• Title/Summary/Keyword: separation of mixture

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Pervaporation separation of water/ethanol mixture through tubular zeolite membranes

  • Matsui, Shigetoshi;Ikeda, Madoka;Shinma, Shuji;Arano, Manabu;Mizoguchi, Kensaku;Ikeda, Shiro;Sawasaki, Toshiaki;Nakane, Takashi
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.98-101
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    • 2004
  • Utilization of biomass resources has considerable contribution to the reduction of carbon dioxide emission. Ethanol is one of the biomass products and is used as an additive to gasoline in several countries. Conventional process to produce ethanol involves energy-intensive azeotropic distillation. Pervaporation (PV) or vapor permeation (VP) is considered to be an alternative separation process to the conventional process.(omitted)

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Pervaporation of aqueous organic mixture through in situ complex membranes based on polycrylonitrile

  • Lee, Young-Moo;Oh, Boo-Keun
    • Proceedings of the Membrane Society of Korea Conference
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    • 1995.09a
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    • pp.39-55
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    • 1995
  • Modified polycrylonitrile(PAN) membranes were prepared by emulsion or emulsifier-free emulsion polymerization technique. Separation capacity was determined at several operating temperatures(25, 40, 55 and 70 $^{\circ}$C) to dehydrate 56wt% pyridine aqueous solution through modified PAN membranes having different functional groups. All these PAN-based membranes were selective toward water to different degrees depending on the nature of functional groups present in the membranes. Pervaporation characteristics of PAN-based membranes are so different and classified into three categories depending on the type of the functional groups in PAN copolymers. Among PAN-based membranes, the in-situ complex membranes show the best separation capacity over the operating temperatures.

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The Separation and Analysis of Babbitt Metal by the Cation Exchange Chromatographic Method (양이온 교환 크로마토그라피에 의한 Babbitt 금속의 분리 및 정량)

  • Sun Tae Kim;Kee Won Cha;Kee Chae Park
    • Journal of the Korean Chemical Society
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    • v.15 no.6
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    • pp.366-369
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    • 1971
  • The cation exchange chromatographic method for the analysis of Babbitt metal has been studied. The quantitative separation of the mixture of Sb, Cu, Pb, and Sn ions has been obtained by elution, through 5cm column of resin, Rexyn 101 (Na form, 100~200 mesh), using 0.1 M NaCl solution for Sb, pH 4.5 and pH 7 solution of 0.01 M Na-Citrate + 0.1 M $NaNO_3$ for Cu and Pb, and 2NHCl solution for Sn as eluent.

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Evaluation of Electrokinetic Flow Mobility Using Isotacho-Electrophoresis Techniques

  • An, J.H.;Joo, Y.H.;Lee, C.Y.;Lee, Y.J.;Park, C.W.
    • Journal of Magnetics
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    • v.16 no.4
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    • pp.444-448
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    • 2011
  • In the present study, we separated the marker particles from the suspending particle mixture solution using isotacho-electrophoresis technique, a novel quantitative ionic particle separation method, in the microchannel. A multiple stacking zone of the suspending particle was visualized with variations in electric field strength, pH value and concentration of the ionic solution. In particular, the electrophoretic mobility of ionic particle (fluorescein) was estimated based on the electrophoretic velocity value measured by the particle image velocimetry. As a result, isotacho-electrophoresis zones were clearly visualized as going downstream in the electric field. The particle migration velocity increased proportional to the applied voltage increase; it was also affected by the pH value variations in the ionic solution.

A Study on the Fiber Orientation and Fiber Content Ratio Distribution during the Injection Molding for FRP (FRP의 사출성형에 있어서 섬유배향상태와 섬유함유율분포에 관한 연구)

  • Kim J. W.;Lee D. G.
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2005.05a
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    • pp.252-257
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    • 2005
  • Injection molding is a very important industrial process for the manufacturing of plastics objects. During an injection molding process of composites, the fiber-matrix separation and fiber orientation are caused by the flow of molten polymer/fiber mixture. As a result, the product tends to be nonhomogeneous and anisotropic. Hence, it is very important to clarify the relations between separation' orientation and injection molding conditions. So far, there is no research on the measurement of fiber orientation using image processing. In this study, the effects of fiber content ratio and molding condition on the fiber orientation-angle distributions are studied experimentally. Using the image processing method, the fiber orientation distribution of weld-line in injection-molded products is assessed. And the effects of fiber content and injection mold-gate conditions on the fiber orientation are also discussed.

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Effect of Atmospheric Gas on the Size and Distribution of Cu Nano Powders Synthesized by Pulsed Wire Evaporation Method (전기 폭발법에 의해 제조된 나노 구리 분말의 크기와 분포에 미치는 조업 가스의 영향)

  • ;;;Y. A. Kotov
    • Journal of Powder Materials
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    • v.11 no.3
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    • pp.210-216
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    • 2004
  • The possibility to decrease agglomeration of Cu nano powders and their separation during pulsed wire evaporation (PWE) process was investigated by controlling the working gas system, i.e., the design of the gas path, the type and pressure of the atmospheric gas. As a result, it was possible to choose the optimal design of the gas path providing large specific surface area and high degree of separation of the synthesized Cu nano powders. It was also shown that an Ar+10∼50$N_2$ mixture can be used in production of Cu nano powders, which do not react with nitrogen.

A Study on Dry Film Formation of Clay Solution (점토 혼합액의 건조박막 형성에 관한 연구)

  • 박헌휘
    • Journal of Energy Engineering
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    • v.7 no.2
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    • pp.180-186
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    • 1998
  • In this study, the effect of shear rate on the viscosity variation is examined to understand the flow characteristics of the mixture of bentonite and water. The variation of film thickness according to mixing ratio and viscosity is measured to characterize the film formation. And, the separation of dried film is studied according to film thickness. Specific surface area affecting on adsorption capability is measured using BET method. The viscosity decreases and the film thickness increases as the mixing ratio increases. The separation characteristic of dried film is suitable within a range of 40 to 150 ${\mu}{\textrm}{m}$ in film thickness and 5 to 10% in mixing ratio.

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Comparison of Size-Exclusion Chromatography and Flow Field-Flow Fractionation for Separation of Whey Proteins

  • Kang, Da-Young;Moon, Jae-Mi;Lee, Seung-Ho
    • Bulletin of the Korean Chemical Society
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    • v.32 no.4
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    • pp.1315-1320
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    • 2011
  • Whey protein (WP) is a mixture of proteins, and is of high nutritional values. WP has become an important source of functional ingredients in various health-promoting foods. In this study, size-exclusion chromatography (SEC) and asymmetrical flow field-flow fractionation (AsFlFFF) were used for separation and analysis of whey proteins. It was found that a lab-prepared WP from raw milk is mostly of ${\beta}$-lactoglobulin with small amount of higher molecular weight components, while a commercial whey protein isolate (WPI) powder contains relatively larger amount of components other than ${\beta}$-lactoglobulin, including IgG and protein aggregates. Results suggest that AsFlFFF provides higher resolution for the major whey proteins than SEC in their normal operation conditions. AsFlFFF could differentiate the BSA and Albumin, despite a small difference in their molecular weights, and also was able to separate much smaller amount of aggregates from monomers. It is noted that SEC was able to show the presence of low molecular weight components other than the major whey proteins in the WP samples, which AsFlFFF could not show, probably due to the partial loss of those low molecular weight species through the membrane.

Separation of Fe(Ⅱ) from Co(Ⅱ), Ni(Ⅱ), Pb(Ⅱ) Using Amberlite IRA 400 Loaded with Alizarin Red S (Alizarin Red S가 결합된 Amberlite IRA 400 에 의한 Co(Ⅱ), Ni(Ⅱ), Pb(Ⅱ) 중 Fe(Ⅱ)의 분리)

  • Cha, Ki Won;Park, Chan Il;Kang, Ji Soo
    • Journal of the Korean Chemical Society
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    • v.42 no.2
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    • pp.172-176
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    • 1998
  • An anion exchange resin which has Alizarin Red S (ARS) as functional group was prepared by batch method. The resin is stable in acidic solutions below 0.5 M hydrochloric acid, nitric acid and sulfuric acid and adsorption capacity of Fe(Ⅱ) ion on the resin was larger than other metal ions. The preconcentration and the separation of Fe(Ⅱ) ion from the mixture solution were carried out with the pH 4.5 buffer solution and 0.1 M $HNO_{3}$ as eluents.

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Characterization of Organic Solvent Resistant Membranes

  • 전종영;김윤조;탁태문
    • Proceedings of the Membrane Society of Korea Conference
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    • 1994.10a
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    • pp.62-63
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    • 1994
  • The membrane technology is more convenient and economical way in the separation field than conventional technology such as distillation, extration, crystallization, and so on. Therefore, membrane are used as efficient tools for the separation and concentration of molecular mixture in many industrial area. Although the polymeric membrane have various advantage, they have disadvantages as well. One of them is a poor resistance to organic solvent. Therefore, organic solvent resistant membranes were prepared by soluble polyimide. prepared by phase inversion method. The membranes were The homogeneous polymer solutions were obtained by the two different method ; the one is that the polymer sythesized was completely dissolved in a solvent to prepare a membrane casting solution, the other is that a membrane casting solution was prepared by the unit process from the viscose solution of polymerization.

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