• 제목/요약/키워드: separation properties.

검색결과 1,078건 처리시간 0.025초

Morphological Effect of Dispersed Phase on Gas Separation Properties through Heterophase Polymer Membrane: Theoretical and Experimental Approaches.

  • Park, Cheolmin;Jo, Won-Ho;Kang, Yong-Soo
    • 한국막학회:학술대회논문집
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    • 한국막학회 1996년도 춘계 총회 및 학술발표회
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    • pp.55-56
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    • 1996
  • Heterophase polymer system has been attractive for a potential applicability to gas separation membrane material. It has been known that there is a trade-off between gas permeability and its selectivity in common polymers. Therefore, the heterophase polymer can be an alternative for a gas separation membrane material because its transport properties can be readily controlled by blending of two different polymers. The transport properties of immiscible polymer blends strongly depend upon the intrinsic transport properties of corresponding polymers. Another important factor to determine the transport properties is their morphology: volume fraction, size and shape of dispersed phase. Although the effect of the volume fraction of the dispersed phase on the transport properties has been widely investigated, the size and shape effects have been paid attention very much. In an immiscible polymer blend of two polymers, its morphology is primarily controlled by its volume fraction of dispersed phase. Therefore, the effect of the size of the dispersed phase can be hardly seen. Therefore, a block copolymer has been commonly employed to control their morphology when each block is miscible with one or the other phase. In this work, gas transport properties will be measured by varying the morphology of the heterophase polymer membrane. The transport properties will be interpreted in terms of their morphology. The effect of the volume fraction of the PI phase and, in particular, its size effect will be investigated experimentally and theoretically.

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폐금속광산 지역의 비소오염토양 처리를 위한 선별 기술 적용 (Application of a Soil Separation System for the Remediation of Arsenic Contaminated Soil in a Metal Mining Area)

  • 박찬오;김종원;박준형;이영재;양인재;이재영
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제18권5호
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    • pp.56-64
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    • 2013
  • After the law has been enacted for the prevention and recovery of mining damage in 2005, efforts of remediation have been started to recover heavy metal contaminated soils in agricultural land near mining sites. As part of an effort, the upper part of cultivation layer has been treated through covering up with clean soil, but the heavy metal contamination could be still spreaded to the surrounding areas because heavy metals may be remained in the lower part of cultivation layers. In this study, the most frequently occurring arsenic (As) contamination was selected to study in agricultural land nearby an abandoned metal mining site. We applied separation technologies considering the differences in the physical characteristics of soil particles (particle size, density, magnetic properties, hydrophobicity, etc.). Based on physical and chemical properties of arsenic (As) containing particles in agricultural lands nearby mining sites, we applied sieve separation, specific gravity separation, magnetic separation, and flotation separation to remove arsenic (As)-containing particles in the contaminated soil. Results of this study show that the removal efficiency of arsenic (As) were higher in the order of the magnetic separation, flotation separation, specific gravity separation and sieve separation.

Pervaporation separation of polyion complex composite membranes for the separation of water/alcohol mixtures: characterization of permeation behavior by using molecular modeling techniques

  • Kim, Sang-Gyun;Lee, Yoon-Gyu;Jonggeon Jegal;Lee, Kew-Ho
    • 한국막학회:학술대회논문집
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    • 한국막학회 2003년도 The 4th Korea-Italy Workshop
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    • pp.91-94
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    • 2003
  • In this work, the physicochemical properties for permeant molecules and polyion complex membrane prepared by complexation between SA and chitosan were determined by using molecular modeling methods, and the permeation behaviors of water and alcohol molecules through the PIC membrane have been investigated. In the case of penetrant molecule, the experimental results showed that the prepared membrane was excellent pervaporation performance result in most solution, and the selectivity and permeability of the membrane were dependent on the molecular size, the polarity and the hydrophilic surface of permeant organics. However, the separation behavior of methanol aqueous solution exhibited other permeation tendency with other feed solutions and contradictory result. That is, the membrane were preferentially permeable to methanol over water despite water molecule has stronger polarity and small molecular size than methanol molecule. In this study, the results were discussed from the viewpoint of chemical and physical properties between permeant molecules and membrane in the diffusion state.

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폴리이서설폰 비대칭 기체분리막의 제조와 분리성능 (Preparation of Asymmetric Polyethersulfone Membrane and its Gas Separation Performance)

  • 함문기;손우익;이용택;김정훈;이수복
    • 멤브레인
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    • 제10권3호
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    • pp.130-138
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    • 2000
  • 건/습식 상전환법을 이용하여 비대칭 polyethersulfone (PES) 기체분리막을 제조하였으며, $CO_2$, $N_2$등의 기체에 대한 투과특성을 조사하였다. 분리막 제조에 있어서 주요 변수인 캐스팅 용액과 증발시간 등이 분리막의 구조에 미치는 영향을 파악하고 투과특성을 조사하여 최적의 제조조건을 확립하였다. 또한 제조된 분리막의 표피층에 존재하는 pin-hole과 같은 결점을 보완하기 위하여 실리콘 수지를 코팅하여 그 투과특성의 변화를 조사하였다. 실리콘 수지 코팅이 결점을 보완하는데 효과적임을 확인하였다. 본 연구에서 분리막 제조에 주로 사용한 캐스팅 용액은 PES, 14-methyl-2-pyrrolidone, 아세톤, 에탄올로 구성되었으며, 응고제로는 증류수를 사용하였다. 캐스팅 용액 중의 PES 함량이 높아질수록, 휘발성 유기용매의 비율이 높아질수록, 증발시간이 길수록, 에탄을 첨가제의 농도가 낮을수록 $CO_2$/$N_2$의 선택도는 높아지고 투과도는 낮아지는 결과를 보였다. 최적의 분리막 제조조건 하에서 얻어진 분리막의 분리성능은 $CO_2$/$N_2$의 선택도가 61이고 $CO_2$의 투과도는 21 GPU인 우수한 결과를 보였다.

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SEPARATION AXIOMS ON BI-GENERALIZED TOPOLOGICAL SPACES

  • Ray, A. Deb;Bhowmick, Rakesh
    • 충청수학회지
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    • 제27권3호
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    • pp.363-379
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    • 2014
  • In this paper, introducing various separation axioms on a bi-GTS, it has been observed that such separation axioms actually unify the well-known separation axioms on topological spaces. Several characterizations of such separation properties of a bi-GTS are established in terms of ${\gamma}_{{\mu}_i,{\mu}_j}$-closure operator, generalized cluster sets of functions and graph of functions.

유기물 분리용 투과증발막

  • 박현채
    • 한국막학회:학술대회논문집
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    • 한국막학회 1996년도 심포지움시리즈 Jan-96 투과증발막과 응용
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    • pp.69-90
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    • 1996
  • In the chemical industry, in the pharmaceutical industry, and in a number of other industries separation processes are necessary to separate and purify products and raw materials [1,2]. Separation processes are also widely used in other applications such as in recycling valuable materials from waste streams. Unit operations for separation processes can be classified in phase separation techniques and component separation techniques based on the nature of the feed mixtures to be separated. The former techniques are used for the separation of heterogeneous mixtures, in which the feed is already present in two or more separated phases on a micro-scale. The latter are suitable for the separation of homogeneous mixtures such as gaseous mixtures and mixtures of completely miscible liquids. tn these cases the separation into individual components is generally achieved by utilizing the differences in physico-chemical properties of components, and is much more difficult compared to phase separation techniques. Separation processes such as distillation, evaporation, liquid-liquid extraction, and crystallization belong to this class.

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컴팩트 타입 실리카막 공정을 이용한 수소 분리 (Hydrogen Separation by Compact-type Silica Membrane Process)

  • 문종호;배지한;이상진;정종태;이창하
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2006년도 추계학술대회
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    • pp.336-339
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    • 2006
  • With the steady depletion off fossil fuel reserves, hydrogen based energy sources become increasingly attractive. Therefore hydrogen production or separation technologies, such as Bas separation membrane based on adsorption technology, have received enormous attention in the industrial and academic fields. In this study, the transport mechanisms of the MTES (methyltriethoxysilane) templating silica/a-alumina composite membrane were evaluated by using unary, binary and quaternary hydrogen gas mixtures permeation experiments at unsteady- and steady-states. Since the permeation flux in the MTES membrane, through the experimental and theoretical study, was affected by molecular sieving effects as well as surface diffusion properties, the kinetic and equilibrium separation should be considered simultaneously in the membrane according to molecular properties. In order to depict the transient multi-component permeation on the templating silica membrane, the GMS (generalized Maxwell-Stefan) and DGM (dust Bas model) were adapted to unsteady-state material balance

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S-D간격 변화에 따른 광양자의 경로와 생체조직의 계층성에 대한 실험적 연구 (An Experimental Study for the Relationship of Photon Flux Path ann Layered Properties of Biological Tissue with S- D Separation)

  • 고한우
    • 대한의용생체공학회:의공학회지
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    • 제15권1호
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    • pp.35-40
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    • 1994
  • 생체조직의 계층성과 광양자속의 경로간의 관계를 연구하기 위하여 어레이형의 프로부를 설계하였다. S-D간격이 변함에 따라서 광원의 파장이 다르면 광은 서로 다른 경로를 가지며, 최대 리플렉턴스의 위치도 달랐다. 설계된 프로브로 측정된 최대 리플렉턴스시의 S-D간격은 7.5mm, 청색은 2.5mm 이었으며 광이 조직내를 투과 및 반사될 때 조직에 따라 주 경로가 있으며, S-D 간격을 변화시키면서 리플렉턴스를 측정하므로서 조직의 계층성을 평가할 수 있었다.

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