• Title/Summary/Keyword: separation process

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The Separation of Particulate within PFC Decontamination Wastewater Generated by PFC Decontamination (PFC 제염 후 발생된 제염폐액 내 오염입자의 제거)

  • Kim Gye-Nam;Lee Sung-Yeol;Won Hui-Jun;Jung Chong-Hun;Oh Won-Zin;Park Jin-Ho;narayan M.
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.32-39
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    • 2005
  • When PFC(Perfluorocarbonate) decontamination technology is applied to removal of radioactive contaminated particulate adhered at surface during the operation of nuclear research facilities, it is necessary to develop a filtration equipment to reuse of PFC solution due to high price, also to minimize the volume of second wastewater. Contaminated characteristics of hot particulate was investigated and a filtration process was presented to remove suspended radioactive particulate from PFC decontamination wastewater generated on PFC decontamination. The range of size of hot particulate adhered at the surface of research facilities measured by SEM was $0.1{\sim}10{\mu}m$. Hot particulate of more than $2{\mu}m$ in PFC contamination wastewater was removed by first filter and then hot particulate of more than $0.2{\mu}m$ was removed by second filter. Results of filter experiments showed that filtration efficiency of PVDF(Poly vinylidene fluoride), PP(Polypropylene), Ceramic filter was $95{\sim}97\%$. A ceramic filter showed a higher filtration efficiency with a little low permeate volume. Also, a ceramic of inorganic compound could be broken easily on experiment and has a high price but was highly stable at radioactivity in comparison of PVDF and PP of a macromolecule which generate $H_2$ gas in alpha radioactivity environment.

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Evaluation of Emulsion Stability for Cosmetic Facial Cream Emulsion Using Mixed Nonionic Emulsifier (비이온성 혼합유화제를 이용한 화장용 크림 유화액의 유화안정성 평가)

  • Hong, In Kwon;Kim, Su In;Park, Bo Ra;Choi, Junho;Lee, Seung Bum
    • Applied Chemistry for Engineering
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    • v.27 no.5
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    • pp.527-531
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    • 2016
  • Emulsification is a fundamental process of cosmetics manufacture which produces stabilized emulsion by dispersing the liquid from the one side to the other by adding an emulsifier in an immiscible liquid. Various types of emulsifiers can produce various cosmetics. In this study, we evaluated the stability of emulsifier by measuring variations in the viscosity, particle size and particle size distribution. HLB values of nonionic emulsifiers which are used in this paper are 12.9, 12.9, 12.6 and 12.5 for EMU-01, EMU-02, EMU-03 and EMU-04, respectively. All types of emulsions showed an increase in the particle size and a decrease in the viscosity with the time. Also they showed a decrease in the particle size and an increase in the viscosity with respect to increasing the stirring speed. However, the stability of emulsions up to 56 days was secured by observing the non-separation of emulsions. In addition, the viscosity of the emulsions was measured in the order of EMU-01 > EMU-02 > EMU-03 > EMU-04 while the size of particles was measured in the order of $EMU-01{\approx}EMU-02$ > $EMU-03{\approx}EMU-04$. This indicates that our emulsion can be potentially used for preparing a cosmetic facial cream.

THE IATROGENIC DAMAGES OF THE FIRST MOLARS FOLLOWING THE STAINLESS STEEL CROWN RESTORATION THE SECOND PRIMARY MOLARS (제 2유구치 기성금관 수복에 따른 제 1대구치의 의원성 손상)

  • Bae, Ik-Hyun;Kim, Shin;Jeong, Tae-Sung
    • Journal of the korean academy of Pediatric Dentistry
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    • v.31 no.2
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    • pp.153-158
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    • 2004
  • Preformed stainless steel crown is an useful restorative material for the treatment of badly broken down primary teeth. However iatrogenic damage to adjacent teeth might occur during the process of tooth reduction. Such damages might lead to plaque accumulation and increase the risks of caries initiation. Especially the damage can make a problem in the first permanent molar. Purpose of this study was to investigate an iatrogenic damage to the first permanent molar during preparation of second primary molar for preformed stainless steel crown. Twelve children restored with preformed stainless steel crown to second primary molar were selected. Contact areas were separated with separation elastics, and tooth surfaces were cleaned. After taking negative impression using vinylpolysiloxane impression material, the specimens were examined by scanning electron microscope for the detection of iatrogenic damage. The prevalence of iatrogenic damage was 66.7% and variable appearances and So we can suggest that when preparing teeth for preformed stainless steel crown, we should be careful about adjacent teeth not to make an iatrogenic damage.

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The Effect of Residual Water on the Adsorption Process of Carbon Tetrachloride by Activated Carbon Pellet (활성탄에 의한 사염화탄소 흡착공정에서 잔존수분의 영향)

  • Jeong, Sung Jun;Lee, Dae Lo;Kim, Tae Young;Kim, Jin Hwan;Kim, Seung Jai;Cho, Sung Young
    • Korean Chemical Engineering Research
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    • v.40 no.6
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    • pp.694-702
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    • 2002
  • Activated carbons have been used as adsorbents in various industrial application, such as solvent recovery, gas separation, deodorization, and catalysts. In this study, the effects of residual water on the activated carbon adsorbent surface on the adsorption capacity of $CCl_4$ were investigated. Adsorption behavior in a fixed bed was studied in terms of feed concentration, flow rate, breakthrough curve and adsorption capacity for $CCl_4$. Desorption characteristics of residual water on activated carbon were also studied. The water contents of the activated carbon were varied in the range of 0-20%(w/w) and all experiments were performed at 298.15 K. The adsorption equilibrium data $CCl_4$ on the activated carbon were well expressed by Langmuir isotherm. The adsorption capacity of $CCl_4$ decreased with increasing residual water content. Desorption of residual water in activated carbon decreased expotentially with $CCl_4$ adsorption. The obtained breakthrough curves using LDF(linear driving force) model represented our experimental data.

The study of Rolled Steel Process Wastewater by Superconducting High Gradient Magnetic Separation (초전도 마그네트를 이용한 고구배 자기분리 열연강판 폐수처리에 관한 연구)

  • Kim, Tea-Hyung;Ha, Dong-Woo;Oh, Sang-Soo;Kim, Ho-Sup;Ko, Rock-Kil;Kwon, Jun-Mo;Lee, Nam-Jin;Kim, Young-Hun;Kang, Chae-Hun;Ha, Tae-Wook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.05a
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    • pp.11-11
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    • 2009
  • 종래의 산업폐수 처리기술로는 중금속 함유 폐수에 수용성의 금속염을 첨가하여 가성소다 혹은 소석회를 이용하여 pH를 조정하고 고분자 응집제를 첨가하여 금속의 수산화물을 생성시켜 이를 부상 혹은 침전시켜 Sludge화하여 제거하는 방법이 주로 사용되고 있다. 그 외 질소, 인, 유기물이 함유된 폐수의 경우에는 Biological Oxidation Techniques, 활성탄 흡착방식이 주로 채택되고 있다.[1-3] 이러한 폐수처리기술은 화학약품 사용량이 과다하고 이는 Sludge 생성량을 증대하고 2차 폐수처리가 필요로 하는 경우가 많고, 처리장이 면적이 넓어야 하고 대용량의 Sludge 제거창치가 필요하여 고비용의 처리공정으로 문제점을 가지고 있다.[2-3] 이에 본 연구에서는 이러한 기존 기술의 문제점을 보완할 수 있고 기존 기술로는 완벽하게 처리하기 곤란한 악성 폐수들에 대한 새로운 고도처리기술로 초전도 마그네트를 이용한 고구배 자기분리기술에 대한 기초연구를 하였다. 본 연구에서 사용한 고구배 자기분리 시스템은 무헬륨 전도냉각방식으로 자기분리를 위해 사용한 필터는 SUS 430 재질의 메쉬 형태로 제작하여 실험하였다. 또한, 자기분리 처리를 위한 전처리 공정으로는 응집제를 첨가하여 자기분리 효율을 높이고자 하였다. 자기분리 처리대상수로는 포항제철에 압연 강판에 사용되는 냉각수를 대상으로 자기분리 처리에 대한 효과를 실험하였다. 또한, 자기분리에 대한 특성을 평가하기 위해 강자성의 $Fe_3O_4$ 미세자성분말을 첨가하여 처리수내의 들어있는 유기물질에 대해 자기분리 자장 및 유속에 대한 처리효율을 미치는 영향을 조사하였다. 자기분리 처리는 1~6 Tesla에서 자기필터는 디스크 형태로 다층으로 연속적으로 적층하였으며, 처리유속은 1~4 l/min으로 하였다. 고농도인 처리폐수를 자가분리 인가 자장에 따라 처리하여 고농도에서는 70%, 저농도에서는 98 %까지 처리되었다. 또한, 자기분리용 필터는 SUS 430 재질의 mesh 망을 사용하였으며 인가자장 및 유속변화에 대한 실험 결과 탁도 및 농도는 필터 크기의 영향은 거의 차이가 없었으며 단지 인가자장 및 유속에 따라서 지수적으로 감소하였다. 자기분리된 용액 내 $Fe_3O_4$ 입도 분석 결과 자기분리 이전에 분포하던 $10\sim20\;{\mu}m$의 입자는 거의 제거되었으며 2 ${\mu}m$ 이하의 입자들은 실험 횟수에 따라 점점 직경이 작은 쪽으로 분포가 좁아졌으며, 마그네타이트의 자화율을 분석한 결과 약 0.8 Tesla에서 포화 되었으며 처리수의 탁도 및 농도가 자장에 따라 감소하는 것으 알 수 있었다.

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Studies on the Removal of Silica from the Boric Acid Solution by Reverse Osmosis Membrane Process (역삼투막 공정을 이용한 붕산수 중의 실리카 제거에 관한 연구)

  • 구본문;임지원;이태원;박길웅
    • Membrane Journal
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    • v.5 no.4
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    • pp.137-144
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    • 1995
  • This studies concern the separation of aqueous boric acid solution and same solution containing silica using cellulose acetate RO S/W 4040 module manufactured by Hydranautics Co. The operating conditions of the applied pressures, temperatures, and feed flow rate are also investigated to characterize the permeabilities, biroc acid recovery, and silica rejection, so that the optimum operating conditions would be found out. In the case where the operating conditions are the temperature 35$^{\circ}$C, The pressure 20atm, and the feed flow rate 2.82 l/min, for the boric acid aqueous solution, the boric acid recovery 58.7% and the permeation rate 2.82 l/min were obtained. And also the results showed the boric acid recovery 68.1% and the permeation rate 1.56 l/min at the operating conditions, 35$^{\circ}$C and 10atm. For the boric acid solution containing silica, when the feed solution are at the conditions of 35$^{\circ}$C and 3.2atm, the boric acid recovery 69.7%, the silica rejection 97.5% and the permeation rate 0.47 l/min were obtained. And the operating conditions were at 35$^{\circ}$C, 20atm and the feed flow rate 2.92 l/min, the results showed the boric acid recovery 56.4%, the silica rejection 96.1% and the permeation rate 2.72 l/min.

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Removal/Recovery of VOCs Using a Rubbery Polymeric Membrane (Rubbery 고분가 막을 이용한 휘발성 유기화학물의 제거 및 회수)

  • Cha, Jun-Seok
    • Membrane Journal
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    • v.6 no.3
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    • pp.173-181
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    • 1996
  • Common volatile organic compounds(VOCs) such as toluene and methanol were removed successfully from N$_{2}$ using a novel silicone-coated hollow fiber membrane module. This novel membrane is a thin film composite(TFC) and was highly efficient in removing VOCs selectively from a N$_{2}$ stream. This membrane had some innate advantages over other silicone-based membrane in that the selective barrier was ultrathin(~1 $\mu$m) and the porosity of the polypropylene substrate was high which leads to a low permeation resistance. The substram was very strongly bonded to the coating layer by plasma polymerization and can withstand a very high pressure. A small hollow fiber module having a length of 25cm and 50 fibers could remove 96~99% of toluene as well as methanol vapors when the feed flow rate was up to 60cc/min. The percent removal of VOCs were even higher when the feed inlet concentration was higher. This process is especially suitable for treating streams having a low flow rate and high VOCs concentration. The permeances of VOCs through this membrane was in the range of $4~30 \times 10^{-9}gmol/sec \cdot cm^{2}\cdot cmHg$ for both toluene and methanol, and nitrogen permeance was between $3~9 \times 10^{-10}gmol/sec \cdot cm^{2} \cdot cmHg$. High separation factor between 10~55 for toluene/N$_{2}$ and 15~125 for methanol/N$_{2}$ were obtained depending on the feed flow rate ranges and feed VOCs concentration levels.

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Extraction of Pigment from Sea Mustard ( Undaiia pinnatinda) using Supercritical Carbon Dioxide and Entrainer (초임계 이산화탄소와 보조용매를 이용한 미역으로부터 색소 추출)

  • HONG Seok-Ki;CHUN Byung-Soo;PARK Sun-Young
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.34 no.3
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    • pp.213-217
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    • 2001
  • In order to develop a new separation technology, supercritical fluid extraction process was used to produce high purity pigments and fatty acids from seaweed (Undaria pinnatifida). Supercritical carbon dioxide was used as a solvent and ethanol as an entrainer. The sample was treated by a frozen drier and experiments were conducted with a semi-batch flow system at various operating conditions (pressure range, $10.3\~17.2$ MPa; temperature range, $30\~45^{\circ}C$: particle size, $500\~1,000{\mu}m$ extraction time, 60 min). Characteristics of the recovered pigment (chlorophyll a) and fatty acids were determined by UV-spectrophotometry and gas chromatography, respectively. The highest extraction efficiency for fatty acids and pigments was achieved at 12.4 MPa, $35^{\circ}C$, $500{\mu}m$of seaweed size.

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The Study on Identifying the Components of Community Pharmacy Externship Based on Korean Community Pharmacists' Consensus (약학교과과정의 개국약국실습 방향에 관한 연구)

  • Kim, Sung Hyun;Oh, Jung Mi
    • Korean Journal of Clinical Pharmacy
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    • v.9 no.2
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    • pp.109-118
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    • 1999
  • The need for and components of a contemporary community pharmacy externship for pharmacy students have not been clearly identified in Korea. Mail survey was performed among 20 college of pharmacy deans and 800 community pharmacists to analyze the current status and develop a consensus regarding major focus area and criteria of community pharmacy externship to be implemented under the separation of dispensary from medical practice in year 2000. Mail survey yielded $80\%\;and\;23.5\%$ response rate for pharmacy school deans and community pharmacists, respectively. Of the 16 pharmacy schools that responded 14 said they have externship program in hospital pharmacy, and only 8 pharmacy schools responded of having externship program for community pharmacy. However, these community pharmacy programs lacked criteria and standard guideline for the externship. The results of survey revealed that community pharmacy externship program for students should be organized and directed toward developing expert knowledge and skills in pharmacy practice activities, clinical services, communications, pharmacy management, and professionalism. Pharmacy practice components should include competencies and skills in computer application, prescription processing, dispensing, pharmaceutical compounding, Narcotics Control Law application, maintenance and provision of drug information, and laws and regulations. Clinical service components should include the ability to identify patient's drug-related problems, provide long-term patient care and appreciate drug therapy services. Communication skills should be taught to effectively express his/her professional opinion, deduce the needs of others, utilize appropriate techniques and media to communicate ideas and conduct a patient interview and to obtain patient drug history. Pharmacy management skills should be taught to be efficient in medical insurance and drug control process. It was found that professionalism, morality, pharmacy practice experience, ability to provide clinical services, collect and provide drug information and regality are important criteria of preceptors. Externship sites should possess the ability to stock various drugs, access and provide diverse pharmacy services and should have private patient counseling area. Most pharmacists agreed that top 200 drugs' generic and brand name, indications, dosage, side effects, and contraindication should be instructed during the externship. It was also found that student and preceptor should be evaluated for their performances during the externship. This information will be incorporated into teaming objectives for students and to develop Academic Extemship Program Guidelines.

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Perceptual cues for /o/ and /u/ in Seoul Korean (서울말 /?/와 /?/의 지각특성)

  • Byun, Hi-Gyung
    • Phonetics and Speech Sciences
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    • v.12 no.3
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    • pp.1-14
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    • 2020
  • Previous studies have confirmed that /o/ and /u/ in Seoul Korean are undergoing a merger in the F1/F2 space, especially for female speakers. As a substitute parameter for formants, it is reported that female speakers use phonation (H1-H2) differences to distinguish /o/ from /u/. This study aimed to explore whether H1-H2 values are being used as perceptual cues for /o/-/u/. A perception test was conducted with 35 college students using /o/ and /u/ spoken by 41 females, which overlap considerably in the vowel space. An acoustic analysis of 182 stimuli was also conducted to see if there is any correspondence between production and perception. The identification rate was 89% on average, 86% for /o/, and 91% for /u/. The results confirmed that when /o/ and /u/ cannot be distinguished in the F1/F2 space because they are too close, H1-H2 differences contribute significantly to the separation of the two vowels. However, in perception, this was not the case. H1-H2 values were not significantly involved in the identification process, and the formants (especially F2) were still dominant cues. The study also showed that even though H1-H2 differences are apparent in females' production, males do not use H1-H2 in their production, and both females and males do not use H1-H2 in their perception. It is presumed that H1-H2 has not yet been developed as a perceptual cue for /o/ and /u/.