• 제목/요약/키워드: separations

검색결과 308건 처리시간 0.03초

융복합기술(融複合技術)에 의한 폐(廢)콘덴서로부터 탄탈륨 재활용(再活用) 기초연구(基礎硏究) (A Preliminary Study on Tantalum Recycling from Obsolete Condenser by Multidisciplinary Process)

  • 이후인;김상배;김병곤;최영윤
    • 자원리싸이클링
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    • 제16권6호
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    • pp.34-38
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    • 2007
  • 폐콘덴서로부터 탄탈륨 음극을 회수하기 위하여 물리적 선별과, 염소가스와 사염화탄소를 이용한 기초 염화반응에 관한 연구를 수행하였다. Stamp mill을 이용한 파쇄, 요동테이블에서의 습식 비중선별 그리고 공기 분급을 통하여 탄탈륨 음극을 98% 회수할 수 있었다. 염소가스를 이용한 TGA분석에서 탄탈륨 음극의 최대 무게 감소는 60%였고, 사염화탄소에 의한 탄탈륨 음극의 염화반응은 탄탈륨 음극을 산화탄탈륨으로 변환한 후가 반응율이 높았다.

디지털 재설계를 이용한 관측기 기반 디지털 퍼지 제어기 설계 (Observer-Based Digital fuzzy Controller Design Using Digital Redesign)

  • 이호재;주영훈;박진배
    • 한국지능시스템학회논문지
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    • 제13권5호
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    • pp.520-525
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    • 2003
  • 본 논문은 지능형 디지털 재설계 기법을 이용한 Takagi-Sugeno (T-S) 퍼지 시스템의 관측기 기반 출력 궤환 디지털 제어기 설계 기법을 제안한다. 지능형 디지털 재설계란 아날로그 퍼지 모델 기반 제어기를 등가의 성능을 발휘하는 퍼지 모델 기반 디지털 제어기로 변환하는 기법을 일컫는다. 여기서 등가의 성능은 상태 정합의 정확도를 의미한다. 본 연구에서 고려된 지능형 디지털 재설계 기법은 정합되어야 할 두개의 선형 작용소의 놈(norm)을 최소화하는 볼록 최적화 문제로 간주한다. 선형 행렬 부등식의 형태로 문제를 구성함으로써 재설계된 디지털 제어기에 의한 시스템의 안정가능성을 증명할 수 있다. 또한 제어기와 관측기의 재설계는 독립적으로 설계될 수 있음을 증명한다.

Explaining the Drift Behavior of Caffeine and Glucosamine After Addition of Ethyl Lactate in the Buffer Gas of an Ion Mobility Spectrometer

  • Fernandez-Maestre, Roberto;Velasco, Andres Reyes;Hill, Herbert H.
    • Bulletin of the Korean Chemical Society
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    • 제35권4호
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    • pp.1023-1028
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    • 2014
  • Protonated caffeine ($CH^+$) and glucosamine ($GH^+$) overlapped in an analysis with ion mobility spectrometryquadrupole mass spectrometry. Ethyl lactate vapor (L) at different concentrations from 0 to 22 mmol $m^{-3}$ was added as a buffer gas modifier to separate these signals. The drift times of $CH^+$ and $GH^+$ increased with L concentration. The drift time increase was associated to clustering equilibria of $CH^+$ and $GH^+$ with one molecule of L and the equilibrium of $GH^+$ was more displaced to the formation of $GLH^+$ than that of $GLH^+$. $GH^+$ clustered more to L than $CH^+$ because $GLH^+$ formed more stable hydrogen bonds (26.30 kcal/mol) than $GLH^+$ (24.66 kcal/mol) and the positive charge in $GH^+$ was more sterically accessible than in $CH^+$. The aim of this work was to use theoretical calculations to guide the selection of a buffer gas modifier for IMS separations of two compounds that overlap in the mobility spectra and predict this separation, simplifying that empirical process.

Fast High-throughput Screening of the H1N1 Virus by Parallel Detection with Multi-channel Microchip Electrophoresis

  • Zhang, Peng;Park, Guenyoung;Kang, Seong Ho
    • Bulletin of the Korean Chemical Society
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    • 제35권4호
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    • pp.1082-1086
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    • 2014
  • A multi-channel microchip electrophoresis (MCME) method with parallel laser-induced fluorescence (LIF) detection was developed for rapid screening of H1N1 virus. The hemagglutinin (HA) and nucleocapsid protein (NP) gene of H1N1 virus were amplified using polymerase chain reaction (PCR). The amplified PCR products of the H1N1 virus DNA (HA, 116 bp and NP, 195 bp) were simultaneously detected within 25 s in three parallel channels using an expanded laser beam and a charge-coupled device camera. The parallel separations were demonstrated using a sieving gel matrix of 0.3% poly(ethylene oxide) ($M_r$ = 8,000,000) in $1{\times}$ TBE buffer (pH 8.4) with a programmed step electric field strength (PSEFS). The method was ~20 times faster than conventional slab gel electrophoresis, without any loss of resolving power or reproducibility. The proposed MCME/PSEFS assay technique provides a simple and accurate method for fast high-throughput screening of infectious virus DNA molecules under 400 bp.

부분입사형 초음속 터빈 익렬내 유동 특성에 관한 수치적 연구 (A Numerical Analysis on the Flow Characteristics within Blades of A Partial Admission Supersonic Turbine)

  • 신봉근;조종재;정수인;김귀순;이은석
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 춘계학술대회
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    • pp.1738-1743
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    • 2004
  • Turbo-pump system, an essential component of liquid rockets and induced weapons, adopts a partial admission axial turbine which drives pump. And the turbine of a turbo-pump system is usually operated at supersonic condition due to its high loading chracteristics. Therefore, reseaches about flow and performance characteristics of a partial admission supersonic turbine must be preceeded to progress the aerospace and defense industries as well as the development of turbo-pump systems. In this study, flow characterisitics within blades of the partial admission supersonic turbine are numerically investigated by using Fine Turbo, a commercial CFD Code. Before performing the numercial analyses, to verify accuracy of the numerical result computed by Fine Turbo, I performed the comparison between the numerical results with J.J.Cho' experimental results. It is found that the numerical results show good agreement with the experimental results. Computations about the partial admission supersonic turbine have been performed to investigate flow characteristics including shock patterns. It is also found that the flow and performance of partial admission supersonic turbine are largely depend on shocks ocurred in the nozzle and at the leading edge of blades, expansion or compression at exit of nozzle and separations occurred in passage.

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KVN SOURCE-FREQUENCY PHASE-REFERENCING OBSERVATION OF 3C 66A AND 3C 66B

  • ZHAO, GUANG-YAO;JUNG, TAEHYUN;DODSON, RICHARD;RIOJA, MARIA;SOHN, BONG WON
    • 천문학논총
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    • 제30권2호
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    • pp.629-631
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    • 2015
  • In this proceedings, preliminary results of the KVN Source-Frequency Phase-Referencing (SFPR) observation of 3C 66A and 3C 66B are presented. The motivation of this work is to measure the core-shift of these 2 sources and study the temporal evolution of the jet opacity. Two more sources were observed as secondary reference calibrators and each source was observed at 22, 43, and 86 GHz simultaneously. Our preliminary results show that after using the observations at the lower frequency to calibrate those at the higher frequency of the same source, the residual visibility phases for each source at the higher frequencies became more aligned, and the coherence time became much longer; also, the residual phases for different sources, within 10 degrees angular separations, follow similar trends. After reference to the nearby calibrator, the SFPRed maps were obtained as well as the astrometric measurements, i.e. the combined coreshift. The measurements were found to be affected by structural blending effects because of the large beamsize of KVN, but this can be corrected with higher resolution maps (e.g. KAVA maps).

MEMBRANES FOR GAS AND LIQUID SEPARATIONS

  • Golemme, Giovanni;Bove, Lucia;Clarizia, Gabriele;Muzzalupo, Rita;Ranieri, Giuseppe;Nam, Sang-Yong;Drioli, Enrico
    • 한국막학회:학술대회논문집
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    • 한국막학회 1999년도 The 7th Summer Workshop of the Membrane Society of Korea
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    • pp.27-30
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    • 1999
  • Poly(phenylene oxide)s were used to prepare flat, integrally skinned self-supporthed asymmetric membranes by dry-wet phase separption. The intrinsic ideal gas selectivity of poly- (2,6-dimethy-1,4-phenylene oxide) (PMPO) was retained in the membranes, and improved by a coating with silicone rubber. Polymers of the same class were coated of UF supports with a silicon rubber gutter layer, yielding composite membranes with high flux but lower selectivity. The effect of th glutaraldehyde cross-linking of sodium alginate (SA) membranes on the mobility of water and ethanol has been studied with pfg nmr. Crosslinking reduces water self-diffusion, and does not seem to be stable on the timescale of weeks.

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케이싱 환경에서의 밀도자료 보정을 위한 기초연구 (A Preliminary Study on Correction for Density Log in Cased Boreholes)

  • 김영화;김지훈;이성진
    • 지질공학
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    • 제16권4호
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    • pp.429-435
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    • 2006
  • 케이싱 시추공 구간의 밀도검층에서 정확한 밀도 값의 산출을 위한 기초연구의 일환으로 세 종류의 서로 다른 밀도를 가진 보정 실험공에서 공벽과 검출기간의 이격 거리를 달리하면서 세 가지 다른 검출기 옵셋 거리에 따른 반응 값의 변화를 알아보았으며 과거 석유 검층에서 이수 보정에 활용되어 온 spine and ribs 기법을 활용함으로써 케이싱 속에서의 감마감마 측정치로부터 지층의 참 밀도를 찾아가는 효과적인 방안을 제시하였다.

소구경 플라스틱 케이싱 공에서의 밀도검층 보정실험 (An Experimental Study on Density Log Correction for Plastic Cased Slim Boreholes)

  • 이성진;김영화;황병철
    • 지질공학
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    • 제18권2호
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    • pp.137-144
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    • 2008
  • 강원대학교 구내에 설치된 4개의 보정시험공에서 플라스틱재질의 원통 및 반원통 케이싱을 이용한 이격오차 실험을 수행하였다. 이격실험 자료에 spine and ribs 기법을 적용한 결과 케이싱 두께 및 유형에 관계없이 하나의 밀도모델에서는 하나의 이격선이 얻어졌으며 그 기울기는 모델지층의 밀도에 비례하는 것으로 나타났다. 이러한 이격특성을 이용하여 플라스틱 케이싱이 설치된 NX시추공에서의 효과적인 밀도보정 방안이 제시되었다.

Progresses and new perspectives of integrated operations for a sustainable industrial growth

  • Drioli, Enrico
    • 한국막학회:학술대회논문집
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    • 한국막학회 1998년도 추계 총회 및 학술발표회
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    • pp.11-14
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    • 1998
  • 1. Introduction : Research progresses in Chemistry and Chemical Engineering have been made during the last decades with important contributions to the industrial development and to the quality of our life. An interesting case is related to the membrane science and technology continuous impact to innovative processes and products, particularly appropriate for a sustainable industrial growth. Membrane operations have been familiar for many years to biologists and chemists working in their laboratorier or studying biological phenomena. Only recently engineers started to operate in' this area. The preparation of asymmetric CA membranes at University of California, Los Angeles in the early 60s is generally recognized as a crucial moment for membranology (1). Loeb and Sourirajan with their discovery of how to increase significantly the permeability of polymeric membranes without significant changes in their selectivity, made realistic the possibility of their use in large scale operations for desalting brackish and sea water by reverse osmosis and for various other molecular separations in different industrial areas. Reverse osmosis is today a well recognized basic unit operations, togheter with ultrafiltration, crossflow microfiltration,. nanofiltration, all pressure driven membrane processes. Already in 1992 more than 4 milIions m$^3$/day were the total capacity of RO desalination plants and in 1995 more than 180.000 m$^2$ of ultrafiltration membranes were installed for the treatment of wheys and milk (2) (3).

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