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Preparation and Application of CSA Expansive Additives Using Industrial Wastes (산업폐기물을 이용한 CSA계 팽창재 제조 및 응용)

  • Yoon Sung-Won;Rho Jae-Seong
    • Journal of the Korea Concrete Institute
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    • v.16 no.3 s.81
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    • pp.369-374
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    • 2004
  • Calcium sulfoalumiante(CSA) was prepared for using natural calcite($CaCO_3$) and industrial by-products and wastes, such as $Al(OH)_3,\;CaSO_4{\cdot}2H_2O$. The mixture of raw materials was fired at 20, 400, 600, $1200^{\circ}C$ for 1h and cooled rapidly in air. The cement replaced by 10 wt% $C_4A_3S$ expansive additives was investigated by the measurement of the hydration products and compressive strength, setting time, expansion at wet curing condition. $C_4A_3S$ was found in x-ray diffraction pattern over the temperature $1200^{\circ}C$. The setting time or the cement pastes added clinkers fired at different temperature was shorter than ordinary portland cement. The compressive strength was higher than the ordinary portland cement about 20~30%. The mainly hydration products were ettringite, and $Ca(OH)_2$. The expansion due to the formation of ettringite during hydration decreased the drying shrinkage of hardened cement rather than the ordinary portland cement.

Properties of Undispersed Underwater Mortar Using the Expansive Additives and Fly Ash (팽창재 및 플라이애쉬를 이용하는 수중불분리 모르터의 특성)

  • 한천구;이대주;이광설;한일영;권지훈;유홍종
    • Magazine of the Korea Concrete Institute
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    • v.10 no.6
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    • pp.223-231
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    • 1998
  • Existing cast in place piles made by grouting cement mortar have many problems that cracks by autogeneous and drying shrinkage bring about the deterioration of force for piles, segregations by the submersion of ground water occur and also, high cement contents lead to rise the manufacturing cost. Therefore, this study is intended to investigate the mechanical properties of high performance mortar, incorporating expansive additives and fly ash. for cast in place piles. According to the experimental results, as the contents of expansive additives increase in mortar mixture, fluidity decrease and air contents shows inverse tendency. Setting time is delayed. Although compressive strength at 7days shows a decline tendency. compressive strength at 28days and 91days increase slightly with 5% of expansive additives. As fly ash increase in mortar mixture, high fluidity is shown, air contents increase and setting time is delayed at fresh state, and additives are, the larger length change is, whereas shrinkage decrease with the increase of fly ash.

An Effect of $Ca(OH)_2$ on Development of an Early Age Strength of GGBFS Cement (고로슬래그 시멘트의 초기강도 발현에 있어서 수산화칼슘의 영향)

  • 이제방;김재신;소승영;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.64-69
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    • 1999
  • Slags are by-products of the metallurgical industry. The most important slag from the standpoint of the quantity used as building material is iron blastfurnace slag. Slags are either crystalline stable solid used as aggregates or glassy material used as hydraulic binder. Slag cements are low heat of hydration cements. Slags react more slowly with than portland cement but they can be activated chemically. Activatiors can be either alkaline activators such as soda, lime, sodium carbonate, sodium silicate or sulphate activators such as calcium sulphate or phosphogypsum. So, in this study slaked lime was used as an activator that the compressive strength of this modified cement(M1 type) is high range in early age. And initial setting time of M1 type cement was shorter than conventional cements.

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Mix Proportions of High Performance Shotcrete for Permanent Support (영구지보재로서 고성능 숏크리트의 적정 배합비 도출)

  • Won, Jong-Pil;Kim, Hwang-Hee;Kim, Jung-Hoon;Park, Kyoung-Hoon;Jang, Chang-Il;Lee, Sang-Woo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.41-44
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    • 2006
  • Recently, single shell lining method of construction is studied by economical method of construction to make use of high-performance shotcrete of permanent shotcrete lining concept in the UStA, Europe, Japan etc. High-performance shotcrete use is essential as permanent support that single shell lining method of construction has two functions of lining and support to shotcrete. In this research, optimum accelerator amount was decided after setting time test using alkai-free and cement mineral accelerator. Also replacement ratio of silica fume and fly-ash was determined.

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Study on engineering properties of ready-mixed soil and slag

  • Chen, Tung-Tsan;Ho, Chun-Ling;Wang, Her-Yung
    • Computers and Concrete
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    • v.21 no.5
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    • pp.531-538
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    • 2018
  • The slag through sieve #4 replaced the natural fine aggregate in different proportions (0-50%) to make ready-mixed soil and slag (RMSAS). The fresh properties studied, and the concrete specimens were produced to test the hardened properties at different ages. Results showed that the workability of RMSAS decreases when the replacement increases. The unit weight increases with the replacement. The setting time extends when the replacement decreases and shortens when the replacement increases. The compressive strength, ultrasonic pulse velocity and hammer rebound value increase with the replacement. However, the high-replacement results decrease because of the expansion factor at late age. Resistivity is close and less than $20k{\Omega}-cm$. After the industrial of steelmaking by-products are processed properly, they can be used in civil engineering, not only as a substitute for natural resources and to reduce costs, but also to provide environmental protection.

Strength of Alkali-Activated GGBF Slag Mortar (활성제를 사용한 슬래그 미분말 혼합 모르타르의 강도)

  • 문한영;신화철;권태석
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.05a
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    • pp.481-486
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    • 2001
  • Ground granulated blast-furnace slag shows very high strength when proper alkali-activator exists. This paper deals with setting time, heat evolution rate and the strength development of alkali-activated slag cement activated by KOH, Ca(OH$)_{2}$, $Na_{2}$ $So_{4}$ , and alum(potassium aluminum sulfate). Alkali-activated slag mortar is studied by comparison with GGBF slag cement mortar. The experimental results indicate that for moisture curing at $25^{\circ}C$, the addiction of either 4% $Na_{2}$ $So_{4}$ or 4% alum increases the strength of GGBF slag cement mortar consisting of 50% GGBF slag and 50% portland cement at early age. Strength of activated GGBF slag cement mortars at 1, 3 and 7 days exceeded that of GGBF slag cement mortar. A conduction calorimeter was used to monitor early age hydration.

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An Experimental Study on the Characteristics of Evaluation with Feature of Self Levelling Primer (셀프레벨링 모르타르용 Primer 성상에 따른 특성평가에 관한 실험적 연구)

  • Kang, Dong-Gyun;Kim, Gyung-Yuk;Kim, Jung-Wan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.505-508
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    • 2006
  • Self-leveling mortar is walkable bottom mortar which can maintain the horizontality of self fluid and have the the quick-setting quality, the low-human-effort practicable material of high-quality bottom in construction. In accordance with more adhesive strength with bottom side and absorption control, Primer is used for purpose to prevent pin-hole occurrence by self leveling mortar application prior to construction. This study is composed measurement of absorption, adhesive strength. Used material is NP-40 as nonionic emulsifying agent, uses SA-210L as negative ion emulsifying agent, uses APS, SBS as ridical initiator. A result of test, in accordance with image of Primer, as low temperature and application frequency, indicates low absorption rate and adhesive strength, as solid powder and dryness time is increse, absorption rate and adhesive strength lowly shows figure.

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The Hardening Characteristics of Underwater Concrete According to the Cellulose Underwater Non-segregation Admixture and Its Preparation (Cellulose계 수중재료분리 방지제의 제조 및 첨가에 따른 수중콘크리트의 경화특성)

  • Shin, Dong-Gil;Song, Yon-Ho;Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.16 no.2
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    • pp.267-274
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    • 2005
  • Preparation of cellulose type underwater non-segregation admixture was attempted and the hardening characteristics of underwater concrete according to the addition of this admixture was investigated in order to make underwater concrete with the compressive strength ratio of 0.8 to that of concrete manufactured in common atmosphere. The proposed underwater non-segregation admixture consisted of methyl cellulose of 0.4% by weight, silicon type antifoaming agent of 20% by weight, and sodium aluminate of 0.1% by weight to the amount of cement as setting accelerant, respectively. As the proposed non-segregation admixture was increased, the amount of suspended solid decreased, air content in concrete was increased but the flow loses by elapsed time did not change. The proper amount added of the proposed non-segregation adimixture was 0.8 wt% to the amount of cement. The compressive strength of the test sample underwater concrete manufactured by the addition of the proposed admixture was $325Kg/cm^3$, and the ratio of compressive strength of this sample concrete to that of a concrete manufactured in air was 0.94.

An Experimental Study on Mechanical Properties of Fly Ash in Mortar (플라이애쉬 혼입 모르터의 역학적 특성에 관한 실험적 연구)

  • Park, Il-Yong;Paik, Min-Su;Shon, Jong-Kyu;Choi, Soo;Jung, Sang-Jin
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.10c
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    • pp.127-132
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    • 1998
  • The purpose of this study is to find mechanical properties of fly ash ratio in mortar as flowing, setting time, compressive strength, suction ratio of water, length change ratio. As a result, it was shown that proper fly ash ratio replaced by cement weight in mortar was generally positive effect to flowing, compressive strength suction ratio of water, length change ratio. So if fly ash is well done quality control is considered as good replacement of cement.

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Examination of the Characteristics of Mortar Mixed with Boron Compounds Presenting Various Levels of Alkalinity (다양한 알칼리도를 가진 붕소화합물이 혼입된 모르타르의 특성 검토)

  • Lee, Binna;Lee, Jong-Suk;Min, Jiyoung;Lee, Jang Hwa
    • Journal of the Korea Concrete Institute
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    • v.29 no.1
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    • pp.85-92
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    • 2017
  • This study examines the characteristics of mortar mixed with various boron compounds. The adapted boron compounds, classified into acid, slightly alkaline and strongly alkaline with respect to the value of the pH are acid-based boron (AA), low-alkaline-based boron (AB), and high-alkaline-based boron (HB). The pH test, setting test and compressive strength test are performed to evaluate the physical and chemical properties of mortar, and SEM imaging is conducted to analyze the microstructure of mortar. The measured pH shows that the specimens mixed with boron compounds have lower pH than the basic mortar without boron and that loss of pH occurs according to time. The setting test reveals that the initial and final setting times of the specimens mixed with boron compounds occur later than the basic mortar, which disagrees slightly with the previous literature stating that the setting time can be shortened according to the alkalinity. From the compressive strength test and SEM imaging results, it is recommended to determine the optimal content of boron considering type and composition of the boron compounds.