• Bulletin of the Korean Chemical Society
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• v.31 no.9
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• pp.2537-2541
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• 2010

We chose a fluorescent pentapeptide sensor (-CPGHE) containing a dansyl fluorophore as a model peptide and investigated whether the selectivity and sensitivity of the peptides for heavy and transition metal ions could be tuned by changing amino acid sequence. In this process, we developed a selective peptide sensor, Cp1-d (-HHPGE, $K_d\;=\;670\;nM$) for detection of $Zn^{2+}$ in 100% aqueous solution and a selective and sensitive peptide sensor, Cp1-e (-CCHPGE, $K_d\;=\;24\;nM$) for detection of $Cd^{2+}$ in 100% aqueous solution. Overall results indicate that the selectivity and sensitivity of the metallopeptide sensors to specific heavy and transition metal ions can be tuned by changing amino acid sequence.

• Analytical Science and Technology
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• v.8 no.4
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• pp.753-758
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• 1995

Thermal desorption/gas chromatography/mass selective detection method using Tenax cartridges for the determination of gaseous polycyclic aromatic hydrocarbons(PAH) is described. Glass fiber filter can collect only PAH in particulate. Gaseous PAH may penetrate the filter. Glass cartridge packed Tenax-GC was uses fur adsorption of gaseous PAH. The air of inhalation zone was collected fur 2-10 hours. Cartridges were thermally desorbed in the reverse direction to sample flow. The desorption conditions were as follows; desorption temperature; $300^{\circ}C$; desorption time; 20min; column head pressure; 30psi; inlet split vent; closed during desorption.

• Journal of Electrochemical Science and Technology
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• v.10 no.2
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• pp.185-195
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• 2019

The large surface area and the high electrical conductivity of graphene (GP) allow it to act as an "electron wire" between the redox center of biomolecules and an electrode surface. The faster electron transfer kinetics and excellent catalytic activity of GP facilitate the accurate and selective electrochemical detection of biomolecules. This mini-review provides an overview of the recent developments and progress of GP, functionalized or doped GP, and GP-composites based sensors for the selective and interference-free detection of dopamine (DA). The electrochemical principles and future perspective and challenges of DA sensors were also discussed based on GP.

• Bulletin of the Korean Chemical Society
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• v.19 no.2
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• pp.207-211
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• 1998

Potentiometric characteristics of DOS plasticized PVC-based membranes containing upper-rim calix[4]crown neutral carrier to various metal cations and protonated alkylamines have been examined. Although the calix[4]crown-based membrane electrodes exhibited substantial emf responses to alkali and alkaline earth metal cations, their high detection limits (- log[Cs+]=4.5) and sub-Nernstian response slopes (48 mV/pCs+) to the most selective cation, cesium, indicate that the metal cation complexing ability of calix[4]crown is much weaker than that of macrocyclic crown ethers. However, the calix[4]crown-based membrane electrodes exhibited near-Nernstian response slopes (56 mV/decade for hexylNH3+) with low detection limits (log[hexylNH3+]= - 6.7) to most alkylammonium ions compared to those of blank (DOS plasticized PVC membrane with no ionophore) or crown ether-based membranes. While the selectivity patterns of blank and crown ether-based membranes are determined primarily by the lipophilicity of alkylammonium ions, the membranes doped with calix[4]crown ionophore could effectively discriminate the steric shapes of nonpolar alkyl groups of alkylammonium ions.

• Journal of Sensor Science and Technology
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• v.31 no.4
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• pp.187-193
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• 2022

The accurate detection of environmental and biomarker gas species has attracted increasing attention due to their broad applications, such as air quality monitoring, disease diagnosis, and explosive chemicals detection. To accurately detect target gas species using chemiresistive gas sensors, using nanocatalysts on semiconducting metal oxides (SMOs) is considered the most promising approach. This review summarizes recent studies on methods for nanocatalysts functionalization on SMOs to achieve the highly selective gas sensors. To this end, we discuss various nanocatalyst decorated metal oxide-based chemiresistive gas sensors and provide an insight to construct highly accurate gas sensors.

• Journal of Integrative Natural Science
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• v.13 no.2
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• pp.41-46
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• 2020

A study is reported about the synthesis processes of various silacrown ether by the reaction of alkoxysilanes with polyethylene glycols (PEG) through transesterification. Crown ether-functionalized carbosilane dendrimers and hybrid crown ethers are also discussed. We will also address the solubility enhancement, phase-transfer catalysis of different silacrown as well as their application as Ion-selective electrodes (ISEs) and as active phase of PVC electrodes for the development of potentiometric sensors for detection of alkali-Ions.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.495-495
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• 2011

Miniaturized sensors capable of both sensitive and selective real-time monitoring of target analytes are tremendously valuable for various applications ranging from hazard detection to medical diagnostics. The wide-spread use of such sensors is currently limited due to insufficient selectivity for target molecules. We developed selective nanocoatings by combining trinitrotoluene (TNT) receptors bound to conjugated polydiacetylene (PDA) with single-walled carbon nanotube-field effect transistors (SWNT-FET). Selective binding events between TNT molecules and phage display derived TNT receptors were effectively transduced to sensitive SWNT-FET conductance sensors through the PDA coating. The resulting sensors exhibited unprecedented 1 fM sensitivity toward TNT in real time, with excellent selectivity over various similar aromatic compounds. Our biomimetic receptor coating approach may be useful for the development of sensitive and selective micro and nanoelectronic sensor devices for various other target analytes.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.25 no.10A
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• pp.1473-1479
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• 2000

This paper presents the performance evaluation of an adaptive QAM scheme under flat and frequency selective fading channels for indoor wireless communication systems. The QAM modulation is combined with differential encoding and the demodulation process is carried out noncoherently. The adaptation is performed by varying the modulation level of QAM, depending upon received signal strength. The adaptation mechanism allows a 2- or 3-bit increase or decrease at a time, if the channel condition is considered to be significantly good or bad. Simulation results show that the average number of bits per symbol (ABPS) for each symbol block transmitted over a flat fading channel is higher than 5.0 and the BER performance is better than 10^-4 for a SNR value higher than 30 dB. For frequency selective fading channels, an oversampling technique in the receiver was employed. The BER performance obtained for frequency selective fading channels is better than 10^-4 with a SNR value of 40 dB and ABPS is found to be approximately 5.5. Therefore, this scheme is very useful in that it provides both very high bandwidth efficiency and acceptable performance with moderate SNR values over flat and frequency selective fading channels. In addition, this scheme provides reduced receiver complexity by way of noncoherent detection.

• Journal of Korea Multimedia Society
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• v.18 no.11
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• pp.1289-1301
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• 2015

Pedestrian detection (PD) is an essential task in various applications and sliding window-based methods utilizing HOG (Histogram of Oriented Gradients) or HOG-like descriptors have been shown to be very effective for accurate PD. However, due to exhaustive search across images, PD methods based on sliding window usually require heavy computational time. In this paper, we propose a real-time PD method for embedded visual surveillance with fixed backgrounds. The proposed PD method employs HOG descriptors as many PD methods does, but utilizes selective search so that it can save processing time significantly. The proposed selective search is guided by restricting searching to candidate regions extracted from Adaptive Gaussian Mixture Model (AGMM)-based background subtraction technique. Moreover, approximate computation of HOG descriptor and implementation in fixed-point arithmetic mode contributes to reduction of processing time further. Possible accuracy degradation due to approximate computation is compensated by applying an appropriate one among three offline trained SVM classifiers according to sizes of candidate regions. The experimental results show that the proposed PD method significantly improves processing speed without noticeable accuracy degradation compared to the original HOG-based PD and HOG with cascade SVM so that it is a suitable real-time PD implementation for embedded surveillance systems.

• Journal of Power Electronics
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• v.13 no.5
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• pp.884-895
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• 2013

In this paper, the Fourier-based PLL (Phase-locked Loop) is introduced with a new structure, capable of selective harmonic detection in single and three-phase systems. The application of the FB-PLL to harmonic detection is discussed and a new model applicable to three-phase systems is introduced. An analysis of the convergence of the FB-PLL based on a linear model is presented. Simulation and experimental results are included for performance analysis and to support the theoretical development. The decomposition of an input signal in its harmonic components using the Fourier theory is based on previous knowledge of the signal fundamental frequency, which cannot be easily implemented with input signals with varying frequencies or subjected to phase-angle jumps. In this scenario, the main contribution of this paper is the association of a phase-locked loop system, with a harmonic decomposition and reconstruction method, based on the well-established Fourier theory, to allow for the tracking of the fundamental component and desired harmonics from distorted input signals with a varying frequency, amplitude and phase-angle. The application of the proposed technique in three-phase systems is supported by results obtained under unbalanced and voltage sag conditions.