l00 V in an argon plasma, whose hardness was 35 GPa was obviously worn under the same wear test conditions. The a-C:N films show higher wear resistance than DLC films and are useful for wear resistant coatings on various mechanical and electronic parts.nic parts.