• Title/Summary/Keyword: semi-continuous

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Semi-continuous Emulsion Polymerization of n-Butyl acrylate/Methyl metacrylate using Environmental-Friendly LE-Type Nonionic Surfactant (환경친화적 LE-형 비이온계면활성제를 사용한 반연속식 말브틸-아크릴레이트/메틸메타-아크릴레이트 유화중합에 관한 연구)

  • Kim, Chul-Ung
    • Clean Technology
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    • v.11 no.1
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    • pp.41-50
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    • 2005
  • In this study, semibatch emulsion copolymerization of n-BA as adhesive component and MMA as coagulant component were carried out for the stable acrylic polymer latex in aqueous phase for polymer cement using LE-type nonionic surfactant as environmental friendly surfactant. The stable polymer emulsion was obtained with the increases of chain length(n) of this surfactant. The effect on the amount of LE-50 as nonionic surfactant were showed that the concentration of polymer latex were increased by increasing the amount of LE-50, whereas the average particle size were decreased by increasing the amount. The addition of functional monomer in initial reactor charge showed a significant effect on the final polymer concentration and the latex particle size. The single polymerization of each n-BA or MMA showed a very low concentration of polymer latex and very big particle size due to coagulation. In the polymerization composed of mixed monomer with MMA and n-BA, the larger the ratio of MMA to n-BA in the copolymers, the greater the amount of coagulum produced. It was found that a stable copolymers were obtained in the range of 15-35 % of n-BA. Moreover, incorporation of some functional monomers in addition to of main monomers became more stable polymer latex. Through DSC and IR analysis, the final polymer latex was composed by MMA/n-BA/AA/AM with a single Tg depending on the reaction conditions. As a result, the conditions of this acrylic polymerization could also be effectively controlled to get the desired final products.

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Effect of Surfactant Type on the Particle Size and Yield in Semi-Continuous Emulsion Polymerization of n-Butyl Acrylate/Methyl Metacrylate (반연속식 노말브틸-아크릴레이트/메틸메타-아크릴레이트 유화중합(1) : 폴리머 라텍스의 수율과 입자크기에 관한 계면활성제 종류의 영향)

  • Ko, Ki-Young;Kim, Sung-il;Kim, Chul-Ung;Hyung, Gi-Woo
    • Clean Technology
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    • v.11 no.1
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    • pp.1-12
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    • 2005
  • In these studies, semibatch emulsion copolymerization of n-butyl acrylate (n-BA) as adhesive component and methyl metacrylate (MMA) as coagulant component was carried out in order to investigate the role of surfactant in aqueous phase for polymer cement. It was found that the particle size and concentration of final polymer are affected by surfactant type used. The effect of nonionic surfactants was shown in the decrease of polymer emulsion concentration and small emulsion particle in order of LE-50, NP-50 > CE-50, Tween 20 > TX-405 > Brij 35. In LE and NP (n=7-50) as nonionic surfactant, it could be obtained the stable polymer emulsion of 40% in aqueous phase with average particle size of 250-320 nm using over n=30. On the other hand, the effect of surfactant type in initial reactor charge was shown that when SDS as ionic surfactant was used, the polymer emulsion concentration was constant irrespective of the amount used, whereas CTAB as cationic surfactant and HN-100 as reactive surfactant were shown a tendency to the decrease of that. The effect surfactant type on final polymer particle size was shown in decrease by the order of SDS > CTAB > HN-100.

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Factors Influencing Protoplast Isolation and Culture in Three Capsicum Species (세 가지 고추속 식물의 원형질체 분리 및 배양에 미치는 요인)

  • 임학태;염옥희;전익조;조미애;양승균
    • Korean Journal of Plant Tissue Culture
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    • v.28 no.3
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    • pp.141-146
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    • 2001
  • Protoplasts were isolated from cotyledons, hypocotyls, and mesophyll tissues of three species of Capsicum species (C. anuumm, C. bacatuum, and C. chacoense). Combination of Cellulysin (1%) and Macero-zyme (0.25%) in 0.65 M sorbitol was found to be the most effective for the digestion of cell wall, regardless of the Capsicum species. Antioxidant MES (2-[N-Morpholino]ethanesulfonic acid) in the enzyme solution helped protoplasts overcome browning. After 5 days of initial culture, Cell division occurred in modified K8p medium containing 1~5 mg/L zeatin, 0.5 mg/L IAA, 0.1~0.5 mg/L TDZ, and 1 mg/L 2,4-D under continuous dark condition at $25^{\circ}C$. Semi-solid agarose culture method was more effective than liquid culture, and it also protected the cells from browning caused by polyphenolic compound released during protoplast culture. A total of 4000 calli were obtained from protoplast culture of different capsicum species. All of these calli were transferred to the 100 combinations of regeneration media using various plant growth regulators; TDZ, IAA, 2ip, BAP, NAA, and zeatin. These calli derived from protoplast of three species of capsicum were, however, not differentiated into shoots.

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Influence of Temperature and pH on Fermentation Pattern and Methane Production in the Rumen Simulating Fermenter (RUSITEC)

  • Bhatta, R.;Tajima, K.;Kurihara, M.
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.3
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    • pp.376-380
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    • 2006
  • An experiment was conducted to study the effect of temperature and pH on in vitro nutrient degradability, volatile fatty acid profile and methane production. The fermenter used was the semi-continuous system, known as the rumen simulation technique (RUSITEC). Sixteen cylinders were used at one time with a volume of 800 ml, the dilution rate was set at 3.5%/hour, the infused buffer being McDougall's artificial saliva. Basal diet (9.6 g DM) used in RUSITEC consisted of (DM) 6.40 g Timothy hay, 1.86 g crushed corn and 1.34 g soybean meal. The food for the fermentation vessel was provided in nylon bags, which were gently agitated in the liquid phase. The experiment lasted for 17 d with all the samples taken during the last 5 d. Treatments were allocated at random to four vessels each and were (1) two temperature levels of $39^{\circ}C$ and $41^{\circ}C$ (2) two pH levels of 6.0 and 7.0. The total diet contained ($g\;kg^{-1}$ DM) 957 OM, 115 CP and $167MJ\;kg^{-1}$ (DM) GE. Although increase in temperature from $39^{\circ}C$ to $41^{\circ}C$ reduced degradation of major nutrients in vitro, it was non-significant. Interaction effect of temperature with pH also reflected a similar trend. However, pH showed a significant (p<0.05) negative effect on the degradability of all the nutrients in vitro. Altering the in vitro pH from 7 to 6 caused marked reduction in DMD from 60.2 to 41.8, CPD from 76.3 to 55.3 and GED from 55.3 to 35.1, respectively. Low pH (6) depressed total VFA production (61.9 vs. 34.9 mM) as well as acetate to propionate ratio in vitro (from 2.0 to 1.5) when compared to pH 7. Compared to pH 7, total gas production decreased from 1,841 ml to 1,148 ml at pH 6, $CO_2$ and $CH_4$ production also reduced from 639 to 260 ml and 138 to 45 ml, respectively. This study supported the premise that pH is one of the principal factors affecting the microbial production of volatile fatty acids and gas. Regulating the ruminal pH to increase bacterial activity may be one of the methods to optimize VFA production, reduce methane and, possibly, improve animal performance.

A study on vibration control of the engine body for a large scale diesel engine using the semi-active controlled hydraulic type of top bracing (준능동형 유압식 톱브레이싱을 이용한 선박용 저속 2행정 디젤엔진의 본체 진동제어)

  • Lee, Moon-Seek;Kim, Yang-Gon;Hwang, Sang-Jae;Lee, Don-Chool;Kim, Ue-Kan
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.6
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    • pp.632-638
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    • 2014
  • Nowadays, as part of an effort to increase the efficiency of propulsion shafting system, the revolution of the main diesel engine in CMCR(Contract Maximum Continuous Rating) is reduced whereas the stiffness of hull structure supporting the main diesel engine is relatively flexible. However, vibration problems related with resonant response of main diesel engine are increasing although top bracing is installed between the main diesel engine and the hull structures to increase natural frequency of engine body above CMCR to avoid resonant phenomenon. In this study, the dynamic characteristic of top bracing is reviewed by analyzing measuring results of general cargo ships which apply the hydraulic type instead of the friction type to control the natural frequency and the vibration of the engine body. Moreover, considering the vibration characteristic of the engine body and the hydraulic type of the top bracing by varying the number of top bracing, authors suggest the more effective way to control the vibration of the engine body despite of lower stiffness of the hull structure than in the past when the hydraulic type of top bracing is used.

Analysis of Effects on SWAT Estimation of Warm-Up Period

  • Lee, Ji-Won;Moon, Jong-Pil;Woo, Won-Hee;Kum, Dong-Hyuk;Kim, Ki-Sung;Lim, Kyoung-Jae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2011.05a
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    • pp.260-260
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    • 2011
  • SWAT is semi-distributed and continuous-time distributed simulation watershed model, which can simulate point and nonpoint source pollutants as well as hydrology and water quality. It was developed to predict the effects of alternative management decisions on water, sediment, and chemical yields with reasonable accuracy. It is able to predict and manage hydrology, sediments, nutrients, and pesticides with Best Management Practices (BMPs) in a watershed. SWAT model also has potential for use in ungauged basins to predict streamflow and baseflow from saturated source area in watersheds. According to various cultivation practices and climate change, SWAT model is available to analyze relative change in hydrology and water quality. In order to establish optimum management of water quality, both monitering and modeling have been conducted actively using SWAT model. As SWAT model is computer program to simulate a lot of natural phenomena, it has limitation to predict and reflect them with on hundred percent accuracy. Thus, it is possible to analyze the effect of BMPs in the watershed where users want to simulate hydrology and water quality only if model accuracy and applicability are assessed first of all and the result of it is well for the study watershed. For assessment of SWAT applicability, most researchers have used $R^2$ and Nash and Sutcliffe Efficiency (NSE). $R^2$ and NSE are likely to show different results according to a warm up period and sometimes its results are very different. There have been hardly any studies of whether warm up period can affect simulation results in SWAT model. In this study, how warm up period has a effect on SWAT results was analyzed and a appropriate warm up period was suggested. Lots of SWAT results were compared after using measured data of Soyanggang-dam watershed and applying various warm up period (0 ~ 10 year(s)). As a result of this study, when there was no warm up period, $R^2$ and NSE were 0.645, 0.602 respectively, when warm up period was 2 years, $R^2$ and NSE were 0.648, 0.632, and when warm up period was 4 years, $R^2$ and NSE were 0.663, 0.652 separately. Through this study, sensitive analysis of warm up period in SWAT model was conducted, and this study could give a guideline able to simulate hydrology and water quality for more accuracy than before as users change a lot of warm up periods as well as any simulation parameters.

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Variation Pattern Analysis on the Air and Surface Water Temperatures of the Yellow Sea Monitoring Buoy (황해중부부이에서 관측된 기온 및 표층수온의 변화양상 분석)

  • Cho, Hong-Yeon;Jeong, Jin-Yong;Shim, Jae-Seol;Kim, Seon-Jeong
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.22 no.5
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    • pp.316-325
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    • 2010
  • Harmonic analyses are carried out in order to obtain the major frequency components of the air temperature (AT) and surface water temperature (SWT) data monitored in the Middle Area of the Yellow Sea (Yellow Sea monitoring buoy). The analysis shows the annual and semi-annual components are predominant and the higher frequency components are relatively weak with contribution to the short fluctuations, i.e. below $0.2{\sim}0.5^{\circ}C$, in the AT and SWT. The standard deviation of the AT residual is 2.4 times larger than that of the SWT residual and the occurrence frequency distributions of the AT and SWT residual components are both closely fitted to a normal-distribution function. The variation pattern on the AT-SWT plane forms the clear continuous hysteresis loop in anti-clockwise direction which is composed of the AT-SWT rising period, AT-SWT falling period, and the constant SWT period in winter season.

Change of fatty acid compositions of rotifer according to enrichment diets and methods in the high density culture (고밀도 배양에 있어서 영양강화 방법 및 종류에 따른 rotifer의 지방산 조성의 변화)

  • PARK Heum Gi;LEE Kyun Woo;LEE Sang-Min;KIM Sung Koo;KIM Hyung Sun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.32 no.6
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    • pp.748-752
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    • 1999
  • This study was carried out to compare the growth and fatty acids composition of the rotifer (Brachionus rotundiformis) cultured in high density by the various enrichments and culture methods. The rotifer fed on condensed freshwater Chlorella was enriched with $\omega$-yeast, Algamac, Super Selco and marine Chlorella. In another culture method, the rotifer was cultured with enrichment supplements for 6 hours after feeding with condensed freshwater Chlorella supplement for 18 hour. The rotifer fed with condensed marine Chlorella for 24 hours without fieshwater Chlorella was used as a control group. Culture tanks (5 $\ell$ working volume) was immersed in a water bath ($28^{\circ}C$). The density of rotifer and dissolved oxygen level in water was stable in control group of rotifer cultured with condensed marine Chlorella for 24 hours and the n-3 HUFA content of rotifer was the highest among the rotifer culture methods. However, the density of rotifer and dissolved oxygen level in the groups of rotifers enriched with $\omega$-yeast, Algamac and Super Selco by methods were drastically decreased, The n-3 HUFA contents of rotifers enriched by Super Selco were higher than those of rotifer enriched by either $\omega$-yeast or Algamac in both methods. The results from this experiment indicated that supplementation of condensed marine Chlorella for 24 hour by the semi-continuous culture was effective for the improvement of the nutritional value of rotifer and it could provide the stable growth condition for rotifer culture in high density.

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Chemical Characteristics and Source Apportionment ofPM2.5 in Seoul Metropolitan Area in 2010 (2010년도 서울시 대기 중 PM2.5의 성분특성 및 발생원 추정에 관한 연구)

  • Moon, Kwang-Joo;Park, Seung-Myung;Park, Jong-Sung;Song, In-Ho;Jang, Sung-Ki;Kim, Jong-Chun;Lee, Seok-Jo
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.6
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    • pp.711-722
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    • 2011
  • This study is aimed to estimate the $PM_{2.5}$ source apportionment at Seoul intensive monitoring site located in Seoul metropolitan area. Time-resolved chemical compositions of $PM_{2.5}$ are measured in real time using ambient ion monitor, semi-continuous carbon monitor, and on-line XRF at Seoul intensive monitoring site in 2010. The mass concentration of $PM_{2.5}$ was simultaneously monitored with eight ionic species (${SO_4}^{2-}$, $NO_3{^-}$, $Cl^-$, $NH_4{^+}$, $Na^+$, $K^+$, $Mg^{2+}$, $Ca^{2+}$), two carbonaceous species (OC and EC), and fourteen elements (Si, K, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Zn, As, Se, Pb) in 1-hr interval. The data sets were then analyzed using EPA PMF version 3 to identify sources and contributions to $PM_{2.5}$ mass. EPA PMF modeling identified eight PM2.5 sources, including soil dust, secondary sulfate, secondary nitrate, motor vehicle, coal combustion, oil combustion, biomass burning, and municipal incineration. This study found that the average $PM_{2.5}$ mass was apportioned to anthropogenic sources such as motor vehicle, fuel combustion, and biomass burning (61%) and secondary aerosols, including sulfate and nitrate (38%).

Recovery of High Unsaturated Fatty Acid from Squid Processing Wastes using Supercritical Carbon Dioxide Extraction Method (초임계 이산화탄소 추출법을 이용한 오징어 가공 부산물로부터 고도불포화 지방산 회수)

  • KANG Seong-Sil;KIM Byung-Jun;CHUN Byung-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.32 no.2
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    • pp.217-222
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    • 1999
  • A squid viscera oil contains a high content of EPA, DHA, and other valuable polyunsaturated fatty acids. The extractions of squid viscera oil by supercritical carbon dioxide both with/without $3\%$ (v/v) ethanol were performed in a semicontinuous flow extractor at 8.3 to 13.8 MPa and 25 to $50^{\circ}C$. When ethanol was added to $SC-CO_2$, the extraction ratio of lipid increased. The extracts contained high content of unsaturated oils like DHA and EPA. The highest extraction yield of lipid from squid viscera oil extracted by supercritical carbon dioxide was obtained at 12.4 MPa and $40^{\circ}C$ with/without entrainer. The main fatty acids of squid viscera oil extracted by supercritical carbon dioxide were myristric acid (14:0), palmitic acid (16:0), palmitoleic acid (16:1), oleic acid (18:1), arachidic acid (20:0), eicosapentaenoic acid (20:5), and docosahaxaenoic acid (22:6).

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